Articles | Volume 20, issue 16
https://doi.org/10.5194/acp-20-9783-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-9783-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation
Archit Mehra
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, United Kingdom
Yuwei Wang
Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Jiangwan Campus, Fudan University, Shanghai, China
Jordan E. Krechmer
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Andrew Lambe
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Francesca Majluf
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Melissa A. Morris
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
now at: Department of Chemistry, University of Colorado Boulder, Boulder, Colorado, USA
Michael Priestley
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, United Kingdom
now at: Department of Chemistry and Molecular Biology, University of Gothenburg, Gothenburg, Sweden
Thomas J. Bannan
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, United Kingdom
Daniel J. Bryant
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, United Kingdom
Kelly L. Pereira
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, United Kingdom
Jacqueline F. Hamilton
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, United Kingdom
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, United Kingdom
National Centre for Atmospheric Science (NCAS), University of York, York, United Kingdom
Mike J. Newland
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, United Kingdom
Harald Stark
Department of Chemistry, University of Colorado Boulder, Boulder, Colorado, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado Boulder, Boulder, Colorado, USA
Philip Croteau
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
John T. Jayne
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Douglas R. Worsnop
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Manjula R. Canagaratna
Center for Aerosol and Cloud Chemistry, Aerodyne Research, Inc., Billerica, Massachusetts, USA
Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Jiangwan Campus, Fudan University, Shanghai, China
Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention (LAP3), Department of Environmental Science and Engineering, Jiangwan Campus, Fudan University, Shanghai, China
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, United Kingdom
Viewed
Total article views: 6,501 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Mar 2020)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
5,023 | 1,408 | 70 | 6,501 | 564 | 60 | 129 |
- HTML: 5,023
- PDF: 1,408
- XML: 70
- Total: 6,501
- Supplement: 564
- BibTeX: 60
- EndNote: 129
Total article views: 5,363 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 21 Aug 2020)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
4,356 | 952 | 55 | 5,363 | 363 | 47 | 110 |
- HTML: 4,356
- PDF: 952
- XML: 55
- Total: 5,363
- Supplement: 363
- BibTeX: 47
- EndNote: 110
Total article views: 1,138 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Mar 2020)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
667 | 456 | 15 | 1,138 | 201 | 13 | 19 |
- HTML: 667
- PDF: 456
- XML: 15
- Total: 1,138
- Supplement: 201
- BibTeX: 13
- EndNote: 19
Viewed (geographical distribution)
Total article views: 6,501 (including HTML, PDF, and XML)
Thereof 6,352 with geography defined
and 149 with unknown origin.
Total article views: 5,363 (including HTML, PDF, and XML)
Thereof 5,368 with geography defined
and -5 with unknown origin.
Total article views: 1,138 (including HTML, PDF, and XML)
Thereof 984 with geography defined
and 154 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
40 citations as recorded by crossref.
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Molecular characterization of oxidized organic nitrogen in the polluted urban atmosphere of Beijing L. Liu et al. 10.1016/j.scitotenv.2024.177109
- Controlled reduction of aromaticity of alkylated polyaromatic compounds by selective oxidation using H2WO4, H3PO4 and H2O2: a route for upgrading heavy oil fractions E. Nowicka et al. 10.1039/D1NJ01986D
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Low-NO-like Oxidation Pathway Makes a Significant Contribution to Secondary Organic Aerosol in Polluted Urban Air C. Ye et al. 10.1021/acs.est.3c01055
- A Scheme for Representing Aromatic Secondary Organic Aerosols in Chemical Transport Models: Application to Source Attribution of Organic Aerosols Over South Korea During the KORUS‐AQ Campaign J. Brewer et al. 10.1029/2022JD037257
- Composition of Ultrafine Particles in Urban Beijing: Measurement Using a Thermal Desorption Chemical Ionization Mass Spectrometer X. Li et al. 10.1021/acs.est.0c06053
- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- SO<sub>2</sub> and NH<sub>3</sub> emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al. 10.5194/acp-21-7963-2021
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Insights into the Peroxide-Bicyclic Intermediate Pathway of Aromatic Photooxidation: Experimental Yields and NOx-Dependency of Ring-Opening and Ring-Retaining Products S. He et al. 10.1021/acs.est.3c05304
- Oxidation Flow Reactor Results in a Chinese Megacity Emphasize the Important Contribution of S/IVOCs to Ambient SOA Formation W. Hu et al. 10.1021/acs.est.1c03155
- Effect of NOx and RH on the secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.1016/j.jes.2021.06.017
- Gas-particle partitioning process contributes more to nitrate dominated air pollution than oxidation process in northern China X. Tian et al. 10.1080/02786826.2023.2294944
- Quantification of solid fuel combustion and aqueous chemistry contributions to secondary organic aerosol during wintertime haze events in Beijing Y. Tong et al. 10.5194/acp-21-9859-2021
- Direct observation of the particle-phase bicyclic products from OH-initiated oxidation of 1,3,5-trimethylbenzene under NOx-free conditions X. Lin et al. 10.1016/j.atmosenv.2021.118914
- Study of secondary organic aerosol formation and aging using ambient air in an oxidation flow reactor during high pollution events over Delhi V. Goel et al. 10.1016/j.envres.2024.118542
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
- Highly time-resolved chemical speciation and source apportionment of organic aerosol components in Delhi, India, using extractive electrospray ionization mass spectrometry V. Kumar et al. 10.5194/acp-22-7739-2022
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. 10.5194/acp-24-7961-2024
- Substantial contribution of transported emissions to organic aerosol in Beijing K. Daellenbach et al. 10.1038/s41561-024-01493-3
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Time-Resolved Molecular Characterization of Secondary Organic Aerosol Formed from OH and NO3Radical Initiated Oxidation of a Mixture of Aromatic Precursors V. Kumar et al. 10.1021/acs.est.3c00225
- Quantifying New Sources of Ambient Organic Aerosol and Their Roles in Particle Growth Using Oxygenated Organic Molecule (OOM) Tracers Y. Zhao et al. 10.1021/acs.estlett.4c00536
- Secondary organic aerosol formed by condensing anthropogenic vapours over China’s megacities W. Nie et al. 10.1038/s41561-022-00922-5
- Precursor apportionment of atmospheric oxygenated organic molecules using a machine learning method X. Qiao et al. 10.1039/D2EA00128D
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- The formation mechanism of highly oxygenated organic molecules produced by toluene in the urban atmosphere Z. Dong et al. 10.1016/j.atmosenv.2022.119555
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- In-situ synthesis of Z-Scheme MIL-100(Fe)/α-Fe2O3 heterojunction for enhanced adsorption and Visible-light photocatalytic oxidation of O-xylene L. Chen et al. 10.1016/j.cej.2021.129112
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
40 citations as recorded by crossref.
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Molecular characterization of oxidized organic nitrogen in the polluted urban atmosphere of Beijing L. Liu et al. 10.1016/j.scitotenv.2024.177109
- Controlled reduction of aromaticity of alkylated polyaromatic compounds by selective oxidation using H2WO4, H3PO4 and H2O2: a route for upgrading heavy oil fractions E. Nowicka et al. 10.1039/D1NJ01986D
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Low-NO-like Oxidation Pathway Makes a Significant Contribution to Secondary Organic Aerosol in Polluted Urban Air C. Ye et al. 10.1021/acs.est.3c01055
- A Scheme for Representing Aromatic Secondary Organic Aerosols in Chemical Transport Models: Application to Source Attribution of Organic Aerosols Over South Korea During the KORUS‐AQ Campaign J. Brewer et al. 10.1029/2022JD037257
- Composition of Ultrafine Particles in Urban Beijing: Measurement Using a Thermal Desorption Chemical Ionization Mass Spectrometer X. Li et al. 10.1021/acs.est.0c06053
- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- SO<sub>2</sub> and NH<sub>3</sub> emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al. 10.5194/acp-21-7963-2021
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Insights into the Peroxide-Bicyclic Intermediate Pathway of Aromatic Photooxidation: Experimental Yields and NOx-Dependency of Ring-Opening and Ring-Retaining Products S. He et al. 10.1021/acs.est.3c05304
- Oxidation Flow Reactor Results in a Chinese Megacity Emphasize the Important Contribution of S/IVOCs to Ambient SOA Formation W. Hu et al. 10.1021/acs.est.1c03155
- Effect of NOx and RH on the secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.1016/j.jes.2021.06.017
- Gas-particle partitioning process contributes more to nitrate dominated air pollution than oxidation process in northern China X. Tian et al. 10.1080/02786826.2023.2294944
- Quantification of solid fuel combustion and aqueous chemistry contributions to secondary organic aerosol during wintertime haze events in Beijing Y. Tong et al. 10.5194/acp-21-9859-2021
- Direct observation of the particle-phase bicyclic products from OH-initiated oxidation of 1,3,5-trimethylbenzene under NOx-free conditions X. Lin et al. 10.1016/j.atmosenv.2021.118914
- Study of secondary organic aerosol formation and aging using ambient air in an oxidation flow reactor during high pollution events over Delhi V. Goel et al. 10.1016/j.envres.2024.118542
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. 10.1039/D1EM00409C
- Highly time-resolved chemical speciation and source apportionment of organic aerosol components in Delhi, India, using extractive electrospray ionization mass spectrometry V. Kumar et al. 10.5194/acp-22-7739-2022
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. 10.5194/acp-24-7961-2024
- Substantial contribution of transported emissions to organic aerosol in Beijing K. Daellenbach et al. 10.1038/s41561-024-01493-3
- Secondary organic aerosol formation from mixed volatile organic compounds: Effect of RO2 chemistry and precursor concentration T. Chen et al. 10.1038/s41612-022-00321-y
- Time-Resolved Molecular Characterization of Secondary Organic Aerosol Formed from OH and NO3Radical Initiated Oxidation of a Mixture of Aromatic Precursors V. Kumar et al. 10.1021/acs.est.3c00225
- Quantifying New Sources of Ambient Organic Aerosol and Their Roles in Particle Growth Using Oxygenated Organic Molecule (OOM) Tracers Y. Zhao et al. 10.1021/acs.estlett.4c00536
- Secondary organic aerosol formed by condensing anthropogenic vapours over China’s megacities W. Nie et al. 10.1038/s41561-022-00922-5
- Precursor apportionment of atmospheric oxygenated organic molecules using a machine learning method X. Qiao et al. 10.1039/D2EA00128D
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- The formation mechanism of highly oxygenated organic molecules produced by toluene in the urban atmosphere Z. Dong et al. 10.1016/j.atmosenv.2022.119555
- Chemical characterisation of benzene oxidation products under high- and low-NO<sub><i>x</i></sub> conditions using chemical ionisation mass spectrometry M. Priestley et al. 10.5194/acp-21-3473-2021
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- In-situ synthesis of Z-Scheme MIL-100(Fe)/α-Fe2O3 heterojunction for enhanced adsorption and Visible-light photocatalytic oxidation of O-xylene L. Chen et al. 10.1016/j.cej.2021.129112
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NO<sub><i>x</i></sub> conditions X. Cheng et al. 10.5194/acp-21-12005-2021
Latest update: 13 Dec 2024
Short summary
Aromatic volatile organic compounds (VOCs) emitted from anthropogenic activity are important for tropospheric ozone and secondary organic aerosol (SOA) formation. Here we present a detailed chemical characterisation of SOA from four C9-aromatic isomers and a polycyclic aromatic hydrocarbon (PAH). We identify and compare their oxidation products in the gas and particle phases, showing the different relative importance of oxidation pathways and proportions of highly oxygenated organic molecules.
Aromatic volatile organic compounds (VOCs) emitted from anthropogenic activity are important for...
Altmetrics
Final-revised paper
Preprint