Articles | Volume 21, issue 17
https://doi.org/10.5194/acp-21-13269-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-13269-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Ammonium nitrate promotes sulfate formation through uptake kinetic regime
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
College of Chemistry and Chemical Engineering, China West Normal
University, Nanchong, 637002, China
Zemin Feng
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Feixue Zheng
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Xiaolei Bao
CORRESPONDING AUTHOR
Hebei Provincial Academy of Environmental Sciences, Shijiazhuang, 050037,
China
Hebei Chemical & Pharmaceutical College, Shijiazhuang, 050026, China
Pengfei Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Yanli Ge
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Yan Zhao
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Tao Jiang
Hebei Provincial Meteorological Technical Equipment Center, Shijiazhuang,
050021, China
Yunwen Liao
College of Chemistry and Chemical Engineering, China West Normal
University, Nanchong, 637002, China
Yusheng Zhang
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Xiaolong Fan
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Yonghong Wang
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Jing Cai
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Federico Bianchi
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Tuukka Petäjä
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
Joint International Research Laboratory of Atmospheric and Earth System
Sciences (JirLATEST), University of Helsinki and Nanjing University, Nanjing
210023, China
Yujing Mu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing, 100085, China
Markku Kulmala
Aerosol and Haze Laboratory, Advanced Innovation Center for Soft Matter
Science and Engineering, Beijing University of Chemical Technology, Beijing,
100029, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of
Science, University of Helsinki, P.O. Box 64, 00014, Finland
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- Mechanism for the promotional formation of NH4+ by SO2 on different mineral dust surfaces H. Li et al. 10.1016/j.partic.2022.07.007
- Strategic control of combustion-induced ammonia emissions: A key initiative for substantial PM2.5 reduction in Tianjin, North China Plain H. Xiao et al. 10.1016/j.scitotenv.2024.172328
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Latest update: 11 Dec 2024
Short summary
The mechanisms and kinetics of particulate sulfate formation in the atmosphere are still open questions although they have been extensively discussed. We found that uptake of SO2 is the rate-determining step for the conversion of SO2 to particulate sulfate. NH4NO3 plays an important role in AWC, the phase state of aerosol particles, and subsequently the uptake kinetics of SO2 under high-RH conditions. This work is a good example of the feedback between aerosol physics and aerosol chemistry.
The mechanisms and kinetics of particulate sulfate formation in the atmosphere are still open...
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