Articles | Volume 21, issue 12
https://doi.org/10.5194/acp-21-9681-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-9681-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
29 Jun 2021
Research article |
| 29 Jun 2021
| 29 Jun 2021
Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO3 radical
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai, 200438, China
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Big Data Institute for Carbon Emission and Environmental Pollution,
Fudan University, Shanghai, 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chenjia Zhen,
Chongming, Shanghai, 202162, China
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland,
Kuopio, 7021, Finland
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Stephanie Schrade
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Rongrong Wu
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Institute of Nutrition and Food Sciences, University of Bonn,
53115 Bonn, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Jürgen Wildt
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Yindong Guo
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai, 200438, China
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
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29 citations as recorded by crossref.
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- Light absorption properties and molecular compositions of water-soluble and methanol-soluble organic carbon emitted from wood pyrolysis and combustion R. Zhao et al. 10.1016/j.scitotenv.2021.151136
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- Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark D. Bell et al. 10.5194/acp-22-13167-2022
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Synergistic Effects of SO2 and NH3 Coexistence on SOA Formation from Gasoline Evaporative Emissions T. Chen et al. 10.1021/acs.est.3c01921
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- CAMx–UNIPAR simulation of secondary organic aerosol mass formed from multiphase reactions of hydrocarbons under the Central Valley urban atmospheres of California Y. Jo et al. 10.5194/acp-24-487-2024
- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
- Emissions of volatile organic compounds from Norway spruce and potential atmospheric impacts H. Hakola et al. 10.3389/ffgc.2023.1116414
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Variations and sources of volatile organic compounds (VOCs) in urban region: insights from measurements on a tall tower X. Li et al. 10.5194/acp-22-10567-2022
- Modelling the influence of biotic plant stress on atmospheric aerosol particle processes throughout a growing season D. Taipale et al. 10.5194/acp-21-17389-2021
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Modeling daytime and nighttime secondary organic aerosol formation via multiphase reactions of biogenic hydrocarbons S. Han & M. Jang 10.5194/acp-23-1209-2023
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
- One-year observation of the mixing states of oxygenated organics-containing single particles in Guangzhou, China L. Mao et al. 10.1007/s11783-024-1824-3
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- Chemical ionization mass spectrometry: Developments and applications for on-line characterization of atmospheric aerosols and trace gases Y. Zhang et al. 10.1016/j.trac.2023.117353
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
Latest update: 26 Apr 2024
Short summary
The reaction of isoprene, a biogenic volatile organic compound with the globally largest emission rates, with NO3, an nighttime oxidant influenced heavily by anthropogenic emissions, forms a large number of highly oxygenated organic molecules (HOM). These HOM are formed via one or multiple oxidation steps, followed by autoxidation. Their total yield is much higher than that in the daytime oxidation of isoprene. They may play an important role in nighttime organic aerosol formation and growth.
The reaction of isoprene, a biogenic volatile organic compound with the globally largest...
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