Atmospheric fate of two relevant unsaturated ketoethers: kinetics, products and mechanisms for the reaction of hydroxyl radicals with (E)-4-methoxy-3-buten-2-one and (1E)-1-methoxy-2-methyl-1-penten-3-one
Rodrigo Gastón Gibilisco,Ian Barnes,Iustinian Gabriel Bejan,and Peter Wiesen
Faculty of Chemistry, Department of Chemistry, Alexandru Ioan Cuza University of Iasi, 11 Carol I, Iasi 700506, Romania
Integrated Centre of Environmental Science Studies in the North Eastern Region, Alexandru Ioan Cuza University of Iasi, 11 Carol I, Iasi 700506, Romania
Peter Wiesen
Institute for Atmospheric and Environmental Research, Bergische Universität Wuppertal, 42097 Wuppertal, Germany
Viewed
Total article views: 2,676 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
1,779
827
70
2,676
335
94
113
HTML: 1,779
PDF: 827
XML: 70
Total: 2,676
Supplement: 335
BibTeX: 94
EndNote: 113
Views and downloads (calculated since 13 Feb 2020)
Cumulative views and downloads
(calculated since 13 Feb 2020)
Total article views: 2,230 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
1,610
562
58
2,230
172
78
99
HTML: 1,610
PDF: 562
XML: 58
Total: 2,230
Supplement: 172
BibTeX: 78
EndNote: 99
Views and downloads (calculated since 29 Jul 2020)
Cumulative views and downloads
(calculated since 29 Jul 2020)
Total article views: 446 (including HTML, PDF, and XML)
HTML
PDF
XML
Total
Supplement
BibTeX
EndNote
169
265
12
446
163
16
14
HTML: 169
PDF: 265
XML: 12
Total: 446
Supplement: 163
BibTeX: 16
EndNote: 14
Views and downloads (calculated since 13 Feb 2020)
Cumulative views and downloads
(calculated since 13 Feb 2020)
Viewed (geographical distribution)
Total article views: 2,676 (including HTML, PDF, and XML)
Thereof 2,676 with geography defined
and 0 with unknown origin.
Total article views: 2,230 (including HTML, PDF, and XML)
Thereof 2,199 with geography defined
and 31 with unknown origin.
Total article views: 446 (including HTML, PDF, and XML)
Thereof 446 with geography defined
and 0 with unknown origin.
Environmental chamber studies were performed to evaluate atmospheric degradation initiated by OH radicals for two unsaturated methoxy ketones. The main gas-phase oxidation products identified and quantified from these reactions are carbonyls and long-lived nitrogen-containing compounds such as peroxyacetyl nitrate and peroxypropionyl nitrate. The kinetic rate constants and atmospheric lifetimes were estimated, degradation mechanisms were developed, and atmospheric implications were assessed.
Environmental chamber studies were performed to evaluate atmospheric degradation initiated by OH...
