Articles | Volume 20, issue 6
https://doi.org/10.5194/acp-20-3739-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-3739-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
30 Mar 2020
Research article |
| 30 Mar 2020
| 30 Mar 2020
Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Louisa K. Emmons
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
John J. Orlando
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Mary C. Barth
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Geoffrey S. Tyndall
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Samuel R. Hall
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Kirk Ullmann
Atmospheric Chemistry Observations and Modeling Laboratory, National Center for Atmospheric Research, Boulder, CO 80301, USA
Jason M. St. Clair
Atmospheric Chemistry and Dynamics Laboratory, NASA Goddard Space Flight Center, Greenbelt, MD 20771, USA
Joint Center for Earth Systems Technology, University of Maryland, Baltimore County, Baltimore, MD 21228, USA
Donald R. Blake
Department of Chemistry, University of California, Irvine, 570 Rowland Hall, Irvine, CA 92697-2025, USA
Armin Wisthaler
Institute for Ion Physics and Applied Physics, University of Innsbruck, Technikerstrasse 25, 6020 Innsbruck, Austria
Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo, Norway
Thao Paul V. Bui
Earth Science Division, NASA Ames Research Center, Moffett Field, CA 94035-1000, USA
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44 citations as recorded by crossref.
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- Stratospheric contribution to the summertime high surface ozone events over the western united states X. Wang et al. 10.1088/1748-9326/abba53
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44 citations as recorded by crossref.
- Cannabis Cultivation Facilities: A Review of Their Air Quality Impacts from the Occupational to Community Scale D. de Ferreyro Monticelli et al. 10.1021/acs.est.1c06372
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Sensitivity of northeastern US surface ozone predictions to the representation of atmospheric chemistry in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMMv1.0) B. Place et al. 10.5194/acp-23-9173-2023
- Performance evaluation of UKESM1 for surface ozone across the pan-tropics F. Brown et al. 10.5194/acp-24-12537-2024
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- The origin of potential precursors of secondary organic aerosols during combustion of biochar and softwood in residential heating J. Růžičková et al. 10.1016/j.psep.2022.03.036
- Comparison and evaluation of updates to WRF-Chem (v3.9) biogenic emissions using MEGAN M. Morichetti et al. 10.5194/gmd-15-6311-2022
- A better representation of volatile organic compound chemistry in WRF-Chem and its impact on ozone over Los Angeles Q. Zhu et al. 10.5194/acp-24-5265-2024
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Global Atmospheric Budget of Acetone: Air‐Sea Exchange and the Contribution to Hydroxyl Radicals S. Wang et al. 10.1029/2020JD032553
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- Large simulated future changes in the nitrate radical under the CMIP6 SSP scenarios: implications for oxidation chemistry S. Archer-Nicholls et al. 10.5194/acp-23-5801-2023
- Stratospheric contribution to the summertime high surface ozone events over the western united states X. Wang et al. 10.1088/1748-9326/abba53
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Modeling Isoprene Emission Response to Drought and Heatwaves Within MEGAN Using Evapotranspiration Data and by Coupling With the Community Land Model H. Wang et al. 10.1029/2022MS003174
- Improvements to the representation of BVOC chemistry–climate interactions in UKCA (v11.5) with the CRI-Strat 2 mechanism: incorporation and evaluation J. Weber et al. 10.5194/gmd-14-5239-2021
- Evaluating the Impact of Chemical Complexity and Horizontal Resolution on Tropospheric Ozone Over the Conterminous US With a Global Variable Resolution Chemistry Model R. Schwantes et al. 10.1029/2021MS002889
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- Simulating impacts on UK air quality from net-zero forest planting scenarios G. Purser et al. 10.5194/acp-23-13713-2023
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Weekly derived top-down volatile-organic-compound fluxes over Europe from TROPOMI HCHO data from 2018 to 2021 G. Oomen et al. 10.5194/acp-24-449-2024
- On the changes in surface ozone over the twenty-first century: sensitivity to changes in surface temperature and chemical mechanisms A. Archibald et al. 10.1098/rsta.2019.0329
- Turbulent transport and reactions of plant-emitted hydrocarbons in an Amazonian rain forest J. Fuentes et al. 10.1016/j.atmosenv.2022.119094
- Large Eddy Simulation for Investigating Coupled Forest Canopy and Turbulence Influences on Atmospheric Chemistry O. Clifton et al. 10.1029/2022MS003078
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- Comparison of Seasonal and Diurnal Concentration Profiles of BVOCs in Coniferous and Deciduous Forests H. Borsdorf et al. 10.3390/atmos14091347
- Implementation and evaluation of the automated model reduction (AMORE) version 1.1 isoprene oxidation mechanism in GEOS-Chem B. Yang et al. 10.1039/D3EA00121K
- Impacts of synoptic circulations on summertime ozone pollution in Guanzhong Basin, northwestern China Y. Yan et al. 10.1016/j.atmosenv.2021.118660
- The Chemistry Mechanism in the Community Earth System Model Version 2 (CESM2) L. Emmons et al. 10.1029/2019MS001882
- Estimating Submicron Aerosol Mixing State at the Global Scale With Machine Learning and Earth System Modeling Z. Zheng et al. 10.1029/2020EA001500
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- Contrasting terpene emissions from canopy and understory vegetation in response to increases in nitrogen deposition and seasonal changes in precipitation J. Fang et al. 10.1016/j.envpol.2022.120800
- Probing isoprene photochemistry at atmospherically relevant nitric oxide levels X. Zhang et al. 10.1016/j.chempr.2022.08.003
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- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
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- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Influence of Organized Turbulence on OH Reactivity at a Deciduous Forest O. Clifton et al. 10.1029/2022GL102548
- Intercomparison of GEOS-Chem and CAM-chem tropospheric oxidant chemistry within the Community Earth System Model version 2 (CESM2) H. Lin et al. 10.5194/acp-24-8607-2024
Latest update: 20 Nov 2024
Short summary
Ozone is a greenhouse gas and air pollutant that is harmful to human health and plants. During the summer in the southeastern US, many regional and global models are biased high for surface ozone compared to observations. Here adding more complex and updated chemistry for isoprene and terpenes, which are biogenic hydrocarbons emitted from trees and vegetation, into an earth system model greatly reduces the simulated surface ozone bias compared to aircraft and monitoring station data.
Ozone is a greenhouse gas and air pollutant that is harmful to human health and plants. During...
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