Articles | Volume 22, issue 10
https://doi.org/10.5194/acp-22-6971-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-6971-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
31 May 2022
Research article |
| 31 May 2022
| 31 May 2022
Reversible and irreversible gas–particle partitioning of dicarbonyl compounds observed in the real atmosphere
Jingcheng Hu
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Zhongming Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Xuan Qin
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Ping Dong
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Viewed
Total article views: 4,039 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 09 Feb 2022)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,883 | 1,062 | 94 | 4,039 | 378 | 99 | 136 |
- HTML: 2,883
- PDF: 1,062
- XML: 94
- Total: 4,039
- Supplement: 378
- BibTeX: 99
- EndNote: 136
Total article views: 3,160 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 31 May 2022)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,288 | 798 | 74 | 3,160 | 209 | 83 | 116 |
- HTML: 2,288
- PDF: 798
- XML: 74
- Total: 3,160
- Supplement: 209
- BibTeX: 83
- EndNote: 116
Total article views: 879 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 09 Feb 2022)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 595 | 264 | 20 | 879 | 169 | 16 | 20 |
- HTML: 595
- PDF: 264
- XML: 20
- Total: 879
- Supplement: 169
- BibTeX: 16
- EndNote: 20
Viewed (geographical distribution)
Total article views: 4,039 (including HTML, PDF, and XML)
Thereof 4,039 with geography defined
and 0 with unknown origin.
Total article views: 3,160 (including HTML, PDF, and XML)
Thereof 3,160 with geography defined
and 0 with unknown origin.
Total article views: 879 (including HTML, PDF, and XML)
Thereof 879 with geography defined
and 0 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
29 citations as recorded by crossref.
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet
- An alcohol-governed mechanism of monocarbonyl oligomerization: implications for explosive growth of fine particulate matter Y. Ji et al.
- Online headspace monitoring of volatile organic compounds using proton transfer reaction-mass spectrometry: Application to the multiphase atmospheric fate of 2,4-hexadienedial N. Brun et al.
- Diurnal and Seasonal Variability of Gas–Particle Partitioning of Secondary Organic Aerosols in the Tropical Atmosphere S. Boreddy et al.
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al.
- Formation and composition of organic aerosols from the uptake of glyoxal on natural mineral dust aerosols: a laboratory study F. Battaglia et al.
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al.
- Online Speciation of Glyoxal Multiphase Reactions on Deliquesced Ammonium Sulfate Particles N. Brun et al.
- Development of SOA modules in the WRF-Chem model and evaluation of the key formation pathways of SOA and associated health risk over mainland China L. Wu et al.
- Positive Feedback between Partitioning of Carbonyl Compounds and Particulate Sulfur Formation during Haze Episodes H. Shen et al.
- Photochemical impacts of atmospheric carbonyl compounds on ozone formation and radical chemistry in urban Shanghai Y. Chen et al.
- Experimental evidence for the elusive ketohydroperoxide pathway and the formation of glyoxal in ethylene ozonolysis C. Lewin et al.
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al.
- Gas–particle partitioning of toluene oxidation products: an experimental and modeling study V. Lannuque et al.
- Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al.
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al.
- Ammonolysis and hydrolysis govern multiphase formaldehyde–amine chemistry Z. Dong & B. Long
- Determination of Urban Formaldehyde Emission Ratios in the Shanghai Megacity Y. Liu et al.
- Driving factors of oxalic acid and enhanced role of gas-phase oxidation under cleaner conditions: insights from 2007–2018 field observations in the Pearl River Delta Y. He et al.
- Impact of reversible and irreversible gas-particle partitioning of atmospheric carbonyl compounds on oxalic acid formation and δ¹ ³C distribution in Northwest China W. Qi et al.
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al.
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen
- Carbonyl Compounds Regulate Atmospheric Oxidation Capacity and Particulate Sulfur Chemistry in the Coastal Atmosphere M. Zhao et al.
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al.
- Kinetics and Mechanisms of Reactive Uptake of Methylglyoxal on Deliquesced Ammonium Salts: Acid Catalysis and Sulfate Inhibition H. Liu et al.
- PTR-QMS observation of OVOCs in an urban suburb of Guangzhou: seasonal characterization, source apportionment and regional transport X. Ma et al.
- Comparison of Gas–Particle Partitioning of Glyoxal and Methylglyoxal in the Summertime Atmosphere at the Foot and Top of Mount Hua W. Qi et al.
- Dark, Photolysis, and Oxidation Reaction Mechanism of Gaseous Dicarbonyls Based on PTR-TOF-MS X. Ma et al.
- Undervalued Contribution of OVOCs to Atmospheric Activity: A Case Study in Beijing K. Chen et al.
29 citations as recorded by crossref.
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet
- An alcohol-governed mechanism of monocarbonyl oligomerization: implications for explosive growth of fine particulate matter Y. Ji et al.
- Online headspace monitoring of volatile organic compounds using proton transfer reaction-mass spectrometry: Application to the multiphase atmospheric fate of 2,4-hexadienedial N. Brun et al.
- Diurnal and Seasonal Variability of Gas–Particle Partitioning of Secondary Organic Aerosols in the Tropical Atmosphere S. Boreddy et al.
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al.
- Formation and composition of organic aerosols from the uptake of glyoxal on natural mineral dust aerosols: a laboratory study F. Battaglia et al.
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al.
- Online Speciation of Glyoxal Multiphase Reactions on Deliquesced Ammonium Sulfate Particles N. Brun et al.
- Development of SOA modules in the WRF-Chem model and evaluation of the key formation pathways of SOA and associated health risk over mainland China L. Wu et al.
- Positive Feedback between Partitioning of Carbonyl Compounds and Particulate Sulfur Formation during Haze Episodes H. Shen et al.
- Photochemical impacts of atmospheric carbonyl compounds on ozone formation and radical chemistry in urban Shanghai Y. Chen et al.
- Experimental evidence for the elusive ketohydroperoxide pathway and the formation of glyoxal in ethylene ozonolysis C. Lewin et al.
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al.
- Gas–particle partitioning of toluene oxidation products: an experimental and modeling study V. Lannuque et al.
- Modelling molecular composition of SOA from toluene photo-oxidation at urban and street scales K. Sartelet et al.
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al.
- Ammonolysis and hydrolysis govern multiphase formaldehyde–amine chemistry Z. Dong & B. Long
- Determination of Urban Formaldehyde Emission Ratios in the Shanghai Megacity Y. Liu et al.
- Driving factors of oxalic acid and enhanced role of gas-phase oxidation under cleaner conditions: insights from 2007–2018 field observations in the Pearl River Delta Y. He et al.
- Impact of reversible and irreversible gas-particle partitioning of atmospheric carbonyl compounds on oxalic acid formation and δ¹ ³C distribution in Northwest China W. Qi et al.
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al.
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen
- Carbonyl Compounds Regulate Atmospheric Oxidation Capacity and Particulate Sulfur Chemistry in the Coastal Atmosphere M. Zhao et al.
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al.
- Kinetics and Mechanisms of Reactive Uptake of Methylglyoxal on Deliquesced Ammonium Salts: Acid Catalysis and Sulfate Inhibition H. Liu et al.
- PTR-QMS observation of OVOCs in an urban suburb of Guangzhou: seasonal characterization, source apportionment and regional transport X. Ma et al.
- Comparison of Gas–Particle Partitioning of Glyoxal and Methylglyoxal in the Summertime Atmosphere at the Foot and Top of Mount Hua W. Qi et al.
- Dark, Photolysis, and Oxidation Reaction Mechanism of Gaseous Dicarbonyls Based on PTR-TOF-MS X. Ma et al.
- Undervalued Contribution of OVOCs to Atmospheric Activity: A Case Study in Beijing K. Chen et al.
Saved (final revised paper)
Latest update: 30 Apr 2026
Short summary
The gas–particle partitioning process of glyoxal and methylglyoxal could contribute to secondary organic aerosol formation. Here, we launched five observations in different seasons and simultaneously measured glyoxal and methylglyoxal in the gas and particle phases. Compared to reversible pathways, irreversible pathways played a dominant role with a proportion of more than 90 % in the ambient atmosphere, and the proportion was influenced by relative humidity and inorganic components in aerosols.
The gas–particle partitioning process of glyoxal and methylglyoxal could contribute to secondary...
Altmetrics
Final-revised paper
Preprint