Articles | Volume 21, issue 12
https://doi.org/10.5194/acp-21-9681-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-9681-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO3 radical
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai, 200438, China
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Big Data Institute for Carbon Emission and Environmental Pollution,
Fudan University, Shanghai, 200438, China
Institute of Eco-Chongming (IEC), 20 Cuiniao Rd., Chenjia Zhen,
Chongming, Shanghai, 202162, China
Iida Pullinen
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Department of Applied Physics, University of Eastern Finland,
Kuopio, 7021, Finland
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Stephanie Schrade
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Rongrong Wu
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
now at: Institute of Nutrition and Food Sciences, University of Bonn,
53115 Bonn, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Jürgen Wildt
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Yindong Guo
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, Shanghai, 200438, China
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Sungah Kang
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
Institute of Energy and Climate Research, IEK-8: Troposphere,
Forschungszentrum Jülich, 52425 Jülich, Germany
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Latest update: 23 Nov 2024
Short summary
The reaction of isoprene, a biogenic volatile organic compound with the globally largest emission rates, with NO3, an nighttime oxidant influenced heavily by anthropogenic emissions, forms a large number of highly oxygenated organic molecules (HOM). These HOM are formed via one or multiple oxidation steps, followed by autoxidation. Their total yield is much higher than that in the daytime oxidation of isoprene. They may play an important role in nighttime organic aerosol formation and growth.
The reaction of isoprene, a biogenic volatile organic compound with the globally largest...
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