Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-8123-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-8123-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
13 Jul 2020
Research article |
| 13 Jul 2020
| 13 Jul 2020
Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from n-dodecane
Junling Li
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, P. R. China
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Air Quality Research Division, Environment and Climate Change Canada, Toronto, Ontario M3H5T4, Canada
now at: Laboratory of Atmospheric Chemistry, Paul Scherrer Institute (PSI), 5232 Villigen, Switzerland
Wenyu Zhang
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Chao Peng
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Li Zhou
College of Architecture and Environment, Sichuan University, Chengdu, P. R. China
Bo Shi
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Yan Chen
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Mingyuan Liu
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Hong Li
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences, Beijing 100012, P. R. China
State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
University of Chinese Academy of Sciences, Beijing 100049, P. R. China
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen, 361021, P. R. China
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26 citations as recorded by crossref.
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- Modeling SOA Formation from Monocyclic, Bicyclic, and Branched-Cyclic Alkanes A. Madhu & M. Jang https://doi.org/10.1021/acsearthspacechem.4c00380
- Modeling the influence of chain length on secondary organic aerosol (SOA) formation via multiphase reactions of alkanes A. Madhu et al. https://doi.org/10.5194/acp-23-1661-2023
- A New Type of Quartz Smog Chamber: Design and Characterization W. Ma et al. https://doi.org/10.1021/acs.est.1c06341
- Modeling the influence of carbon branching structure on secondary organic aerosol formation via multiphase reactions of alkanes A. Madhu et al. https://doi.org/10.5194/acp-24-5585-2024
- Measurement report: Analysis of aerosol optical depth variation at Zhongshan Station in Antarctica L. Chen et al. https://doi.org/10.5194/acp-25-727-2025
- Measurement and Modeling of Ship-Related Ultrafine Particles and Secondary Organic Aerosols in a Mediterranean Port City M. Karl et al. https://doi.org/10.3390/toxics11090771
- Impact of temperature on optical sensing in biology based on investigation of SARS‐CoV‐2 M. Szczerska et al. https://doi.org/10.1002/jbio.202200186
- Enhanced continuous aerosol optical depth (AOD) estimation using geostationary satellite data: focusing on nighttime AOD over East Asia S. Song et al. https://doi.org/10.1016/j.atmosenv.2025.121365
- Fluorescent Poly(ε-Caprolactone)s Micelles for Anticancer Drug Delivery and Bioimaging G. Babanyinah et al. https://doi.org/10.1021/acs.biomac.5c00262
- Enhanced secondary organic aerosol formation from the photo-oxidation of mixed anthropogenic volatile organic compounds J. Li et al. https://doi.org/10.5194/acp-21-7773-2021
- Regional-specific trends of PM2.5 and O3 temperature sensitivity in the United States L. Yin et al. https://doi.org/10.1038/s41612-024-00862-4
- Long-chain alkanes in the atmosphere: A review J. Li et al. https://doi.org/10.1016/j.jes.2021.07.021
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. https://doi.org/10.1038/s41612-022-00238-6
- Important Oxidants and Their Impact on the Environmental Effects of Aerosols M. Ge et al. https://doi.org/10.1021/acs.jpca.0c10236
- Effects of OH radical and SO2 concentrations on photochemical reactions of mixed anthropogenic organic gases J. Li et al. https://doi.org/10.5194/acp-22-10489-2022
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. https://doi.org/10.1016/j.jes.2022.06.021
- A large-scale outdoor atmospheric simulation smog chamber for studying atmospheric photochemical processes: Characterization and preliminary application J. Li et al. https://doi.org/10.1016/j.jes.2020.09.015
- Gas–particle partitioning of m-xylene and naphthalene oxidation products: temperature and NOx influence M. Shahin et al. https://doi.org/10.5194/acp-25-10267-2025
- Exploring the Trends of Aerosol Optical Depth and Its Relationship with Climate Variables over Saudi Arabia M. Rahman et al. https://doi.org/10.1007/s41748-024-00452-7
- Effect of chemical structure on optical properties of secondary organic aerosols derived from C12 alkanes J. Li et al. https://doi.org/10.1016/j.scitotenv.2020.141620
- Temperature effects on SOA formation of n-dodecane reaction initiated by Cl atoms C. Fan et al. https://doi.org/10.1016/j.atmosenv.2025.121070
- Photochemical Aging of China VI Gasoline Vehicle Exhaust Drives Nonlinear Secondary Aerosol Formation J. Li et al. https://doi.org/10.1021/acs.est.6c00964
- A Novel AI Framework for PM Pollution Prediction Applied to a Greek Port City F. Anagnostopoulos et al. https://doi.org/10.3390/atmos14091413
- Development of the low-temperature hygroscopicity tandem differential mobility analyzer (Low-T HTDMA) and its application to (NH4)2SO4 and NaCl particles M. Cheng & M. Kuwata https://doi.org/10.1016/j.jaerosci.2022.106111
Saved (final revised paper)
Latest update: 13 Jun 2026
Short summary
Long-chain alkanes (a large fraction of diesel fuel and its exhaust) are important potential contributors of SOA. Through the analysis of the components of formed SOA, we found that low-temperature conditions promote the oligomerization of n-dodecane, and the degree of oligomerization can reach tetramerization. The presence of the oligomers enhances the light extinction of the particles. UV-scattering particles in the boundary layer can accelerate photochemical reactions and haze production.
Long-chain alkanes (a large fraction of diesel fuel and its exhaust) are important potential...
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