Articles | Volume 21, issue 17
https://doi.org/10.5194/acp-21-13269-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-13269-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Sep 2021
Research article |
| 07 Sep 2021
| 07 Sep 2021
Ammonium nitrate promotes sulfate formation through uptake kinetic regime
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
College of Chemistry and Chemical Engineering, China West Normal
University, Nanchong, 637002, China
Zemin Feng
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Feixue Zheng
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Xiaolei Bao
CORRESPONDING AUTHOR
Hebei Provincial Academy of Environmental Sciences, Shijiazhuang, 050037,
China
Hebei Chemical & Pharmaceutical College, Shijiazhuang, 050026, China
Pengfei Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Yanli Ge
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Yan Zhao
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Tao Jiang
Hebei Provincial Meteorological Technical Equipment Center, Shijiazhuang,
050021, China
Yunwen Liao
College of Chemistry and Chemical Engineering, China West Normal
University, Nanchong, 637002, China
Yusheng Zhang
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Xiaolong Fan
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Yonghong Wang
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Jing Cai
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Federico Bianchi
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Tuukka Petäjä
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Joint International Research Laboratory of Atmospheric and Earth System
Sciences (JirLATEST), University of Helsinki and Nanjing University, Nanjing
210023, China
Yujing Mu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Markku Kulmala
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
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23 citations as recorded by crossref.
- Atmospheric sulfate formation in the Seoul Metropolitan Area during spring/summer: Effect of trace metal ions N. Kim et al. 10.1016/j.envpol.2022.120379
- The role of source emissions in sulfate formation pathways based on chemical thermodynamics and kinetics model J. Gao et al. 10.1016/j.scitotenv.2022.158104
- Dust emission reduction enhanced gas-to-particle conversion of ammonia in the North China Plain Y. Liu et al. 10.1038/s41467-022-34733-4
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023
- Changes in source specific PM2.5 from 2010 to 2019 in New York and New Jersey identified by dispersion normalized PMF Y. Chen et al. 10.1016/j.atmosres.2024.107353
- Weakened Gas-to-Particle Partitioning of Oxygenated Organic Molecules in Liquified Aerosol Particles W. Ma et al. 10.1021/acs.estlett.2c00556
- Characteristics of aerosol size distribution and liquid water content under ambient RH conditions in Beijing H. Dai et al. 10.1016/j.atmosenv.2022.119397
- Characterization and sources of water-soluble inorganic ions during sulfate-driven and nitrate-driven haze on the largest loess accumulation plateau W. Wang et al. 10.1016/j.chemosphere.2023.140261
- Nitrate formation and iron dissolution in the heterogeneous reactions of NH3 on nano α-Fe2O3 R. Wang et al. 10.1039/D3EN00494E
- Decade-long trends in chemical component properties of PM2.5 in Beijing, China (2011−2020) J. Wang et al. 10.1016/j.scitotenv.2022.154664
- Mechanism for the promotional formation of NH4+ by SO2 on different mineral dust surfaces H. Li et al. 10.1016/j.partic.2022.07.007
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- High contribution of anthropogenic combustion sources to atmospheric inorganic reactive nitrogen in South China evidenced by isotopes T. Li et al. 10.5194/acp-23-6395-2023
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al. 10.1029/2022JD038382
- Progressively narrow the gap of PM2.5 pollution characteristics at urban and suburban sites in a megacity of Sichuan Basin, China N. Wang et al. 10.1016/j.jes.2022.05.017
- Promoted Activity of Surface Hydroxyls on γ-Al2O3 Mineral Dust with the Coexistence of SO2 and NH3 H. Li et al. 10.1021/acs.jpclett.2c02734
- Role of WSOCs and pH on Ammonium Nitrate Aerosol Efflorescence: Insights into Secondary Aerosol Formation J. Sun et al. 10.1021/acs.est.3c07603
- Combustion related ammonia promotes PM2.5 accumulation in autumn in Tianjin, China H. Xiao et al. 10.1016/j.atmosres.2022.106225
- The role of NOx in Co-occurrence of O3 and PM2.5 pollution driven by wintertime east Asian monsoon in Hainan J. Zhan et al. 10.1016/j.jenvman.2023.118645
- Exploring the formation mechanism of fine particles in an ex-heavily polluted Northwestern city, China Z. Liu et al. 10.1016/j.scitotenv.2022.161333
- Highly oxidized organic aerosols in Beijing: Possible contribution of aqueous-phase chemistry Z. Feng et al. 10.1016/j.atmosenv.2022.118971
- Impact of atmospheric O3 and NO2 on the secondary sulfates in real atmosphere K. Shi et al. 10.1016/j.jes.2024.02.019
23 citations as recorded by crossref.
- Atmospheric sulfate formation in the Seoul Metropolitan Area during spring/summer: Effect of trace metal ions N. Kim et al. 10.1016/j.envpol.2022.120379
- The role of source emissions in sulfate formation pathways based on chemical thermodynamics and kinetics model J. Gao et al. 10.1016/j.scitotenv.2022.158104
- Dust emission reduction enhanced gas-to-particle conversion of ammonia in the North China Plain Y. Liu et al. 10.1038/s41467-022-34733-4
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al. 10.5194/amt-16-1147-2023
- Changes in source specific PM2.5 from 2010 to 2019 in New York and New Jersey identified by dispersion normalized PMF Y. Chen et al. 10.1016/j.atmosres.2024.107353
- Weakened Gas-to-Particle Partitioning of Oxygenated Organic Molecules in Liquified Aerosol Particles W. Ma et al. 10.1021/acs.estlett.2c00556
- Characteristics of aerosol size distribution and liquid water content under ambient RH conditions in Beijing H. Dai et al. 10.1016/j.atmosenv.2022.119397
- Characterization and sources of water-soluble inorganic ions during sulfate-driven and nitrate-driven haze on the largest loess accumulation plateau W. Wang et al. 10.1016/j.chemosphere.2023.140261
- Nitrate formation and iron dissolution in the heterogeneous reactions of NH3 on nano α-Fe2O3 R. Wang et al. 10.1039/D3EN00494E
- Decade-long trends in chemical component properties of PM2.5 in Beijing, China (2011−2020) J. Wang et al. 10.1016/j.scitotenv.2022.154664
- Mechanism for the promotional formation of NH4+ by SO2 on different mineral dust surfaces H. Li et al. 10.1016/j.partic.2022.07.007
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- High contribution of anthropogenic combustion sources to atmospheric inorganic reactive nitrogen in South China evidenced by isotopes T. Li et al. 10.5194/acp-23-6395-2023
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al. 10.1029/2022JD038382
- Progressively narrow the gap of PM2.5 pollution characteristics at urban and suburban sites in a megacity of Sichuan Basin, China N. Wang et al. 10.1016/j.jes.2022.05.017
- Promoted Activity of Surface Hydroxyls on γ-Al2O3 Mineral Dust with the Coexistence of SO2 and NH3 H. Li et al. 10.1021/acs.jpclett.2c02734
- Role of WSOCs and pH on Ammonium Nitrate Aerosol Efflorescence: Insights into Secondary Aerosol Formation J. Sun et al. 10.1021/acs.est.3c07603
- Combustion related ammonia promotes PM2.5 accumulation in autumn in Tianjin, China H. Xiao et al. 10.1016/j.atmosres.2022.106225
- The role of NOx in Co-occurrence of O3 and PM2.5 pollution driven by wintertime east Asian monsoon in Hainan J. Zhan et al. 10.1016/j.jenvman.2023.118645
- Exploring the formation mechanism of fine particles in an ex-heavily polluted Northwestern city, China Z. Liu et al. 10.1016/j.scitotenv.2022.161333
- Highly oxidized organic aerosols in Beijing: Possible contribution of aqueous-phase chemistry Z. Feng et al. 10.1016/j.atmosenv.2022.118971
- Impact of atmospheric O3 and NO2 on the secondary sulfates in real atmosphere K. Shi et al. 10.1016/j.jes.2024.02.019
Latest update: 25 Apr 2024
Short summary
The mechanisms and kinetics of particulate sulfate formation in the atmosphere are still open questions although they have been extensively discussed. We found that uptake of SO2 is the rate-determining step for the conversion of SO2 to particulate sulfate. NH4NO3 plays an important role in AWC, the phase state of aerosol particles, and subsequently the uptake kinetics of SO2 under high-RH conditions. This work is a good example of the feedback between aerosol physics and aerosol chemistry.
The mechanisms and kinetics of particulate sulfate formation in the atmosphere are still open...
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