Articles | Volume 22, issue 3
https://doi.org/10.5194/acp-22-1951-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-1951-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Pyruvic acid, an efficient catalyst in SO3 hydrolysis and effective clustering agent in sulfuric-acid-based new particle formation
Narcisse Tsona Tchinda
Environment Research Institute, Shandong University, Qingdao, 266237, China
Environment Research Institute, Shandong University, Qingdao, 266237, China
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China
Xiuhui Zhang
Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China
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Cited
13 citations as recorded by crossref.
- Atmospheric Chemistry of NH2SO3H in Polluted Areas: An Unexpected Isomerization of NH2SO3H in Acid-Polluted Regions Y. Zhang et al. 10.1021/acs.jpca.3c04982
- Theoretical Study of the Synergistic Effect of Hydroxymethanesulfonic Acid With Ammonia/Methylamine/Dimethylamine/Water in the Clustering D. Chen et al. 10.1002/qua.70038
- The enhanced role of formic acid on sulfuric acid-ammonia-driven nucleation in forest regions and polluted city areas S. Chen et al. 10.1016/j.jes.2025.05.025
- A novel formation mechanism of sulfamic acid and its enhancing effect on methanesulfonic acid–methylamine aerosol particle formation in agriculture-developed and coastal industrial areas H. Wang et al. 10.5194/acp-25-2829-2025
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- The role of sulfur cycle in new particle formation: Cycloaddition reaction of SO3 to H2S H. Zhang et al. 10.1016/j.jes.2023.09.010
- Enhancing SO3 hydrolysis and nucleation: the role of formic sulfuric anhydride R. Wang et al. 10.5194/acp-25-5695-2025
- Significant influence of water molecules on the SO3 + HCl reaction in the gas phase and at the air–water interface Y. Cheng et al. 10.1039/D3CP03172A
- Sulfuric acid–dimethylamine particle formation enhanced by functional organic acids: an integrated experimental and theoretical study C. Wang et al. 10.1039/D2CP01671K
- Structural Diversity of Protonated Citric Acid-Ammonia Clusters and Its Atmospheric Implication S. Zhou et al. 10.1021/acs.jpca.3c05160
- The reaction mechanism of SO3 with the multifunctional compound ethanolamine and its atmospheric implications R. Wang et al. 10.1039/D4CP01543F
- The role of trifluoroacetic acid in new particle formation from methanesulfonic acid-methylamine Y. Hu et al. 10.1016/j.atmosenv.2023.120001
- The role of aldehydes on sulfur based-new particle formation: a theoretical study G. Zhang et al. 10.1039/D4RA00952E
13 citations as recorded by crossref.
- Atmospheric Chemistry of NH2SO3H in Polluted Areas: An Unexpected Isomerization of NH2SO3H in Acid-Polluted Regions Y. Zhang et al. 10.1021/acs.jpca.3c04982
- Theoretical Study of the Synergistic Effect of Hydroxymethanesulfonic Acid With Ammonia/Methylamine/Dimethylamine/Water in the Clustering D. Chen et al. 10.1002/qua.70038
- The enhanced role of formic acid on sulfuric acid-ammonia-driven nucleation in forest regions and polluted city areas S. Chen et al. 10.1016/j.jes.2025.05.025
- A novel formation mechanism of sulfamic acid and its enhancing effect on methanesulfonic acid–methylamine aerosol particle formation in agriculture-developed and coastal industrial areas H. Wang et al. 10.5194/acp-25-2829-2025
- Computational chemistry of cluster: Understanding the mechanism of atmospheric new particle formation at the molecular level X. Zhang et al. 10.1016/j.chemosphere.2022.136109
- The role of sulfur cycle in new particle formation: Cycloaddition reaction of SO3 to H2S H. Zhang et al. 10.1016/j.jes.2023.09.010
- Enhancing SO3 hydrolysis and nucleation: the role of formic sulfuric anhydride R. Wang et al. 10.5194/acp-25-5695-2025
- Significant influence of water molecules on the SO3 + HCl reaction in the gas phase and at the air–water interface Y. Cheng et al. 10.1039/D3CP03172A
- Sulfuric acid–dimethylamine particle formation enhanced by functional organic acids: an integrated experimental and theoretical study C. Wang et al. 10.1039/D2CP01671K
- Structural Diversity of Protonated Citric Acid-Ammonia Clusters and Its Atmospheric Implication S. Zhou et al. 10.1021/acs.jpca.3c05160
- The reaction mechanism of SO3 with the multifunctional compound ethanolamine and its atmospheric implications R. Wang et al. 10.1039/D4CP01543F
- The role of trifluoroacetic acid in new particle formation from methanesulfonic acid-methylamine Y. Hu et al. 10.1016/j.atmosenv.2023.120001
- The role of aldehydes on sulfur based-new particle formation: a theoretical study G. Zhang et al. 10.1039/D4RA00952E
Latest update: 20 Jun 2025
Short summary
This study explores the effect of pyruvic acid (PA) both in the SO3 hydrolysis and in sulfuric-acid-based aerosol formation. Results show that in dry and polluted areas, PA-catalyzed SO3 hydrolysis is about 2 orders of magnitude more efficient at forming sulfuric acid than the water-catalyzed reaction. Moreover, PA can effectively enhance the ternary SA-PA-NH3 particle formation rate by up to 4.7×102 relative to the binary SA-NH3 particle formation rate at cold temperatures.
This study explores the effect of pyruvic acid (PA) both in the SO3 hydrolysis and in...
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