Articles | Volume 20, issue 8
https://doi.org/10.5194/acp-20-5145-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-5145-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
30 Apr 2020
Research article |
| 30 Apr 2020
| 30 Apr 2020
Formation of highly oxygenated organic molecules from chlorine-atom-initiated oxidation of alpha-pinene
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Matthieu Riva
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON,
69626, Villeurbanne, France
Hongbin Xie
CORRESPONDING AUTHOR
Key Laboratory of Industrial Ecology and Environmental Engineering
(MOE), School of Environmental Science and Technology, Dalian University of
Technology, Dalian 116024, China
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Liine Heikkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Simon Schallhart
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Qiaozhi Zha
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Xu-Cheng He
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Otso Peräkylä
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
Mikael Ehn
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, P.O. Box 64, University of Helsinki, 00014 Helsinki, Finland
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Cited
21 citations as recorded by crossref.
- Increasing contribution of nighttime nitrogen chemistry to wintertime haze formation in Beijing observed during COVID-19 lockdowns C. Yan et al. 10.1038/s41561-023-01285-1
- Absolute Photoionization Cross Section and Dissociative Ionization Pathways of Alpha‐Pinene R. Rodriguez et al. 10.1002/cphc.202300891
- Rapid mass growth and enhanced light extinction of atmospheric aerosols during the heating season haze episodes in Beijing revealed by aerosol–chemistry–radiation–boundary layer interaction Z. Lin et al. 10.5194/acp-21-12173-2021
- Elucidating the critical oligomeric steps in secondary organic aerosol and brown carbon formation Y. Ji et al. 10.5194/acp-22-7259-2022
- Drivers of High Concentrations of Secondary Organic Aerosols in Northern China during the COVID-19 Lockdowns X. Chang et al. 10.1021/acs.est.2c06914
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
- Multi-Oxygenated Organic Compounds in Fine Particulate Matter Collected in the Western Mediterranean Area E. Borrás et al. 10.3390/atmos12010094
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Implications for ozone control by understanding the survivor bias in observed ozone-volatile organic compounds system Z. Wang et al. 10.1038/s41612-022-00261-7
- Progress in quantitative research on the relationship between atmospheric oxidation and air quality Y. Wang et al. 10.1016/j.jes.2022.06.029
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Size‐dependent Molecular Characteristics and Possible Sources of Organic Aerosols at a Coastal New Particle Formation Hotspot of East China Y. Wan et al. 10.1029/2021JD034610
- A neglected pathway for the accretion products formation in the atmosphere X. Shi et al. 10.1016/j.scitotenv.2022.157494
21 citations as recorded by crossref.
- Increasing contribution of nighttime nitrogen chemistry to wintertime haze formation in Beijing observed during COVID-19 lockdowns C. Yan et al. 10.1038/s41561-023-01285-1
- Absolute Photoionization Cross Section and Dissociative Ionization Pathways of Alpha‐Pinene R. Rodriguez et al. 10.1002/cphc.202300891
- Rapid mass growth and enhanced light extinction of atmospheric aerosols during the heating season haze episodes in Beijing revealed by aerosol–chemistry–radiation–boundary layer interaction Z. Lin et al. 10.5194/acp-21-12173-2021
- Elucidating the critical oligomeric steps in secondary organic aerosol and brown carbon formation Y. Ji et al. 10.5194/acp-22-7259-2022
- Drivers of High Concentrations of Secondary Organic Aerosols in Northern China during the COVID-19 Lockdowns X. Chang et al. 10.1021/acs.est.2c06914
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
- Multi-Oxygenated Organic Compounds in Fine Particulate Matter Collected in the Western Mediterranean Area E. Borrás et al. 10.3390/atmos12010094
- Oxygenated products formed from OH-initiated reactions of trimethylbenzene: autoxidation and accretion Y. Wang et al. 10.5194/acp-20-9563-2020
- Implications for ozone control by understanding the survivor bias in observed ozone-volatile organic compounds system Z. Wang et al. 10.1038/s41612-022-00261-7
- Progress in quantitative research on the relationship between atmospheric oxidation and air quality Y. Wang et al. 10.1016/j.jes.2022.06.029
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- Size‐dependent Molecular Characteristics and Possible Sources of Organic Aerosols at a Coastal New Particle Formation Hotspot of East China Y. Wan et al. 10.1029/2021JD034610
- A neglected pathway for the accretion products formation in the atmosphere X. Shi et al. 10.1016/j.scitotenv.2022.157494
Latest update: 01 Nov 2024
Short summary
Chamber experiments were conducted with alpha-pinene and chlorine under low- and high-nitrogen-oxide (NOX) conditions. We estimated the HOM yields from chlorine-initiated oxidation of alpha-pinene under low-NOX conditions to be around 1.8 %, though with a uncertainty range (0.8 %–4 %) due to lack of suitable calibration methods. Our study clearly demonstrates that the chlorine-atom-initiated oxidation of alpha-pinene can produce low-volatility organic compounds.
Chamber experiments were conducted with alpha-pinene and chlorine under low- and...
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