Articles | Volume 21, issue 16
https://doi.org/10.5194/acp-21-12665-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-12665-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Aug 2021
Research article |
| 26 Aug 2021
| 26 Aug 2021
Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields
Luisa Hantschke
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Anna Novelli
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Changmin Cho
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
David Reimer
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Marvin Glowania
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
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Cited
10 citations as recorded by crossref.
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. 10.1039/D3EA00128H
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. 10.5194/acp-22-8497-2022
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. 10.5194/acp-23-10809-2023
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- The Chemical Landscape of Leaf Surfaces and Its Interaction with the Atmosphere R. Ossola & D. Farmer 10.1021/acs.chemrev.3c00763
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Pathways to Highly Oxidized Products in the Δ3-Carene + OH System E. D’Ambro et al. 10.1021/acs.est.1c06949
- Effects of isoprene on the ozonolysis of Δ3-carene and β-caryophyllene: Mechanisms of secondary organic aerosol formation and cross-dimerization Z. Zhang et al. 10.1016/j.jes.2023.11.024
10 citations as recorded by crossref.
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. 10.5194/acp-24-9459-2024
- The effect of temperature and relative humidity on secondary organic aerosol formation from ozonolysis of Δ3-carene D. Thomsen et al. 10.1039/D3EA00128H
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. 10.5194/acp-22-8497-2022
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. 10.5194/acp-23-10809-2023
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- The Chemical Landscape of Leaf Surfaces and Its Interaction with the Atmosphere R. Ossola & D. Farmer 10.1021/acs.chemrev.3c00763
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Pathways to Highly Oxidized Products in the Δ3-Carene + OH System E. D’Ambro et al. 10.1021/acs.est.1c06949
- Effects of isoprene on the ozonolysis of Δ3-carene and β-caryophyllene: Mechanisms of secondary organic aerosol formation and cross-dimerization Z. Zhang et al. 10.1016/j.jes.2023.11.024
Latest update: 13 Dec 2024
Short summary
The reactions of Δ3-carene with ozone and the hydroxyl radical (OH) and the photolysis and OH reaction of caronaldehyde were investigated in the simulation chamber SAPHIR. Reaction rate constants of these reactions were determined. Caronaldehyde yields of the ozonolysis and OH reaction were determined. The organic nitrate yield of the reaction of Δ3-carene and caronaldehyde-derived peroxy radicals with NO was determined. The ROx budget (ROx = OH+HO2+RO2) was also investigated.
The reactions of Δ3-carene with ozone and the hydroxyl radical (OH) and the photolysis and OH...
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