Articles | Volume 21, issue 18
https://doi.org/10.5194/acp-21-13973-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-13973-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants
School of Energy and Environment, City University of Hong Kong, Hong Kong SAR, China
City University of Hong Kong Shenzhen Research Institute, Shenzhen, China
Daniel J. Jacob
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
William Downs
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
Shuting Zhai
Department of Atmospheric Sciences, University of Washington, Seattle, Washington, USA
School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen, China
Viral Shah
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
Christopher D. Holmes
Department of Earth, Ocean, and Atmospheric Science, Florida State University, Tallahassee, Florida, USA
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Becky Alexander
Department of Atmospheric Sciences, University of Washington, Seattle, Washington, USA
Mathew J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Sebastian D. Eastham
Laboratory for Aviation and the Environment, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA
J. Andrew Neuman
NOAA Chemical Sciences Laboratory (CSL), Boulder, Colorado, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
Patrick R. Veres
NOAA Chemical Sciences Laboratory (CSL), Boulder, Colorado, USA
Theodore K. Koenig
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
Department of Chemistry, University of Colorado, Boulder, Colorado, USA
Rainer Volkamer
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA
Department of Chemistry, University of Colorado, Boulder, Colorado, USA
L. Gregory Huey
School of Earth and Atmospheric Science, Georgia Institute of Technology, Atlanta, Georgia, USA
Thomas J. Bannan
School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, UK
Carl J. Percival
School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, UK
now at: Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
Ben H. Lee
Department of Atmospheric Sciences, University of Washington, Seattle, Washington, USA
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle, Washington, USA
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- Aerosol iodine recycling is a major control on tropospheric reactive iodine abundance A. Moon et al.
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- Isotopic Evidence Suggests a High Contribution of Hypohalous Acids to Sulfate Formation in the Coastal Marine Boundary Layer Q. Chen et al.
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- Exploring Deposition Observations of Oxidized Sulfur and Nitrogen as a Constraint on Emissions in the United States I. Dutta & C. Heald
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- N2O5 uptake onto saline mineral dust: a potential missing source of tropospheric ClNO2 in inland China H. Wang et al.
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- Dimethyl sulfide chemistry over the industrial era: comparison of key oxidation mechanisms and long-term observations U. Jongebloed et al.
- Nitrate chemistry in the northeast US – Part 1: Nitrogen isotope seasonality tracks nitrate formation chemistry C. Bekker et al.
- Photocatalytic chlorine atom production on mineral dust–sea spray aerosols over the North Atlantic M. van Herpen et al.
- Pollution-Derived Br2 Boosts Oxidation Power of the Coastal Atmosphere M. Xia et al.
- Application of Satellite‐Based Detections of Arctic Bromine Explosion Events Within GEOS‐Chem P. Wales et al.
- Troposphere–stratosphere-integrated bromine monoxide (BrO) profile retrieval over the central Pacific Ocean T. Koenig et al.
- Research Progress on Photolysis of Particulate Nitrate: From Experimental Characterization to Model Simulation Y. XIONG et al.
- Implementation and evaluation of the GEOS-Chem chemistry module version 13.1.2 within the Community Earth System Model v2.1 T. Fritz et al.
- Improved advection, resolution, performance, and community access in the new generation (version 13) of the high-performance GEOS-Chem global atmospheric chemistry model (GCHP) R. Martin et al.
- A novel technique for the humidity dependent calibration of hypoiodous acid (HOI) and iodine (I2) L. Marden et al.
- Interpreting Measurements of the Global Diurnal Variation of Fine Particulate Matter Using the GEOS-Chem Model Y. Li et al.
- Developing the chemistry module for 27 fluorinated greenhouse gases (F-gases): Reactions, emissions, and implementation in GEOS-Chem Y. Li et al.
- Atmospheric oxidation of hydroxymethyl methyl α-lactone (HMML), initiated by OH radicals and Cl atoms S. Daimari et al.
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al.
- Impacts of sea ice leads on sea salt aerosols and atmospheric chemistry in the Arctic E. Emme & H. Horowitz
- Characterisation of gaseous iodine species detection using the multi-scheme chemical ionisation inlet 2 with bromide and nitrate chemical ionisation methods X. He et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- Halogen Emissions from Coal-Fired Power Plants in China: Evolutions, Driving Forces, and Future Trends Z. Fu et al.
- Elevated Gaseous Oxidized Mercury Revealed by a Newly Developed Speciated Atmospheric Mercury Monitoring System Y. Tang et al.
- Clumped‐Isotope Constraint on Upper‐Tropospheric Cooling During the Last Glacial Maximum A. Banerjee et al.
- Predictive Chemical Kinetic Modeling: Where We Succeed, Where We Struggle, and What Comes Next A. Grinberg Dana et al.
- Efficient Production of Carbonyl Sulfide in the Low‐NOx Oxidation of Dimethyl Sulfide C. Jernigan et al.
- Global retrieval of stratospheric and tropospheric BrO columns from the Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) on board the Suomi-NPP satellite H. Chong et al.
- Development, intercomparison, and evaluation of an improved mechanism for the oxidation of dimethyl sulfide in the UKCA model B. Cala et al.
- Comparing the Effect of Anthropogenically Amplified Halogen Natural Emissions on Tropospheric Ozone Chemistry Between Pre‐Industrial and Present‐Day J. Barrera et al.
- Impacts of Ship Emissions on Air Quality in Southern China: Opportunistic Insights from the Abrupt Emission Changes in Early 2020 X. Feng et al.
- Background nitrogen dioxide (NO2) over the United States and its implications for satellite observations and trends: effects of nitrate photolysis, aircraft, and open fires R. Dang et al.
- Impact of eastern and central Pacific El Niño on lower tropospheric ozone in China Z. Jiang & J. Li
- Atmospheric source of mercury to the ocean constrained by isotopic model Z. Song et al.
- Seasonal Variability in Marine Atmospheric Mercury Isotope Signatures and Environmental Drivers Z. Song et al.
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al.
- Contributions of lightning to long-term trends and inter-annual variability in global atmospheric chemistry constrained by Schumann resonance observations X. Wang et al.
- The Multi-Compartment Hg Modeling and Analysis Project (MCHgMAP): mercury modeling to support international environmental policy A. Dastoor et al.
- An Adaptive Auto‐Reduction Solver for Speeding Up Integration of Chemical Kinetics in Atmospheric Chemistry Models: Implementation and Evaluation in the Kinetic Pre‐Processor (KPP) Version 3.0.0 H. Lin et al.
- Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS J. Halfacre et al.
- Estimating emissions of methane consistent with atmospheric measurements of methane and δ13C of methane S. Basu et al.
- Fundamental oxidation processes in the remote marine atmosphere investigated using the NO–NO2–O3 photostationary state S. Andersen et al.
- Technical note: Entrainment-limited kinetics of bimolecular reactions in clouds C. Holmes
- Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO2) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer D. Kilgour et al.
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- Spatial and temporal variations of surface background ozone in China analyzed with the grid-stretching capability of GEOS-Chem High Performance X. Ye et al.
- How do Cl concentrations matter for the simulation of CH4 and δ13C(CH4) and estimation of the CH4 budget through atmospheric inversions? J. Thanwerdas et al.
- Impact of Model Spatial Resolution on Global Geophysical Satellite-Derived Fine Particulate Matter D. Zhang et al.
- Enhanced photochemical formation of active nitrogen species from aqueous nitrate in the presence of halide ions Y. Zhao et al.
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li
- Evaluating atmospheric mercury (Hg) uptake by vegetation in a chemistry-transport model A. Feinberg et al.
- Daytime Atmospheric Halogen Cycling through Aqueous-Phase Oxygen Atom Chemistry E. Dalton et al.
- Comparing the Importance of Iodine and Isoprene on Tropospheric Photochemistry R. Pound et al.
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li
- Multidecadal increases in global tropospheric ozone derived from ozonesonde and surface site observations: can models reproduce ozone trends? A. Christiansen et al.
- Significant contributions of sea spray aerosol to vertical ClNO2 formation over coastal South China Y. Zhu et al.
- Nitrate chemistry in the northeast US – Part 2: Oxygen isotopes reveal differences in particulate and gas-phase formation H. Kim et al.
- Impacts of updated reaction kinetics on the global GEOS-Chem simulation of atmospheric chemistry K. Bates et al.
- Determining the key sources of uncertainty in dimethyl sulfide and methanethiol oxidation under tropical, temperate, and polar marine conditions L. Jacob et al.
- Halogen Production from Playa Dust Emitted from the Great Salt Lake: Implications of the Shrinking Great Salt Lake on Regional Air Quality J. Christie et al.
- Global Methane Budget 2000–2020 M. Saunois et al.
- A nitrate photolysis source of tropospheric HONO is incompatible with current understanding of atmospheric chemistry M. Rowlinson et al.
Saved (final revised paper)
Latest update: 28 Apr 2026
Short summary
Halogen radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a new mechanistic description and comprehensive simulation of tropospheric halogens in a global 3-D model and compare the model results with surface and aircraft measurements. We find that halogen chemistry decreases the global tropospheric burden of ozone by 11 %, NOx by 6 %, and OH by 4 %.
Halogen radicals have a broad range of implications for tropospheric chemistry, air quality, and...
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