Articles | Volume 21, issue 17
https://doi.org/10.5194/acp-21-13537-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-13537-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Reactions of NO3 with aromatic aldehydes: gas-phase kinetics and insights into the mechanism of the reaction
Yangang Ren
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
Li Zhou
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
present address: College of Architecture and Environment, Sichuan
University, Chengdu 610065, China
Abdelwahid Mellouki
CORRESPONDING AUTHOR
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
Environment Research Institute, School of Environmental Science and
Engineering, Shandong University, Qingdao 266237, China
Véronique Daële
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
Mahmoud Idir
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
Steven S. Brown
NOAA, Chemical Sciences Laboratory, Boulder, CO, USA
Department of Chemistry, University of Colorado, Boulder, CO, USA
Branko Ruscic
Chemical Sciences and Engineering Division, Argonne National Laboratory,
Lemont, IL 60439, USA
Robert S. Paton
Department of Chemistry, Colorado State University, Fort Collins, CO, USA
Max R. McGillen
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
A. R. Ravishankara
CORRESPONDING AUTHOR
Institut de Combustion Aèrothermique, Réactivité et Environnement, Centre
National de la Recherche Scientifique (ICARE-CNRS), Observatoire des
Sciences de l'Univers en reìgion Centre (OSUC), CS 50060, 45071 CEDEX02
Orléans, France
Department of Chemistry, Colorado State University, Fort Collins, CO, USA
Department of Atmospheric Science, Colorado State University, Fort Collins,
CO, USA
Le Studium Institute for Advanced Studies, Orléans, France
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- Development, optimization and validation of automated volatile organic compound data analysis using an on-line thermal desorption gas chromatograph with dual detection and application to measurements in ambient air F. Bachelier et al. 10.1016/j.chroma.2024.465327
- Theoretical kinetic investigation of the multichannel mechanism of O(3P) atmospheric oxidation reaction of but-3-enal B. Messaoudı et al. 10.33435/tcandtc.1277724
- Quantitative kinetics reveal that reactions of HO2 are a significant sink for aldehydes in the atmosphere and may initiate the formation of highly oxygenated molecules via autoxidation Q. Gao et al. 10.1039/D4CP00693C
Latest update: 01 Nov 2024
Short summary
Aromatic aldehydes are a family of compounds emitted into the atmosphere from both anthropogenic and biogenic sources that are formed from the degradation of aromatic hydrocarbons. Their atmospheric degradation may impact air quality. We report on their atmospheric degradation through reaction with NO3, which is useful to estimate their atmospheric lifetimes. We have also attempted to elucidate the mechanism of these reactions via studies of isotopic substitution and quantum chemistry.
Aromatic aldehydes are a family of compounds emitted into the atmosphere from both anthropogenic...
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