Articles | Volume 22, issue 8
https://doi.org/10.5194/acp-22-5477-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-5477-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Apr 2022
Research article |
| 26 Apr 2022
| 26 Apr 2022
Global simulations of monoterpene-derived peroxy radical fates and the distributions of highly oxygenated organic molecules (HOMs) and accretion products
Ruochong Xu
Department of Atmospheric Sciences, University of Washington,
Seattle, WA 91895, USA
School of Atmospheric Sciences, Nanjing University, Nanjing 210023,
China
now at: Department of Earth System Science, Tsinghua University,
Beijing 100084, China
Joel A. Thornton
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington,
Seattle, WA 91895, USA
Ben H. Lee
Department of Atmospheric Sciences, University of Washington,
Seattle, WA 91895, USA
Yanxu Zhang
School of Atmospheric Sciences, Nanjing University, Nanjing 210023,
China
Lyatt Jaeglé
Department of Atmospheric Sciences, University of Washington,
Seattle, WA 91895, USA
Felipe D. Lopez-Hilfiker
Department of Atmospheric Sciences, University of Washington,
Seattle, WA 91895, USA
now at: TOFWERK AG, 3645 Thun, Switzerland
Pekka Rantala
Institute for Atmospheric and Earth System Research (INAR)/Physics,
University of Helsinki, Helsinki 00014, Finland
Tuukka Petäjä
Institute for Atmospheric and Earth System Research (INAR)/Physics,
University of Helsinki, Helsinki 00014, Finland
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Cited
15 citations as recorded by crossref.
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Ring-opening yields and auto-oxidation rates of the resulting peroxy radicals from OH-oxidation of α-pinene and β-pinene B. Lee et al. 10.1039/D2EA00133K
- Olfaction in the Anthropocene: NO 3 negatively affects floral scent and nocturnal pollination J. Chan et al. 10.1126/science.adi0858
- Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon Y. He et al. 10.1021/acsestair.4c00240
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al. 10.1016/j.jes.2024.08.007
- Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs) X. Shao et al. 10.5194/acp-24-11365-2024
- Kinetics and Oligomer Products of the Multiphase Reactions of Hydroxyacetone with Atmospheric Amines, Ammonium Sulfate, and Cloud Processing D. De Haan et al. 10.1021/acsearthspacechem.4c00237
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. 10.1007/s40726-022-00246-3
- On the formation of biogenic secondary organic aerosol in chemical transport models: an evaluation of the WRF-CHIMERE (v2020r2) model with a focus over the Finnish boreal forest G. Ciarelli et al. 10.5194/gmd-17-545-2024
- High frequency of new particle formation events driven by summer monsoon in the central Tibetan Plateau, China L. Tang et al. 10.5194/acp-23-4343-2023
- Theoretical study of the reaction of organic peroxyl radicals with alkenes and their accretion products involved in the atmospheric nucleation B. Dong et al. 10.1016/j.atmosenv.2024.120718
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Global Simulations of Phase State and Equilibration Time Scales of Secondary Organic Aerosols with GEOS-Chem R. Luu et al. 10.1021/acsearthspacechem.4c00281
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Exploring the Factors Controlling the Long‐Term Trend (1988–2019) of Surface Organic Aerosols in the Continental United States by Simulations Y. Liu et al. 10.1029/2022JD037935
14 citations as recorded by crossref.
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Ring-opening yields and auto-oxidation rates of the resulting peroxy radicals from OH-oxidation of α-pinene and β-pinene B. Lee et al. 10.1039/D2EA00133K
- Olfaction in the Anthropocene: NO 3 negatively affects floral scent and nocturnal pollination J. Chan et al. 10.1126/science.adi0858
- Kinetic Modeling of Secondary Organic Aerosol in a Weather-Chemistry Model: Parameterizations, Processes, and Predictions for GOAmazon Y. He et al. 10.1021/acsestair.4c00240
- Comparative studies of the NOx impacts on the photooxidation mechanisms of isomeric monoterpenes of β-pinene and limonene Y. Zhao et al. 10.1016/j.jes.2024.08.007
- Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs) X. Shao et al. 10.5194/acp-24-11365-2024
- Kinetics and Oligomer Products of the Multiphase Reactions of Hydroxyacetone with Atmospheric Amines, Ammonium Sulfate, and Cloud Processing D. De Haan et al. 10.1021/acsearthspacechem.4c00237
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. 10.1007/s40726-022-00246-3
- On the formation of biogenic secondary organic aerosol in chemical transport models: an evaluation of the WRF-CHIMERE (v2020r2) model with a focus over the Finnish boreal forest G. Ciarelli et al. 10.5194/gmd-17-545-2024
- High frequency of new particle formation events driven by summer monsoon in the central Tibetan Plateau, China L. Tang et al. 10.5194/acp-23-4343-2023
- Theoretical study of the reaction of organic peroxyl radicals with alkenes and their accretion products involved in the atmospheric nucleation B. Dong et al. 10.1016/j.atmosenv.2024.120718
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Global Simulations of Phase State and Equilibration Time Scales of Secondary Organic Aerosols with GEOS-Chem R. Luu et al. 10.1021/acsearthspacechem.4c00281
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
Latest update: 23 Apr 2025
Short summary
Monoterpenes are emitted into the atmosphere by vegetation and by the use of certain consumer products. Reactions of monoterpenes in the atmosphere lead to low-volatility products that condense to grow particulate matter or participate in new particle formation and, thus, affect air quality and climate. We use a model of atmospheric chemistry and transport to evaluate the global-scale importance of recent updates to our understanding of monoterpene chemistry in particle formation and growth.
Monoterpenes are emitted into the atmosphere by vegetation and by the use of certain consumer...
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