Articles | Volume 21, issue 13
https://doi.org/10.5194/acp-21-10477-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-10477-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report
| 
13 Jul 2021
Measurement report |
| 13 Jul 2021
| 13 Jul 2021
Measurement report: Nitrogen isotopes (δ15N) and first quantification of oxygen isotope anomalies (Δ17O, δ18O) in atmospheric nitrogen dioxide
Sarah Albertin
CORRESPONDING AUTHOR
LATMOS/IPSL, Sorbonne Université, UVSQ, CNRS, 75005 Paris,
France
IGE, Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, 38000
Grenoble, France
Joël Savarino
IGE, Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, 38000
Grenoble, France
Slimane Bekki
LATMOS/IPSL, Sorbonne Université, UVSQ, CNRS, 75005 Paris,
France
Albane Barbero
IGE, Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, 38000
Grenoble, France
Nicolas Caillon
IGE, Univ. Grenoble Alpes, CNRS, IRD, Grenoble INP, 38000
Grenoble, France
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Cited
17 citations as recorded by crossref.
- Mass-independent fractionation of oxygen and sulfur isotopes M. LIN 10.3724/j.issn.1007-2802.20240026
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- Low blank sampling method for measurement of the nitrogen isotopic composition of atmospheric NOx K. Kamezaki et al. 10.1371/journal.pone.0298539
- Nitrogen isotope signatures of oxidized nitrogen species from biomass burning W. Song & X. Liu 10.1016/j.apgeochem.2023.105569
- 40 years of theoretical advances in mass-independent oxygen isotope effects and applications in atmospheric chemistry: A critical review and perspectives M. Lin & M. Thiemens 10.1016/j.apgeochem.2023.105860
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
- Isotopic Evidence for the High Contribution of Wintertime Photochemistry to Particulate Nitrate Formation in Northern China Z. Zhang et al. 10.1029/2021JD035324
- Dominant Contribution of NO3 Radical to NO3– Formation during Heavy Haze Episodes: Insights from High-Time Resolution of Dual Isotopes Δ17O and δ18O X. Feng et al. 10.1021/acs.est.3c07590
- Formation pathways and sources of size-segregated nitrate aerosols in a megacity identified by dual isotopes Y. Zhu et al. 10.1016/j.atmosenv.2021.118708
- Comparative contributions of primary emission and secondary production of HONO from unfertilized soil in Eastern China M. Fan et al. 10.1016/j.horiz.2025.100136
- Fast and Efficient Atmospheric NO2 Collection for Isotopic Analysis by a 3D-Printed Denuder System T. Zhou et al. 10.1021/acs.analchem.2c02839
- Triple oxygen stable isotope analysis of nitrite measured using continuous flow isotope ratio mass spectrometry W. Walters & M. Hastings 10.1016/j.mex.2023.102413
- Modeling the Oxygen Isotope Anomaly (Δ17O) of Reactive Nitrogen in the Community Multiscale Air Quality Model: Insights into Nitrogen Oxide Chemistry in the Northeastern United States W. Walters et al. 10.1021/acsestair.3c00056
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- High-Resolution Measurements of Multi-Isotopic Signatures (δ15N, δ18O, and Δ17O) of Winter NO2 in a Megacity in Central China Z. Zhang et al. 10.1021/acs.est.4c07724
17 citations as recorded by crossref.
- Mass-independent fractionation of oxygen and sulfur isotopes M. LIN 10.3724/j.issn.1007-2802.20240026
- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- Low blank sampling method for measurement of the nitrogen isotopic composition of atmospheric NOx K. Kamezaki et al. 10.1371/journal.pone.0298539
- Nitrogen isotope signatures of oxidized nitrogen species from biomass burning W. Song & X. Liu 10.1016/j.apgeochem.2023.105569
- 40 years of theoretical advances in mass-independent oxygen isotope effects and applications in atmospheric chemistry: A critical review and perspectives M. Lin & M. Thiemens 10.1016/j.apgeochem.2023.105860
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
- Isotopic Evidence for the High Contribution of Wintertime Photochemistry to Particulate Nitrate Formation in Northern China Z. Zhang et al. 10.1029/2021JD035324
- Dominant Contribution of NO3 Radical to NO3– Formation during Heavy Haze Episodes: Insights from High-Time Resolution of Dual Isotopes Δ17O and δ18O X. Feng et al. 10.1021/acs.est.3c07590
- Formation pathways and sources of size-segregated nitrate aerosols in a megacity identified by dual isotopes Y. Zhu et al. 10.1016/j.atmosenv.2021.118708
- Comparative contributions of primary emission and secondary production of HONO from unfertilized soil in Eastern China M. Fan et al. 10.1016/j.horiz.2025.100136
- Fast and Efficient Atmospheric NO2 Collection for Isotopic Analysis by a 3D-Printed Denuder System T. Zhou et al. 10.1021/acs.analchem.2c02839
- Triple oxygen stable isotope analysis of nitrite measured using continuous flow isotope ratio mass spectrometry W. Walters & M. Hastings 10.1016/j.mex.2023.102413
- Modeling the Oxygen Isotope Anomaly (Δ17O) of Reactive Nitrogen in the Community Multiscale Air Quality Model: Insights into Nitrogen Oxide Chemistry in the Northeastern United States W. Walters et al. 10.1021/acsestair.3c00056
- A diurnal story of Δ17O($$\rm{NO}_{3}^{-}$$) in urban Nanjing and its implication for nitrate aerosol formation Y. Zhang et al. 10.1038/s41612-022-00273-3
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- High-Resolution Measurements of Multi-Isotopic Signatures (δ15N, δ18O, and Δ17O) of Winter NO2 in a Megacity in Central China Z. Zhang et al. 10.1021/acs.est.4c07724
Latest update: 29 May 2025
Short summary
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and...
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