Articles | Volume 21, issue 15
https://doi.org/10.5194/acp-21-12005-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-12005-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
11 Aug 2021
Research article |
| 11 Aug 2021
| 11 Aug 2021
Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NOx conditions
Xi Cheng
State Key Joint Laboratory of Environmental Simulation and Pollution Control, BIC-ESAT and IJRC, College of Environmental Sciences and Engineering, Peking University, Beijing, China
State Key Joint Laboratory of Environmental Simulation and Pollution Control, BIC-ESAT and IJRC, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Yong Jie Li
CORRESPONDING AUTHOR
Department of Civil and Environmental Engineering, Faculty of Science and Technology, University of Macau, Taipa, Macau SAR, China
Yan Zheng
State Key Joint Laboratory of Environmental Simulation and Pollution Control, BIC-ESAT and IJRC, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Keren Liao
State Key Joint Laboratory of Environmental Simulation and Pollution Control, BIC-ESAT and IJRC, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Guancong Huang
State Key Joint Laboratory of Environmental Simulation and Pollution Control, BIC-ESAT and IJRC, College of Environmental Sciences and Engineering, Peking University, Beijing, China
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Cited
21 citations as recorded by crossref.
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- The formation mechanism of highly oxygenated organic molecules produced by toluene in the urban atmosphere Z. Dong et al. 10.1016/j.atmosenv.2022.119555
- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al. 10.1016/j.envpol.2022.120684
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al. 10.1016/j.scitotenv.2024.170836
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Insufficient Condensable Organic Vapors Lead to Slow Growth of New Particles in an Urban Environment X. Li et al. 10.1021/acs.est.2c01566
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al. 10.1021/acs.est.1c08794
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- Photoinduced release of odorous volatile organic compounds from aqueous pollutants: The role of reactive oxygen species in increasing risk during cross-media transformation J. Lin et al. 10.1016/j.scitotenv.2022.153397
- The Explainable Potential of Coupling Metaheuristics-Optimized-XGBoost and SHAP in Revealing VOCs’ Environmental Fate L. Jovanovic et al. 10.3390/atmos14010109
- Revealing the sources and sinks of negative cluster ions in an urban environment through quantitative analysis R. Yin et al. 10.5194/acp-23-5279-2023
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Combined Smog Chamber/Oxidation Flow Reactor Study on Aging of Secondary Organic Aerosol from Photooxidation of Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.3c04089
- Marine biogenic emissions of benzene and toluene and their contribution to secondary organic aerosols over the polar oceans C. Wohl et al. 10.1126/sciadv.add9031
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Characterization of products formed from the oxidation of toluene and m-xylene with varying NOx and OH exposure D. Srivastava et al. 10.1016/j.chemosphere.2023.139002
21 citations as recorded by crossref.
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- The formation mechanism of highly oxygenated organic molecules produced by toluene in the urban atmosphere Z. Dong et al. 10.1016/j.atmosenv.2022.119555
- Investigation into the differences and relationships between gasSOA and aqSOA in winter haze pollution on Chongming Island, Shanghai, based on VOCs observation F. Wang et al. 10.1016/j.envpol.2022.120684
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al. 10.1016/j.scitotenv.2024.170836
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Insufficient Condensable Organic Vapors Lead to Slow Growth of New Particles in an Urban Environment X. Li et al. 10.1021/acs.est.2c01566
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Nitrogen-Containing Compounds Enhance Light Absorption of Aromatic-Derived Brown Carbon Z. Yang et al. 10.1021/acs.est.1c08794
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Precursors and Pathways Leading to Enhanced Secondary Organic Aerosol Formation during Severe Haze Episodes Y. Zheng et al. 10.1021/acs.est.1c04255
- Photoinduced release of odorous volatile organic compounds from aqueous pollutants: The role of reactive oxygen species in increasing risk during cross-media transformation J. Lin et al. 10.1016/j.scitotenv.2022.153397
- The Explainable Potential of Coupling Metaheuristics-Optimized-XGBoost and SHAP in Revealing VOCs’ Environmental Fate L. Jovanovic et al. 10.3390/atmos14010109
- Revealing the sources and sinks of negative cluster ions in an urban environment through quantitative analysis R. Yin et al. 10.5194/acp-23-5279-2023
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Combined Smog Chamber/Oxidation Flow Reactor Study on Aging of Secondary Organic Aerosol from Photooxidation of Aromatic Hydrocarbons T. Chen et al. 10.1021/acs.est.3c04089
- Marine biogenic emissions of benzene and toluene and their contribution to secondary organic aerosols over the polar oceans C. Wohl et al. 10.1126/sciadv.add9031
- Molecular Characterization of Oxygenated Organic Molecules and Their Dominating Roles in Particle Growth in Hong Kong P. Zheng et al. 10.1021/acs.est.2c09252
- Contribution of Organic Nitrates to Organic Aerosol over South Korea during KORUS-AQ H. Kenagy et al. 10.1021/acs.est.1c05521
- Characterization of products formed from the oxidation of toluene and m-xylene with varying NOx and OH exposure D. Srivastava et al. 10.1016/j.chemosphere.2023.139002
Latest update: 25 Apr 2024
Short summary
In this study, we conducted laboratory studies to investigate the formation of gas-phase highly oxygenated organic molecules (HOMs). We provide a thorough analysis on the importance of multistep auto-oxidation and multigeneration OH reactions. We also give an intensive investigation on the roles of high-NO2 conditions that represent a wide range of anthropogenically influenced environments.
In this study, we conducted laboratory studies to investigate the formation of gas-phase highly...
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