Articles | Volume 21, issue 8
https://doi.org/10.5194/acp-21-6175-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-6175-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Non-equilibrium interplay between gas–particle partitioning and multiphase chemical reactions of semi-volatile compounds: mechanistic insights and practical implications for atmospheric modeling of polycyclic aromatic hydrocarbons
Jake Wilson
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Department of Chemistry, University of California, Irvine, CA, USA
Multiphase Chemistry Department, Max Planck Institute for Chemistry, Mainz, Germany
Viewed
Total article views: 2,804 (including HTML, PDF, and XML)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,972 | 784 | 48 | 2,804 | 50 | 78 |
- HTML: 1,972
- PDF: 784
- XML: 48
- Total: 2,804
- BibTeX: 50
- EndNote: 78
Cumulative views and downloads
(calculated since 07 Oct 2020)
Total article views: 2,224 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 23 Apr 2021)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,614 | 568 | 42 | 2,224 | 41 | 66 |
- HTML: 1,614
- PDF: 568
- XML: 42
- Total: 2,224
- BibTeX: 41
- EndNote: 66
Total article views: 580 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 07 Oct 2020)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
358 | 216 | 6 | 580 | 9 | 12 |
- HTML: 358
- PDF: 216
- XML: 6
- Total: 580
- BibTeX: 9
- EndNote: 12
Viewed (geographical distribution)
Total article views: 2,804 (including HTML, PDF, and XML)
Thereof 2,924 with geography defined
and -120 with unknown origin.
Total article views: 2,224 (including HTML, PDF, and XML)
Thereof 2,280 with geography defined
and -56 with unknown origin.
Total article views: 580 (including HTML, PDF, and XML)
Thereof 644 with geography defined
and -64 with unknown origin.
Country | # | Views | % |
---|---|---|---|
United States of America | 1 | 1180 | 42 |
China | 2 | 663 | 23 |
Germany | 3 | 297 | 10 |
United Kingdom | 4 | 93 | 3 |
France | 5 | 77 | 2 |
Country | # | Views | % |
---|---|---|---|
United States of America | 1 | 998 | 44 |
China | 2 | 522 | 23 |
Germany | 3 | 140 | 6 |
United Kingdom | 4 | 70 | 3 |
India | 5 | 52 | 2 |
Country | # | Views | % |
---|---|---|---|
United States of America | 1 | 182 | 31 |
Germany | 2 | 157 | 27 |
China | 3 | 141 | 24 |
France | 4 | 27 | 4 |
United Kingdom | 5 | 23 | 3 |
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
- 1180
1
1180
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
- 998
1
998
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
- 182
1
182
Cited
12 citations as recorded by crossref.
- Seasonal distribution of PM2.5-bound polycyclic aromatic hydrocarbons as a critical indicator of air quality and health impact in a coastal-urban region of Poland P. Siudek 10.1016/j.scitotenv.2022.154375
- The key characteristics of cardiotoxicity for the pervasive pollutant phenanthrene E. England et al. 10.1016/j.jhazmat.2024.133853
- Seasonal Distribution of Pm2.5-Bound Polycyclic Aromatic Hydrocarbons as a Critical Indicator of Air Quality and Health Impact in a Coastal-Urban Region of Poland P. Siudek 10.2139/ssrn.3993357
- Size-resolved gas-particle partitioning characteristics of typical semi-volatile organic compounds in urban atmosphere S. Wang et al. 10.1016/j.envpol.2023.121101
- Toxicological Effects of Secondary Air Pollutants W. Xiang et al. 10.1007/s40242-023-3050-0
- Assessment of factors affecting the diurnal variations of atmospheric PAHs based on a numerical simulation Z. Zhen et al. 10.1016/j.scitotenv.2022.158975
- A new steady-state gas–particle partitioning model of polycyclic aromatic hydrocarbons: implication for the influence of the particulate proportion in emissions F. Zhu et al. 10.5194/acp-23-8583-2023
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- An improved model on the evaporation kinetics of the single aerosol droplet and its application for the droplet composed of ammonium sulfate or sucrose solution C. Zhang et al. 10.1016/j.powtec.2025.120627
- Characterization, risk assessment, and source estimation of PM10-bound polycyclic aromatic hydrocarbons during wintertime in the ambient air of Basrah City, Iraq A. Alshaheen et al. 10.1016/j.chemosphere.2023.138444
- The impact of gaseous degradation on the gas–particle partitioning of methylated polycyclic aromatic hydrocarbons F. Zhu et al. 10.5194/acp-24-6095-2024
- Detection of polycyclic aromatic hydrocarbons using a high performance-single particle aerosol mass spectrometer Y. Zhang et al. 10.1016/j.jes.2022.02.003
12 citations as recorded by crossref.
- Seasonal distribution of PM2.5-bound polycyclic aromatic hydrocarbons as a critical indicator of air quality and health impact in a coastal-urban region of Poland P. Siudek 10.1016/j.scitotenv.2022.154375
- The key characteristics of cardiotoxicity for the pervasive pollutant phenanthrene E. England et al. 10.1016/j.jhazmat.2024.133853
- Seasonal Distribution of Pm2.5-Bound Polycyclic Aromatic Hydrocarbons as a Critical Indicator of Air Quality and Health Impact in a Coastal-Urban Region of Poland P. Siudek 10.2139/ssrn.3993357
- Size-resolved gas-particle partitioning characteristics of typical semi-volatile organic compounds in urban atmosphere S. Wang et al. 10.1016/j.envpol.2023.121101
- Toxicological Effects of Secondary Air Pollutants W. Xiang et al. 10.1007/s40242-023-3050-0
- Assessment of factors affecting the diurnal variations of atmospheric PAHs based on a numerical simulation Z. Zhen et al. 10.1016/j.scitotenv.2022.158975
- A new steady-state gas–particle partitioning model of polycyclic aromatic hydrocarbons: implication for the influence of the particulate proportion in emissions F. Zhu et al. 10.5194/acp-23-8583-2023
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- An improved model on the evaporation kinetics of the single aerosol droplet and its application for the droplet composed of ammonium sulfate or sucrose solution C. Zhang et al. 10.1016/j.powtec.2025.120627
- Characterization, risk assessment, and source estimation of PM10-bound polycyclic aromatic hydrocarbons during wintertime in the ambient air of Basrah City, Iraq A. Alshaheen et al. 10.1016/j.chemosphere.2023.138444
- The impact of gaseous degradation on the gas–particle partitioning of methylated polycyclic aromatic hydrocarbons F. Zhu et al. 10.5194/acp-24-6095-2024
- Detection of polycyclic aromatic hydrocarbons using a high performance-single particle aerosol mass spectrometer Y. Zhang et al. 10.1016/j.jes.2022.02.003
Latest update: 12 Jan 2025
Short summary
This work explores the gas–particle partitioning of PAHs on soot with a kinetic model. We show that the equilibration timescale depends on PAH molecular structure, temperature, and particle number concentration. We explore scenarios in which the particulate fraction is perturbed from equilibrium by chemical loss and discuss implications for chemical transport models that assume instantaneous equilibration at each model time step.
This work explores the gas–particle partitioning of PAHs on soot with a kinetic model. We show...
Similar articles
The role of interfacial tension in the...
Schmedding et al.
Gaps in our understanding of...
Herbert et al.
Warming effects of reduced sulfur...
Yoshioka et al.