Articles | Volume 22, issue 8 
            
                
                    
            
            
            https://doi.org/10.5194/acp-22-5619-2022
                    © Author(s) 2022. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-5619-2022
                    © Author(s) 2022. This work is distributed under 
the Creative Commons Attribution 4.0 License.
                the Creative Commons Attribution 4.0 License.
Oxidation product characterization from ozonolysis of the diterpene ent-kaurene
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    Olga Garmash
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    
                                            Aerosol Physics Laboratory, Physics Unit, Tampere University, Tampere,
33014, Finland
                                        
                                    Haiyan Li
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    
                                            School of Civil and Environmental Engineering, Harbin Institute of
Technology, Shenzhen, 518055, China
                                        
                                    Frans Graeffe
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    Arnaud P. Praplan
                                            Atmospheric Composition Research, Finnish Meteorological Institute,
Helsinki, 00101, Finland
                                        
                                    Anssi Liikanen
                                            Atmospheric Composition Research, Finnish Meteorological Institute,
Helsinki, 00101, Finland
                                        
                                    Yanjun Zhang
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    
                                            Université Claude Bernard Lyon 1, CNRS, IRCELYON,
Villeurbanne, 69626, France
                                        
                                    Melissa Meder
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    Otso Peräkylä
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    Josep Peñuelas
                                            Centre for Research on Ecology and Forestry Applications (CREAF), Bellaterra (Cerdanyola del Vallès), Catalonia, 08193, Spain
                                        
                                    
                                            Consejo Superior de Investigaciones Científicas (CSIC), Global Ecology Unit, CREAF-CSIC-UAB, Bellaterra (Cerdanyola del
Vallès), Catalonia, 08193, Spain
                                        
                                    Ana María Yáñez-Serrano
                                            Centre for Research on Ecology and Forestry Applications (CREAF), Bellaterra (Cerdanyola del Vallès), Catalonia, 08193, Spain
                                        
                                    
                                            Consejo Superior de Investigaciones Científicas (CSIC), Global Ecology Unit, CREAF-CSIC-UAB, Bellaterra (Cerdanyola del
Vallès), Catalonia, 08193, Spain
                                        
                                    
                                            Institute of Environmental Assessment and Water Research (IDAEA)-CSIC, Barcelona, 08034, Spain
                                        
                                    
                                            Institute for Atmospheric and Earth System Research/Physics, Faculty
of Science, University of Helsinki, Helsinki, 00014, Finland
                                        
                                    Viewed
                        
                            Total article views: 3,333 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 27 Oct 2021)
                        
                        
                            
                                
                            
                    
        
                    
                    | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,488 | 782 | 63 | 3,333 | 269 | 65 | 94 | 
- HTML: 2,488
- PDF: 782
- XML: 63
- Total: 3,333
- Supplement: 269
- BibTeX: 65
- EndNote: 94
                        
                            Total article views: 2,471 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 27 Apr 2022)
                        
                        
                            
                                
                            
                    
                    
                    | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,997 | 435 | 39 | 2,471 | 138 | 56 | 83 | 
- HTML: 1,997
- PDF: 435
- XML: 39
- Total: 2,471
- Supplement: 138
- BibTeX: 56
- EndNote: 83
                        
                            Total article views: 862 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 27 Oct 2021)
                        
                        
                            
                                
                            
                    
        
                
            | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 491 | 347 | 24 | 862 | 131 | 9 | 11 | 
- HTML: 491
- PDF: 347
- XML: 24
- Total: 862
- Supplement: 131
- BibTeX: 9
- EndNote: 11
Viewed (geographical distribution)
                                Total article views: 3,333 (including HTML, PDF, and XML)
                                
                                Thereof 3,333 with geography defined
                                    and 0 with unknown origin. 
                            
        
                            
                                Total article views: 2,471 (including HTML, PDF, and XML)
                                
                                Thereof 2,471 with geography defined
                                    and 0 with unknown origin. 
                            
        
                            
                                Total article views: 862 (including HTML, PDF, and XML)
                                
                                Thereof 862 with geography defined
                                    and 0 with unknown origin. 
                            
                    | Country | # | Views | % | 
|---|
| Country | # | Views | % | 
|---|
| Country | # | Views | % | 
|---|
| Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
1
                            | Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
1
                            | Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
1
                            Cited
6 citations as recorded by crossref.
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids Y. Luo et al. 10.5194/acp-25-4655-2025
- High emission rates and strong temperature response make boreal wetlands a large source of isoprene and terpenes L. Vettikkat et al. 10.5194/acp-23-2683-2023
- Unaccounted impacts of diterpene emissions on atmospheric aerosol loadings A. Yáñez-Serrano et al. 10.1038/s43247-025-02613-6
- Common garden experiments suggest terpene-mediated associations between phyllosphere microbes and Japanese cedar S. Ishizaki et al. 10.1038/s41598-025-16496-2
- Production of secondary metabolites using tissue culture-based biotechnological applications I. Ozyigit et al. 10.3389/fpls.2023.1132555
5 citations as recorded by crossref.
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids Y. Luo et al. 10.5194/acp-25-4655-2025
- High emission rates and strong temperature response make boreal wetlands a large source of isoprene and terpenes L. Vettikkat et al. 10.5194/acp-23-2683-2023
- Unaccounted impacts of diterpene emissions on atmospheric aerosol loadings A. Yáñez-Serrano et al. 10.1038/s43247-025-02613-6
- Common garden experiments suggest terpene-mediated associations between phyllosphere microbes and Japanese cedar S. Ishizaki et al. 10.1038/s41598-025-16496-2
1 citations as recorded by crossref.
Latest update: 30 Oct 2025
Short summary
                    Diterpenes were only recently observed in the atmosphere, and little is known of their atmospheric fates. We explored the ozonolysis of the diterpene kaurene in a chamber, and we characterized the oxidation products for the first time using chemical ionization mass spectrometry. Our findings highlight similarities and differences between diterpenes and smaller terpenes during their atmospheric oxidation.
                    Diterpenes were only recently observed in the atmosphere, and little is known of their...
                    
                Altmetrics
                
                Final-revised paper
            
            
                    Preprint
                
                     
 
                             
                             
                     
                     
                    