Articles | Volume 22, issue 20
https://doi.org/10.5194/acp-22-13677-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-22-13677-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Oct 2022
Research article |
| 21 Oct 2022
| 21 Oct 2022
The influence of the addition of isoprene on the volatility of particles formed from the photo-oxidation of anthropogenic–biogenic mixtures
Aristeidis Voliotis
CORRESPONDING AUTHOR
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Yunqi Shao
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Thomas J. Bannan
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Michael Flynn
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Spyros N. Pandis
Department of Chemical Engineering, University of Patras, Patras,
Greece
Institute of Chemical Engineering Sciences, FORTH, Patras, Greece
Carl J. Percival
NASA Jet Propulsion Laboratory, California Institute of Technology,
4800 Oak Grove Drive, Pasadena, CA 91109, USA
M. Rami Alfarra
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Department of Earth and
Environmental Science, National Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
Gordon McFiggans
CORRESPONDING AUTHOR
Department of Earth and Environmental
Science, Centre for Atmospheric Science, School of Natural Sciences, University of Manchester, Oxford Road, M13 9PL, Manchester, UK
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Cited
9 citations as recorded by crossref.
- The evolution of carbon oxidation state during secondary organic aerosol formation from individual and mixed organic precursors Y. Shao et al. https://doi.org/10.5194/ar-3-619-2025
- Mechanism in the synergistic effects of NH3 and NOx on secondary organic aerosol formation via α-pinene photooxidation S. Liu et al. https://doi.org/10.1016/j.atmosenv.2026.122049
- Formation of secondary organic aerosol during the dark-ozonolysis of α-humulene D. Sippial et al. https://doi.org/10.1039/D2EA00181K
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. https://doi.org/10.5194/acp-22-14147-2022
- Changes in Secondary Organic Aerosol Composition and Volatility Going from a Low to a High HO2/RO2 Regime in α-Pinene Photooxidation V. Geretti et al. https://doi.org/10.1021/acsestair.5c00254
- Novel Findings on Molecular SOA Fingerprint Lists: Implications for Interaction of Multiprecursor Oxidation W. Zhu et al. https://doi.org/10.1021/acs.estlett.4c00585
- Interaction between marine and terrestrial biogenic volatile organic compounds: Non-linear effect on secondary organic aerosol formation X. Chen et al. https://doi.org/10.1016/j.atmosenv.2024.120868
- The importance of burning conditions on the composition of domestic biomass-burning organic aerosol and the impact of atmospheric ageing R. Evans et al. https://doi.org/10.5194/acp-25-4367-2025
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. https://doi.org/10.1039/D4FD00175C
9 citations as recorded by crossref.
- The evolution of carbon oxidation state during secondary organic aerosol formation from individual and mixed organic precursors Y. Shao et al. https://doi.org/10.5194/ar-3-619-2025
- Mechanism in the synergistic effects of NH3 and NOx on secondary organic aerosol formation via α-pinene photooxidation S. Liu et al. https://doi.org/10.1016/j.atmosenv.2026.122049
- Formation of secondary organic aerosol during the dark-ozonolysis of α-humulene D. Sippial et al. https://doi.org/10.1039/D2EA00181K
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. https://doi.org/10.5194/acp-22-14147-2022
- Changes in Secondary Organic Aerosol Composition and Volatility Going from a Low to a High HO2/RO2 Regime in α-Pinene Photooxidation V. Geretti et al. https://doi.org/10.1021/acsestair.5c00254
- Novel Findings on Molecular SOA Fingerprint Lists: Implications for Interaction of Multiprecursor Oxidation W. Zhu et al. https://doi.org/10.1021/acs.estlett.4c00585
- Interaction between marine and terrestrial biogenic volatile organic compounds: Non-linear effect on secondary organic aerosol formation X. Chen et al. https://doi.org/10.1016/j.atmosenv.2024.120868
- The importance of burning conditions on the composition of domestic biomass-burning organic aerosol and the impact of atmospheric ageing R. Evans et al. https://doi.org/10.5194/acp-25-4367-2025
- In situ measurements of gas–particle partitioning of organic compounds in Fairbanks A. Ijaz et al. https://doi.org/10.1039/D4FD00175C
Saved (final revised paper)
Latest update: 28 May 2026
Short summary
The addition of a low-yield precursor to the reactive mixture of aVOC and bVOC can increase or decrease the SOA volatility that is system-dependent. Therefore, the SOA volatility of the mixtures cannot always be predicted based on the additivity. In complex mixtures the formation of lower-volatility products likely outweighs the formation of products with higher volatility. The unique products of each mixture contribute significantly to the signal, suggesting interactions can be important.
The addition of a low-yield precursor to the reactive mixture of aVOC and bVOC can increase or...
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