Articles | Volume 20, issue 10
https://doi.org/10.5194/acp-20-5887-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-5887-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 May 2020
Research article |
| 18 May 2020
| 18 May 2020
Contribution of hydroxymethanesulfonate (HMS) to severe winter haze in the North China Plain
Tao Ma
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Hiroshi Furutani
Support Center for Scientific Instrument Renovation and Custom
Fabrication, Osaka University, Osaka, 560-0043, Japan
Project Research Center for Fundamental Sciences, Graduate School of
Science, Osaka University, Osaka, 560-0043, Japan
Fengkui Duan
CORRESPONDING AUTHOR
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Takashi Kimoto
Kimoto Electric Co., Ltd, 3-1 Funahashi-cho Tennoji-ku, Osaka
543-0024, Japan
Jingkun Jiang
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Qiang Zhang
Ministry of Education Key Laboratory for Earth System Modeling,
Department of Earth System Science, Tsinghua University, Beijing 100084,
China
Xiaobin Xu
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences,
Beijing 100081, China
Ying Wang
State Key Laboratory of Severe Weather & Key Laboratory for
Atmospheric Chemistry of CMA, Chinese Academy of Meteorological Sciences,
Beijing 100081, China
Jian Gao
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Guannan Geng
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Ministry of Education Key Laboratory for Earth System Modeling,
Department of Earth System Science, Tsinghua University, Beijing 100084,
China
Shaojie Song
School of Engineering and Applied Sciences, Harvard University,
Cambridge, MA 02138, USA
Yongliang Ma
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Fei Che
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Jie Wang
State Key Laboratory of Environmental Criteria and Risk Assessment,
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Lidan Zhu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
Tao Huang
Kimoto Electric Co., Ltd, 3-1 Funahashi-cho Tennoji-ku, Osaka
543-0024, Japan
Michisato Toyoda
Project Research Center for Fundamental Sciences, Graduate School of
Science, Osaka University, Osaka, 560-0043, Japan
Kebin He
CORRESPONDING AUTHOR
State Key Joint Laboratory of Environment Simulation and Pollution
Control, School of Environment, State Environmental Protection Key
Laboratory of Sources and Control of Air Pollution Complex, Beijing Key
Laboratory of Indoor Air Quality Evaluation and Control, Tsinghua
University, Beijing 100084, China
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Cited
44 citations as recorded by crossref.
- Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field J. Liu et al. 10.1021/acs.estlett.1c00357
- Primary Sulfate Is the Dominant Source of Particulate Sulfate during Winter in Fairbanks, Alaska A. Moon et al. 10.1021/acsestair.3c00023
- Characteristics, primary sources and secondary formation of water-soluble organic aerosols in downtown Beijing Q. Yu et al. 10.5194/acp-21-1775-2021
- Chemical and optical characterization of aqueous secondary organic aerosol generated by reaction of pyruvaldehyde with sodium sulfite M. Zhu et al. 10.1016/j.apr.2024.102124
- A critical review of sulfate aerosol formation mechanisms during winter polluted periods C. Ye et al. 10.1016/j.jes.2022.07.011
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Global modeling of heterogeneous hydroxymethanesulfonate chemistry S. Song et al. 10.5194/acp-21-457-2021
- Source and Chemistry of Hydroxymethanesulfonate (HMS) in Fairbanks, Alaska J. Campbell et al. 10.1021/acs.est.2c00410
- Global Importance of Hydroxymethanesulfonate in Ambient Particulate Matter: Implications for Air Quality J. Moch et al. 10.1029/2020JD032706
- Carbonyl Compounds Regulate Atmospheric Oxidation Capacity and Particulate Sulfur Chemistry in the Coastal Atmosphere M. Zhao et al. 10.1021/acs.est.4c03947
- Multiphase interactions between sulfur dioxide and secondary organic aerosol from the photooxidation of toluene: Reactivity and sulfate formation Q. Ye et al. 10.1016/j.scitotenv.2023.168736
- Field observations and quantifications of atmospheric formaldehyde partitioning in gaseous and particulate phases R. Xu et al. 10.1016/j.scitotenv.2021.152122
- Real-Time Single-Particle Characteristics and Aging of Cooking Aerosols in Urban Beijing T. Ma et al. 10.1021/acs.estlett.3c00053
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Improving the representation of HONO chemistry in CMAQ and examining its impact on haze over China S. Zhang et al. 10.5194/acp-21-15809-2021
- Detailed NMR analysis of water-soluble organic compounds in size-resolved particulate matter seasonally collected at a suburban site in Prague Š. Horník et al. 10.1016/j.atmosenv.2021.118757
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al. 10.1021/acs.est.0c06496
- Characteristics of volatile organic compounds (VOCs) based on multisite observations in Hebei province in the warm season in 2019 Z. Wang et al. 10.1016/j.atmosenv.2021.118435
- Exploring the amplified role of HCHO in the formation of HMS and O3 during the co-occurring PM2.5 and O3 pollution in a coastal city of southeast China Y. Hong et al. 10.5194/acp-23-10795-2023
- Positive matrix factorization of seasonally resolved organic aerosol at three different central European background sites based on nuclear magnetic resonance Aerosolomics data Š. Horník et al. 10.1016/j.scitotenv.2024.170303
- Hydroxymethanesulfonate formation as a significant pathway of transformation of SO2 H. Zhang et al. 10.1016/j.atmosenv.2022.119474
- Identification of O3 Sensitivity to Secondary HCHO and NO2 Measured by MAX-DOAS in Four Cities in China C. Lu et al. 10.3390/rs16040662
- Enhanced aqueous formation and neutralization of fine atmospheric particles driven by extreme cold J. Campbell et al. 10.1126/sciadv.ado4373
- The importance of hydroxymethanesulfonate (HMS) in winter haze episodes in North China Plain C. Chen et al. 10.1016/j.envres.2022.113093
- Model Simulations and Predictions of Hydroxymethanesulfonate (HMS) in the Beijing-Tianjin-Hebei Region, China: Roles of Aqueous Aerosols and Atmospheric Acidity H. Wang et al. 10.1021/acs.est.3c07306
- A comprehensive observation-based multiphase chemical model analysis of sulfur dioxide oxidations in both summer and winter H. Song et al. 10.5194/acp-21-13713-2021
- Characterization of haze pollution in Zibo, China: Temporal series, secondary species formation, and PMx distribution H. Li et al. 10.1016/j.chemosphere.2021.131807
- Existence of hydroxymethanesulfonate (HMS) during spring haze and sandstorm events in Beijing: Implications for a heterogeneous formation pathway on mineral aerosols Y. Xu et al. 10.1016/j.envpol.2024.125483
- Unbalanced emission reductions and adverse meteorological conditions facilitate the formation of secondary pollutants during the COVID-19 lockdown in Beijing T. Ma et al. 10.1016/j.scitotenv.2022.155970
- Positive Feedback between Partitioning of Carbonyl Compounds and Particulate Sulfur Formation during Haze Episodes H. Shen et al. 10.1021/acs.est.4c07278
- Hygroscopicity and cloud condensation nucleation activities of hydroxyalkylsulfonates C. Peng et al. 10.1016/j.scitotenv.2022.154767
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- Hydroxymethanesulfonate and Sulfur(IV) in Fairbanks Winter During the ALPACA Study K. Dingilian et al. 10.1021/acsestair.4c00012
- Universal ion chromatography method for anions in active pharmaceutical ingredients enabled by computer-assisted separation modeling T. Yuan et al. 10.1016/j.jpba.2023.115923
- Effect of NOX, O3 and NH3 on sulfur isotope composition during heterogeneous oxidation of SO2: a laboratory investigation Z. Guo et al. 10.1007/s11869-024-01543-0
- Trace Metals Reveal Significant Contribution of Coal Combustion to Winter Haze Pollution in Northern China H. Shen et al. 10.1021/acsestair.4c00050
- Sulfate Formation Apportionment during Winter Haze Events in North China T. Wang et al. 10.1021/acs.est.2c02533
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Significantly Accelerated Photosensitized Formation of Atmospheric Sulfate at the Air–Water Interface of Microdroplets W. Wang et al. 10.1021/jacs.3c11892
- Insight into wet scavenging effects on sulfur and nitrogen containing organic compounds in urban Beijing C. Zhang et al. 10.1038/s41612-024-00756-5
- Distinct diurnal chemical compositions and formation processes of individual organic-containing particles in Beijing winter T. Ma et al. 10.1016/j.envpol.2022.120846
- Oxidation of sulfur dioxide by nitrogen dioxide accelerated at the interface of deliquesced aerosol particles T. Liu & J. Abbatt 10.1038/s41557-021-00777-0
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions X. Huang et al. 10.1038/s41612-023-00504-1
44 citations as recorded by crossref.
- Hydroxymethanesulfonate (HMS) Formation during Summertime Fog in an Arctic Oil Field J. Liu et al. 10.1021/acs.estlett.1c00357
- Primary Sulfate Is the Dominant Source of Particulate Sulfate during Winter in Fairbanks, Alaska A. Moon et al. 10.1021/acsestair.3c00023
- Characteristics, primary sources and secondary formation of water-soluble organic aerosols in downtown Beijing Q. Yu et al. 10.5194/acp-21-1775-2021
- Chemical and optical characterization of aqueous secondary organic aerosol generated by reaction of pyruvaldehyde with sodium sulfite M. Zhu et al. 10.1016/j.apr.2024.102124
- A critical review of sulfate aerosol formation mechanisms during winter polluted periods C. Ye et al. 10.1016/j.jes.2022.07.011
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Global modeling of heterogeneous hydroxymethanesulfonate chemistry S. Song et al. 10.5194/acp-21-457-2021
- Source and Chemistry of Hydroxymethanesulfonate (HMS) in Fairbanks, Alaska J. Campbell et al. 10.1021/acs.est.2c00410
- Global Importance of Hydroxymethanesulfonate in Ambient Particulate Matter: Implications for Air Quality J. Moch et al. 10.1029/2020JD032706
- Carbonyl Compounds Regulate Atmospheric Oxidation Capacity and Particulate Sulfur Chemistry in the Coastal Atmosphere M. Zhao et al. 10.1021/acs.est.4c03947
- Multiphase interactions between sulfur dioxide and secondary organic aerosol from the photooxidation of toluene: Reactivity and sulfate formation Q. Ye et al. 10.1016/j.scitotenv.2023.168736
- Field observations and quantifications of atmospheric formaldehyde partitioning in gaseous and particulate phases R. Xu et al. 10.1016/j.scitotenv.2021.152122
- Real-Time Single-Particle Characteristics and Aging of Cooking Aerosols in Urban Beijing T. Ma et al. 10.1021/acs.estlett.3c00053
- Significant Conversion of Organic Sulfur from Hydroxymethanesulfonate to Inorganic Sulfate and Peroxydisulfate Ions upon Heterogeneous OH Oxidation D. Lai et al. 10.1021/acs.estlett.3c00472
- Improving the representation of HONO chemistry in CMAQ and examining its impact on haze over China S. Zhang et al. 10.5194/acp-21-15809-2021
- Detailed NMR analysis of water-soluble organic compounds in size-resolved particulate matter seasonally collected at a suburban site in Prague Š. Horník et al. 10.1016/j.atmosenv.2021.118757
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al. 10.1021/acs.est.0c06496
- Characteristics of volatile organic compounds (VOCs) based on multisite observations in Hebei province in the warm season in 2019 Z. Wang et al. 10.1016/j.atmosenv.2021.118435
- Exploring the amplified role of HCHO in the formation of HMS and O3 during the co-occurring PM2.5 and O3 pollution in a coastal city of southeast China Y. Hong et al. 10.5194/acp-23-10795-2023
- Positive matrix factorization of seasonally resolved organic aerosol at three different central European background sites based on nuclear magnetic resonance Aerosolomics data Š. Horník et al. 10.1016/j.scitotenv.2024.170303
- Hydroxymethanesulfonate formation as a significant pathway of transformation of SO2 H. Zhang et al. 10.1016/j.atmosenv.2022.119474
- Identification of O3 Sensitivity to Secondary HCHO and NO2 Measured by MAX-DOAS in Four Cities in China C. Lu et al. 10.3390/rs16040662
- Enhanced aqueous formation and neutralization of fine atmospheric particles driven by extreme cold J. Campbell et al. 10.1126/sciadv.ado4373
- The importance of hydroxymethanesulfonate (HMS) in winter haze episodes in North China Plain C. Chen et al. 10.1016/j.envres.2022.113093
- Model Simulations and Predictions of Hydroxymethanesulfonate (HMS) in the Beijing-Tianjin-Hebei Region, China: Roles of Aqueous Aerosols and Atmospheric Acidity H. Wang et al. 10.1021/acs.est.3c07306
- A comprehensive observation-based multiphase chemical model analysis of sulfur dioxide oxidations in both summer and winter H. Song et al. 10.5194/acp-21-13713-2021
- Characterization of haze pollution in Zibo, China: Temporal series, secondary species formation, and PMx distribution H. Li et al. 10.1016/j.chemosphere.2021.131807
- Existence of hydroxymethanesulfonate (HMS) during spring haze and sandstorm events in Beijing: Implications for a heterogeneous formation pathway on mineral aerosols Y. Xu et al. 10.1016/j.envpol.2024.125483
- Unbalanced emission reductions and adverse meteorological conditions facilitate the formation of secondary pollutants during the COVID-19 lockdown in Beijing T. Ma et al. 10.1016/j.scitotenv.2022.155970
- Positive Feedback between Partitioning of Carbonyl Compounds and Particulate Sulfur Formation during Haze Episodes H. Shen et al. 10.1021/acs.est.4c07278
- Hygroscopicity and cloud condensation nucleation activities of hydroxyalkylsulfonates C. Peng et al. 10.1016/j.scitotenv.2022.154767
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- Hydroxymethanesulfonate and Sulfur(IV) in Fairbanks Winter During the ALPACA Study K. Dingilian et al. 10.1021/acsestair.4c00012
- Universal ion chromatography method for anions in active pharmaceutical ingredients enabled by computer-assisted separation modeling T. Yuan et al. 10.1016/j.jpba.2023.115923
- Effect of NOX, O3 and NH3 on sulfur isotope composition during heterogeneous oxidation of SO2: a laboratory investigation Z. Guo et al. 10.1007/s11869-024-01543-0
- Trace Metals Reveal Significant Contribution of Coal Combustion to Winter Haze Pollution in Northern China H. Shen et al. 10.1021/acsestair.4c00050
- Sulfate Formation Apportionment during Winter Haze Events in North China T. Wang et al. 10.1021/acs.est.2c02533
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Significantly Accelerated Photosensitized Formation of Atmospheric Sulfate at the Air–Water Interface of Microdroplets W. Wang et al. 10.1021/jacs.3c11892
- Insight into wet scavenging effects on sulfur and nitrogen containing organic compounds in urban Beijing C. Zhang et al. 10.1038/s41612-024-00756-5
- Distinct diurnal chemical compositions and formation processes of individual organic-containing particles in Beijing winter T. Ma et al. 10.1016/j.envpol.2022.120846
- Oxidation of sulfur dioxide by nitrogen dioxide accelerated at the interface of deliquesced aerosol particles T. Liu & J. Abbatt 10.1038/s41557-021-00777-0
- Deactivating Effect of Hydroxyl Radicals Reactivity by Sulfate and Sulfite Functional Groups in Aqueous Phase─Atmospheric Implications for Small Organosulfur Compounds D. Lai et al. 10.1021/acsestair.4c00033
- Aerosol high water contents favor sulfate and secondary organic aerosol formation from fossil fuel combustion emissions X. Huang et al. 10.1038/s41612-023-00504-1
Latest update: 30 Dec 2024
Short summary
The formation mechanisms of organic matter and sulfate in winter haze in the North China Plain remain unclear. This paper presents the identification and quantification of hydroxymethanesulfonate (HMS) in PM2.5 in Beijing winter and elucidates the heterogeneous HMS chemistry in favorable winter haze conditions. We show that the HMS not only contributes a substantial mass of organic matter, but also leads to an overestimation of sulfate in conventional measurements.
The formation mechanisms of organic matter and sulfate in winter haze in the North China Plain...
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