Articles | Volume 21, issue 24
https://doi.org/10.5194/acp-21-18283-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-18283-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Evolution of volatility and composition in sesquiterpene-mixed and α-pinene secondary organic aerosol particles during isothermal evaporation
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Arttu Ylisirniö
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Luis Barreira
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Atmospheric Composition Research, Finnish Meteorological Institute,
Helsinki, Finland
Liqing Hao
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Siegfried Schobesberger
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Taina Yli-Juuti
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Annele Virtanen
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
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Cited
11 citations as recorded by crossref.
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. https://doi.org/10.5194/acp-23-6863-2023
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. https://doi.org/10.1016/j.trac.2024.117614
- Oxidation Flow Reactor and Its Application in Secondary Organic Aerosol Formation in Laboratory Studies X. Ma et al. https://doi.org/10.1021/acsestair.5c00047
- The saturation vapor pressures of higher-order polyethylene glycols and achieving a wide calibration range for volatility measurements by FIGAERO-CIMS A. Ylisirniö et al. https://doi.org/10.5194/amt-18-6449-2025
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. https://doi.org/10.5194/acp-23-203-2023
- Secondary Organic Aerosol from OH Oxidation of Acyclic Terpenes Is More Viscous and Less Volatile than That of Their Cyclic Analogs S. Liu et al. https://doi.org/10.1021/acsestair.5c00226
- Study of secondary organic aerosol formation and aging using ambient air in an oxidation flow reactor during high pollution events over Delhi V. Goel et al. https://doi.org/10.1016/j.envres.2024.118542
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. https://doi.org/10.1021/acs.est.3c01151
- Direct mitigation of secondary organic aerosol particulate pollutants by multiphase photocatalysis L. Hao et al. https://doi.org/10.1016/j.scitotenv.2024.171323
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. https://doi.org/10.5194/acp-23-6613-2023
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al. https://doi.org/10.1021/acs.est.5c11018
11 citations as recorded by crossref.
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al. https://doi.org/10.5194/acp-23-6863-2023
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. https://doi.org/10.1016/j.trac.2024.117614
- Oxidation Flow Reactor and Its Application in Secondary Organic Aerosol Formation in Laboratory Studies X. Ma et al. https://doi.org/10.1021/acsestair.5c00047
- The saturation vapor pressures of higher-order polyethylene glycols and achieving a wide calibration range for volatility measurements by FIGAERO-CIMS A. Ylisirniö et al. https://doi.org/10.5194/amt-18-6449-2025
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. https://doi.org/10.5194/acp-23-203-2023
- Secondary Organic Aerosol from OH Oxidation of Acyclic Terpenes Is More Viscous and Less Volatile than That of Their Cyclic Analogs S. Liu et al. https://doi.org/10.1021/acsestair.5c00226
- Study of secondary organic aerosol formation and aging using ambient air in an oxidation flow reactor during high pollution events over Delhi V. Goel et al. https://doi.org/10.1016/j.envres.2024.118542
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. https://doi.org/10.1021/acs.est.3c01151
- Direct mitigation of secondary organic aerosol particulate pollutants by multiphase photocatalysis L. Hao et al. https://doi.org/10.1016/j.scitotenv.2024.171323
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. https://doi.org/10.5194/acp-23-6613-2023
- Surface Crust Formation Controls Evaporation Kinetics of Secondary Organic Aerosols M. Schervish et al. https://doi.org/10.1021/acs.est.5c11018
Saved (final revised paper)
Latest update: 11 Jun 2026
Short summary
We compared the evolution of two types of secondary organic aerosol (SOA) particles during isothermal evaporation. The sesquiterpene SOA particles demonstrated higher resilience to evaporation than α-pinene SOA particles generated under comparable conditions. In-depth analysis showed that under high-relative-humidity conditions, particulate water drove the evolution of particulate constituents by reducing the particle viscosity and initiating chemical aqueous-phase processes.
We compared the evolution of two types of secondary organic aerosol (SOA) particles during...
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