Articles | Volume 20, issue 2
https://doi.org/10.5194/acp-20-649-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-649-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
20 Jan 2020
Research article |
| 20 Jan 2020
| 20 Jan 2020
Experimental investigation into the volatilities of highly oxygenated organic molecules (HOMs)
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Matthieu Riva
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Univ Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON, 69626, Villeurbanne,
France
Liine Heikkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Lauriane Quéléver
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
Pontus Roldin
Division of Nuclear Physics, Lund University, P.O. Box 118, 22100 Lund, Sweden
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, Finland
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- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
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- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
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- The Response of Summertime Organic Aerosol Composition to Emission Controls in the Northeastern United States J. Zhang et al. 10.1029/2022JD037056
- Selective deuteration as a tool for resolving autoxidation mechanisms in α-pinene ozonolysis M. Meder et al. 10.5194/acp-23-4373-2023
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- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene Y. Wang et al. 10.5194/acp-20-5145-2020
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Look Up: Probing the Vertical Profile of New Particle Formation and Growth in the Planetary Boundary Layer With Models and Observations S. O’Donnell et al. 10.1029/2022JD037525
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- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
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- Recent advances on SOA formation in indoor air, fate and strategies for SOA characterization in indoor air - A review K. Pytel et al. 10.1016/j.scitotenv.2022.156948
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- Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra Y. Zhang et al. 10.5194/acp-20-5945-2020
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Anomalous Vertical Distribution of Organic Aerosol over the South of Western Siberia in September 2018 M. Arshinov et al. 10.1134/S1024856021050043
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- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- Measurement report: Effects of NOx and seed aerosol on highly oxygenated organic molecules (HOMs) from cyclohexene ozonolysis M. Räty et al. 10.5194/acp-21-7357-2021
- Condensation sink of atmospheric vapors: the effect of vapor properties and the resulting uncertainties S. Tuovinen et al. 10.1039/D1EA00032B
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
40 citations as recorded by crossref.
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Improving the Sensitivity of Fourier Transform Mass Spectrometer (Orbitrap) for Online Measurements of Atmospheric Vapors R. Cai et al. 10.1021/acs.analchem.2c03403
- Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides H. Li et al. 10.5194/amt-15-1811-2022
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from <i>α</i>-pinene ozonolysis at different temperatures K. Kristensen et al. 10.5194/acp-20-12549-2020
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
- PyCHAM (v2.1.1): a Python box model for simulating aerosol chambers S. O'Meara et al. 10.5194/gmd-14-675-2021
- The Response of Summertime Organic Aerosol Composition to Emission Controls in the Northeastern United States J. Zhang et al. 10.1029/2022JD037056
- Selective deuteration as a tool for resolving autoxidation mechanisms in α-pinene ozonolysis M. Meder et al. 10.5194/acp-23-4373-2023
- On the potential use of highly oxygenated organic molecules (HOMs) as indicators for ozone formation sensitivity J. Zhang et al. 10.5194/acp-24-2885-2024
- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene Y. Wang et al. 10.5194/acp-20-5145-2020
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Look Up: Probing the Vertical Profile of New Particle Formation and Growth in the Planetary Boundary Layer With Models and Observations S. O’Donnell et al. 10.1029/2022JD037525
- Predicting gas–particle partitioning coefficients of atmospheric molecules with machine learning E. Lumiaro et al. 10.5194/acp-21-13227-2021
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Theoretical study of the formation and nucleation mechanism of highly oxygenated multi-functional organic compounds produced by α-pinene X. Shi et al. 10.1016/j.scitotenv.2021.146422
- Recent advances on SOA formation in indoor air, fate and strategies for SOA characterization in indoor air - A review K. Pytel et al. 10.1016/j.scitotenv.2022.156948
- Indoor secondary organic aerosols: Towards an improved representation of their formation and composition in models M. Kruza et al. 10.1016/j.atmosenv.2020.117784
- Insights into atmospheric oxidation processes by performing factor analyses on subranges of mass spectra Y. Zhang et al. 10.5194/acp-20-5945-2020
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. 10.1021/acs.est.3c01162
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Anomalous Vertical Distribution of Organic Aerosol over the South of Western Siberia in September 2018 M. Arshinov et al. 10.1134/S1024856021050043
- Online measurement of highly oxygenated compounds from organic aerosol E. Häkkinen et al. 10.5194/amt-16-1705-2023
- Impact of NO<sub><i>x</i></sub> on secondary organic aerosol (SOA) formation from <i>α</i>-pinene and <i>β</i>-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al. 10.1021/acs.jpca.3c07316
- Measurement report: Effects of NOx and seed aerosol on highly oxygenated organic molecules (HOMs) from cyclohexene ozonolysis M. Räty et al. 10.5194/acp-21-7357-2021
- Condensation sink of atmospheric vapors: the effect of vapor properties and the resulting uncertainties S. Tuovinen et al. 10.1039/D1EA00032B
- Characterization of the Vaporization Inlet for Aerosols (VIA) for online measurements of particulate highly oxygenated organic molecules (HOMs) J. Zhao et al. 10.5194/amt-17-1527-2024
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
Latest update: 15 Apr 2024
Short summary
Highly oxygenated organic molecules have been suggested to form a large part of secondary organic aerosol. However, with their exotic structures, their volatilities are not well known, making their exact role in particle formation hard to assess. In laboratory experiments, we found the volatility of HOMs formed in the ozonolysis of the monoterpene alpha-pinene to be in the middle of earlier estimates. The volatilities of HOMs could be well explained in terms of their molecular formulae.
Highly oxygenated organic molecules have been suggested to form a large part of secondary...
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