Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 22, issue 5
Articles | Volume 22, issue 5
https://doi.org/10.5194/acp-22-3525-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-3525-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 22, issue 5
Research article
 | 
16 Mar 2022
Research article |  | 16 Mar 2022

Interpretation of NO3–N2O5 observation via steady state in high-aerosol air mass: the impact of equilibrium coefficient in ambient conditions

Xiaorui Chen, Haichao Wang, and Keding Lu

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Short summary
We use a complete set of simulations to evaluate whether equilibrium and steady state are appropriate for a chemical system involving several reactive nitrogen-containing species (NO2, NO3, and N2O5) under various conditions. A previously neglected bias for the coefficient applied for interpreting their effects is disclosed, and the relevant ambient factors are examined. We therefore provide a good solution to an accurate representation of nighttime chemistry in high-aerosol areas.
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