Articles | Volume 20, issue 5
https://doi.org/10.5194/acp-20-2709-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-2709-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Significant seasonal changes in optical properties of brown carbon in the midlatitude atmosphere
Heejun Han
School of Earth and Environmental Sciences/RIO, Seoul National
University, Seoul, 08826, South Korea
School of Earth and Environmental Sciences/RIO, Seoul National
University, Seoul, 08826, South Korea
Hojong Seo
School of Earth and Environmental Sciences/RIO, Seoul National
University, Seoul, 08826, South Korea
Kyung-Hoon Shin
Department of Marine Sciences and Convergent Technology, Hanyang
University, Ansan, 15588, South Korea
Dong-Hun Lee
Department of Marine Sciences and Convergent Technology, Hanyang
University, Ansan, 15588, South Korea
Related authors
No articles found.
Junhyeong Seo, Heejun Han, Intae Kim, and Guebuem Kim
Biogeosciences, 22, 4423–4431, https://doi.org/10.5194/bg-22-4423-2025, https://doi.org/10.5194/bg-22-4423-2025, 2025
Short summary
Short summary
This study examines methodological uncertainties in FDOM (fluorescent dissolved organic matter) measurements due to filter blanks, pore sizes, and storage conditions. Results show that pre-cleaning filters and optimizing storage improve measurement reliability. These findings minimize procedural errors and provide clear guidelines for FDOM analysis, emphasizing the need for method standardization in marine biogeochemical research.
Christian Lønborg, Cátia Carreira, Gwenaël Abril, Susana Agustí, Valentina Amaral, Agneta Andersson, Javier Arístegui, Punyasloke Bhadury, Mariana B. Bif, Alberto V. Borges, Steven Bouillon, Maria Ll. Calleja, Luiz C. Cotovicz Jr., Stefano Cozzi, Maryló Doval, Carlos M. Duarte, Bradley Eyre, Cédric G. Fichot, E. Elena García-Martín, Alexandra Garzon-Garcia, Michele Giani, Rafael Gonçalves-Araujo, Renee Gruber, Dennis A. Hansell, Fuminori Hashihama, Ding He, Johnna M. Holding, William R. Hunter, J. Severino P. Ibánhez, Valeria Ibello, Shan Jiang, Guebuem Kim, Katja Klun, Piotr Kowalczuk, Atsushi Kubo, Choon-Weng Lee, Cláudia B. Lopes, Federica Maggioni, Paolo Magni, Celia Marrase, Patrick Martin, S. Leigh McCallister, Roisin McCallum, Patricia M. Medeiros, Xosé Anxelu G. Morán, Frank E. Muller-Karger, Allison Myers-Pigg, Marit Norli, Joanne M. Oakes, Helena Osterholz, Hyekyung Park, Maria Lund Paulsen, Judith A. Rosentreter, Jeff D. Ross, Digna Rueda-Roa, Chiara Santinelli, Yuan Shen, Eva Teira, Tinkara Tinta, Guenther Uher, Masahide Wakita, Nicholas Ward, Kenta Watanabe, Yu Xin, Youhei Yamashita, Liyang Yang, Jacob Yeo, Huamao Yuan, Qiang Zheng, and Xosé Antón Álvarez-Salgado
Earth Syst. Sci. Data, 16, 1107–1119, https://doi.org/10.5194/essd-16-1107-2024, https://doi.org/10.5194/essd-16-1107-2024, 2024
Short summary
Short summary
In this paper, we present the first edition of a global database compiling previously published and unpublished measurements of dissolved organic matter (DOM) collected in coastal waters (CoastDOM v1). Overall, the CoastDOM v1 dataset will be useful to identify global spatial and temporal patterns and to facilitate reuse in studies aimed at better characterizing local biogeochemical processes and identifying a baseline for modelling future changes in coastal waters.
Cited articles
Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, https://doi.org/10.5194/acp-6-3131-2006, 2006.
Baduel, C., Voisin, D., and Jaffrezo, J. L.: Comparison of analytical methods for Humic Like Substances (HULIS) measurements in atmospheric particles, Atmos. Chem. Phys., 9, 5949–5962, https://doi.org/10.5194/acp-9-5949-2009, 2009.
Baduel, C., Voisin, D., and Jaffrezo, J.-L.: Seasonal variations of concentrations and optical properties of water soluble HULIS collected in urban environments, Atmos. Chem. Phys., 10, 4085–4095, https://doi.org/10.5194/acp-10-4085-2010, 2010.
Birdwell, J. E. and Engel, A. S.: Characterization of dissolved organic
matter in cave and spring waters using UV-Vis absorbance and fluorescence
spectroscopy, Org. Geochem., 41, 270–280,
https://doi.org/10.1016/j.orggeochem.2009.11.002, 2010.
Bro, R.: PARAFAC. Tutorial and applications, Chemometr. Intell. Lab., 38,
149–171, https://doi.org/10.1016/S0169-7439(97)00032-4, 1997.
Chen, Q., Ikemori, F., and Mochida, M.: Light absorption and
excitation-emission fluorescence of urban organic aerosol components and
their relationship to chemical structure, Environ. Sci. Technol., 50,
10859–10868, https://doi.org/10.1021/acs.est.6b02541, 2016.
Coble, P. G.: Marine optical biogeochemistry: the chemistry of ocean color,
Chem. Rev., 107, 402–418, https://doi.org/10.1021/cr050350+, 2007.
Das, O., Wang, Y., and Hsieh, Y.-P.: Chemical and carbon isotopic
characteristics of ash and smoke derived from burning of C3 and C4
grasses, Org. Geochem., 41, 263–269,
https://doi.org/10.1016/j.orggeochem.2009.11.001, 2010.
Dasari, S., Andersson, A., Bikkina, S., Holmstrand, H., Budhavant, K.,
Satheesh, S., Asmi, E., Kesti, J., Backman, J., Salam, A., Bisht, D. S.,
Tiwari, S., Hameed, Z., and Gustafsson, Ö.: Photochemical degradation
affects the light absorption of water-soluble brown carbon in the South
Asian outflow, Sci. Adv., 5, eaau8066,
https://doi.org/10.1126/sciadv.aau8066, 2019.
Del Vecchio, R. and Blough, N. V.: Photobleaching of chromophoric dissolved
organic matter in natural waters: Kinetics and modelling, Mar. Chem., 78,
231–253, https://doi.org/10.1016/S0304-4203(02)00036-1, 2002.
Després, V. R., Huffman, J. A., Burrows, S. M., Hoose, C., Safatov, A.
S., Buryak, G., Fröhlich-Nowoisky, J., Elbert, W., Andreae, M. O.,
Pöschl, U., and Jaenicke, R.: Primary biological aerosol particles in
the atmosphere: a review, Tellus B, 64, 15598,
https://doi.org/10.3402/tellusb.v64i0.15598, 2012.
Duarte, R. M. B. O. and Duarte, A. C.: Atmospheric organic matter, eMagRes,
2, 415–426, https://doi.org/10.1002/9780470034590.emrstm1331, 2013.
Feng, Y., Ramanathan, V., and Kotamarthi, V. R.: Brown carbon: a significant atmospheric absorber of solar radiation?, Atmos. Chem. Phys., 13, 8607–8621, https://doi.org/10.5194/acp-13-8607-2013, 2013.
Forrister, H., Liu, J., Scheuer, E., Dibb, J., Ziemba, L., Thornhill, K. L.,
Anderson, B., Diskin, B., Perring, A. E., Schwarz, J. P., Campuzano-Jost,
P., Day, D. A., Palm, B. B., Jimenez, J. L., Nenes, A., and Weber, R. J.:
Evolution of brown carbon in wildfire plumes, Geophys. Res. Lett., 42,
4623–4630, https://doi.org/10.1002/2015GL063897, 2015.
Fu, P., Kawamura, K., Chen, J., Qin, M., Ren, L., Sun, Y., Wang, Z., Barrie,
L. A., Tachibana, E., Ding, A., and Yamashita, Y.: Fluorescent water-soluble
organic aerosols in the High Arctic atmosphere, Sci. Rep.-UK, 5, 9845,
https://doi.org/10.1038/srep09845, 2015.
Gabriel, R., Mayol-Bracero, O. L., and Andreae, M. O.: Chemical
characterization of submicron aerosol particles collected over the Indian
Ocean, J. Geophys. Res., 107, 8005, https://doi.org/10.1029/2000JD000034,
2002.
Ghan, S. J. and Schwartz, S. E.: Aerosol properties and processes: A path
from field and laboratory measurements to global climate models, Amer.
Meteor. Soc., 88, 1059–1083, 2007.
Graber, E. R. and Rudich, Y.: Atmospheric HULIS: How humic-like are they? A comprehensive and critical review, Atmos. Chem. Phys., 6, 729–753, https://doi.org/10.5194/acp-6-729-2006, 2006.
Gustafsson, Ö., Kruså, M., Zencak, Z., Sheesley, R. J., Granat, L.,
Engström, E., Praveen, P. S., Rao, P. S. P., Leck, C., and Rodhe, H.:
Brown clouds over South Asia: biomass or fossil fuel combustion?, Science,
323, 495–498, https://doi.org/10.1126/science.1164857, 2009.
Healy, R. M., Wang, J. M., Sofowote, U., Su, Y., Debosz, J., Noble, M.,
Munoz, A., Jeong, C.-H., Hilker, N., Evans, G. J., and Doerksen, G.: Black
carbon in the Lower Fraser Valley, British Columbia: Impact of 2017
wildfires on local air quality and aerosol optical properties, Atmos.
Environ., 217, 116976, https://doi.org/10.1016/j.atmosenv.2019.116976, 2019.
Helms, J. R., Stubbins, A., Ritchie, J. D., and Minor, E. C.: Absorption
spectral slopes and slope ratios as indicators of molecular weight, source,
and photobleaching of chromophoric dissolved organic matter, Limnol.
Oceanogr., 33, 955–969, https://doi.org/10.4319/lo.2008.53.3.0955, 2008.
Hennigan, C. J., Sullivan, A. P., Collett, J. L., and Robinson, A. L.:
Levoglucosan stability in biomass burning particles exposed to hydroxyl
radicals, Geophys. Res. Lett., 37, L09806,
https://doi.org/10.1029/2010GL043088, 2010.
Hoffer, A., Gelencsér, A., Guyon, P., Kiss, G., Schmid, O., Frank, G. P., Artaxo, P., and Andreae, M. O.: Optical properties of humic-like substances (HULIS) in biomass-burning aerosols, Atmos. Chem. Phys., 6, 3563–3570, https://doi.org/10.5194/acp-6-3563-2006, 2006.
Hoffmann, D., Tilgner, A., Iinuma, Y., and Herrmann, H.: Atmospheric
stability of levoglucosan: a detailed laboratory and modeling study,
Environ. Sci. Technol., 44, 694–699, https://doi.org/10.1021/es902476f,
2010.
Kanakidou, M., Seinfeld, J. H., Pandis, S. N., Barnes, I., Dentener, F. J., Facchini, M. C., Van Dingenen, R., Ervens, B., Nenes, A., Nielsen, C. J., Swietlicki, E., Putaud, J. P., Balkanski, Y., Fuzzi, S., Horth, J., Moortgat, G. K., Winterhalter, R., Myhre, C. E. L., Tsigaridis, K., Vignati, E., Stephanou, E. G., and Wilson, J.: Organic aerosol and global climate modelling: a review, Atmos. Chem. Phys., 5, 1053–1123, https://doi.org/10.5194/acp-5-1053-2005, 2005.
Kawashima, H. and Haneishi, Y.: Effects of combustion emissions from the
Eurasian continent in winter on seasonal δ13C of elemental
carbon in aerosols in Japan, Atmos. Environ., 46, 568–579,
https://doi.org/10.1016/j.atmosenv.2011.05.015, 2012.
Kelly, S. D., Stein, C., and Jickelle, T. D.: Carbon and nitrogen isotopic
analysis of atmospheric organic matter, Atmos. Environ., 39, 6007–6011,
https://doi.org/10.1016/j.atmosenv.2005.05.030, 2005.
Kieber, R. J., Whitehead, R. F., Reid, S. N., Willey, J. D., and Seaton, P.
J.: Chromophoric dissolved organic matter (CDOM) in rainwater, Southeastern
North Carolina, USA, J. Atmos. Chem., 54, 21–41, 2006.
Kim, T.-H., Kim, G., Lee, S.-A., and Dittmar, T.: Extraordinary slow
degradation of dissolved organic carbon (DOC) in a cold marginal sea, Sci.
Rep.-UK, 5, 13808, https://doi.org/10.1038/srep13808, 2015.
Kirillova, E. N., Andersson, A., Han, J., Lee, M., and Gustafsson, Ö.: Sources and light absorption of water-soluble organic carbon aerosols in the outflow from northern China, Atmos. Chem. Phys., 14, 1413–1422, https://doi.org/10.5194/acp-14-1413-2014, 2014a.
Kirillova, E. N., Andersson, A., Tiwari, S., Sribastava, A. K., Bisht, D.
S., and Gustafsson, Ö.: Water-soluble organic carbon aerosols during a
fall New Delhi winter: Isotope-based source apportionment and optical
properties, J. Geophys. Res.-Atmos., 119, 3476–3485,
https://doi.org/10.1002/2013JD020041, 2014b.
Kuang, B. Y., Lin, P., Huang, X. H. H., and Yu, J. Z.: Sources of humic-like substances in the Pearl River Delta, China: positive matrix factorization analysis of PM2.5 major components and source markers, Atmos. Chem. Phys., 15, 1995–2008, https://doi.org/10.5194/acp-15-1995-2015, 2015.
Laskin, A., Laskin, J., and Nizkorodov, S. A.: Chemistry of Atmospheric
Brown Carbon, Chem. Rev., 115, 4335–4382,
https://doi.org/10.1021/cr5006167, 2015.
Lawaetz, A. J. and Stedmon, C. A.: Fluorescence intensity calibration using
the raman scatter peak of water, Appl. Spectrosc., 63, 936–940,
https://doi.org/10.1366/000370209788964548, 2009.
Li, X., Han, J., Hopke, P. K., Hu, J., Shu, Q., Chang, Q., and Ying, Q.: Quantifying primary and secondary humic-like substances in urban aerosol based on emission source characterization and a source-oriented air quality model, Atmos. Chem. Phys., 19, 2327–2341, https://doi.org/10.5194/acp-19-2327-2019, 2019.
Lin, C.-Y., Sheng, Y.-F., Chen, W.-N., Wang, Z., Kuo, C.-H., Chen, W.-C., and Yang, T.: The impact of channel effect on Asian dust transport dynamics: a case in southeastern Asia, Atmos. Chem. Phys., 12, 271–285, https://doi.org/10.5194/acp-12-271-2012, 2012.
Lin, P., Huang, X.-F., He, L.-Y., and Yu, J. Z.: Abundance and size
distribution of HULIS in ambient aerosols at a rural site in South China, J.
Aerosol Sci., 41, 74–87, https://doi.org/10.1016/j.jaerosci.2009.09.001,
2010.
Lukács, H., Gelencsér, A., Hammer, S., Puxbaum, H., Pio, C.,
Legrand, M., Kasper-Giebl, A., Handler, M., Limbeck, A., Simpson, D., and
Preunkert, S.: Seasonal trends and possible sources of brown carbon based on
2-year aerosol measurements at six sites in Europe, J. Geophys. Res., 122,
D23S18, https://doi.org/10.1029/2006JD008151, 2007.
Maenhaut, W., Raes, N., Chi, X., Cafmeyer, J., and Wang, W.: Chemical
composition and mass closure for PM2.5 and PM10 aerosols at
K-puszta, Hungary, in summer 2006, X-RAY Spectrom., 37, 193–197,
https://doi.org/10.1002/xrs.1062, 2007.
Matos, J. T. V., Freire, S. M. S. C., Duarte, R. M. B. O., and Duarte, A.
C.: Natural organic matter in urban aerosols: comparison between water and
alkaline soluble components using excitation-emission matrix fluorescence
spectroscopy and multiway data analysis, Atmos. Environ., 102, 1–10,
https://doi.org/10.1016/j.atmosenv.2014.11.042, 2015.
Mladenov, N., Lopez-Ramos, J., McKnight, D. M., and Reche, I.: Alpine lake
optical properties as sentinels of dust deposition and global change,
Limnol. Oceanogr., 54, 2386–2400,
https://doi.org/10.4319/lo.2009.54.6_part_2.2386, 2009.
Mladenov, N., Sommaruga, R., Morales-Baquero, R., Laurion, I., Camarero, L.,
Diéguez, M. C., Camacho, A., Delgado, A., Torres, O., Chen, Z., Felip,
M., and Reche, I.: Dust inputs and bacteria influence dissolved organic
matter in clear alpine lakes, Nat. Commun., 2, 405,
https://doi.org/10.1038/ncomms1411, 2011.
Panetta, R. J., Ibrahim, M., and Gélinas, Y.: Coupling a
high-temperature catalytic oxidation total organic carbon analyzer to an
isotope ratio mass spectrometer to measure natural-abundance δ13C-dissolved organic carbon in marine and freshwater samples, Anal.
Chem., 80, 5232–5239, https://doi.org/10.1021/ac702641z, 2008.
Park, S. S. and Son, S.-C.: Relationship between carbonaceous components and
aerosol light absorption during winter at an urban site of Gwangju, Korea,
Atmos. Res., 185, 73–83, https://doi.org/10.1016/j.atmosres.2016.11.005,
2017.
Park, S. S., Kim, Y. J., Cho, S. Y., and Kim, S. J.: Characterization of
PM2.5 aerosols dominated by local pollution and Asian dust observed at
an urban site in Korea during aerosol characterization experiments
(ACE)-Asia project, J. Air Waste Manage., 57, 434–443, https://doi.org/10.3155/1047-3289.57.4.434, 2007.
Pöhlker, C., Huffman, J. A., and Pöschl, U.: Autofluorescence of atmospheric bioaerosols – fluorescent biomolecules and potential interferences, Atmos. Meas. Tech., 5, 37–71, https://doi.org/10.5194/amt-5-37-2012, 2012.
Ramanathan, V., Ramana, M. V., Roberts, G., Kim, D., Corrigan, C., Chung,
C., and Winker, D.: Warming trends in Asia amplified by brown cloud solar
absorption, Nature, 448, 575–578, https://doi.org/10.1038/nature06019,
2007.
Saleh, R., Robinson, E. S., Tkacik, D. S., Ahern, A. T., Liu, S., Aiker, A.
C., Sullivan, R. C., Presto, A. A., Dubey, M. K., Yokelson, R. J., Donahue,
N. M., and Robinson, A. L.: Brownness of organics in aerosols from biomass
burning linked to their black carbon content, Nat. Geosci., 7, 36940,
https://doi.org/10.1038/ngeo2220, 2014.
Seinfeld, J. H., Carmichael, G. R., Arimoto, R., Conant, W. C., Brechtel, F.
J., Bates, T. S., Cahill, T. A., Clarke, A. D., Doherty, S. J., Flatau, P.
J., Huebert, B. J., Kim, J., Markowicz, K. M., Quinn, P. K., Russell, L. M.,
Russell, P. B., Shimizu, A., Shinozuka, Y., Song, C. H., Tang, Y., Uno, I.,
Vogelmann, A. M., Weber, R. J., Woo, J.-H., and Zhang, X. Y.: ACE-ASIA:
Regional climatic and atmospheric chemical effects of Asian dust and
pollution, B. Am. Meteorol. Soc., 85, 367–380, 2004.
Stedmon, C. A. and Bro, R.: Characterizing dissolved organic matter
fluorescence with parallel factory analysis: a tutorial, Limnol. Oceanogr.
Meth., 6, 572–579, https://doi.org/10.4319/lom.2008.6.572, 2008.
Stein, A. F., Draxler, R. R., Rolph, G. D., Stunder, B. J. B., Cohen, M. D.,
and Ngan, F.: NOAA's HYSPLIT atmospheric transport and dispersion modeling
system, Amer. Meteor. Soc., 96, 2059–2077,
https://doi.org/10.1175/BAMS-D-14-00110.1, 2015.
Tan, J., Xiang, P., Zhou, X., Duan, J., Ma, Y., He, K., Cheng, Y., Yu, J.,
and Querol, X.: Chemical characterization of humic-like substances (HULIS)
in PM2.5 in Lanzhou, China, Sci. Total Environ., 573, 1481–1490,
https://doi.org/10.1016/j.scitotenv.2016.08.025, 2016.
Taylor, S. R. and McLennan, S. M.: The geochemical evolution of the
continental crust, Rev. Geophys., 33, 241–265,
https://doi.org/10.1007/s10201-006-0194-9, 1995.
Troyer, I. D., Bouillon, S., Barker, S., Perry, C., Coorevits, K., and
Merckx, R.: Stable isotope analysis of dissolved organic carbon in soil
solutions using a catalytic combustion total organic carbon analyzer-isotope
ratio mass spectrometer with a cryofocusing interface, Rapid Commun. Mass
Spectrom., 24, 365–374, https://doi.org/10.1002/rcm.4403, 2010.
Tsukuda, S., Sugiyama, M., Harita, Y., and Nishimura, K.: Atmospheric bulk
deposition of soluble phosphorus in Ashiu Experimental Forest, Central
Japan: source apportionment and sample contamination problem, Atmos.
Environ., 39, 823–836, https://doi.org/10.1016/j.atmosenv.2004.10.028,
2005.
Twardowski, M. S., Boss, E., Sullivan, J. M., and Donaghay, P. L.: Modeling
the spectral shape of absorbing chromophoric dissolved organic matter, Mar.
Chem., 89, 69–88, https://doi.org/10.1016/j.marchem.2004.02.008, 2004.
Voliotis, A., Prokeš, R., Lammel, G., and Samara, C.: New insights on
humic-like substances associated with wintertime urban aerosols from central
and southern Europe: Size-resolved chemical characterization and optical
properties, Atmos. Environ., 166, 286–299,
https://doi.org/10.1016/j.atmosenv.2017.07.024, 2017.
Wozniak, A. S., Bauer, J. E., and Dickhut, R. B.: Characteristics of
water-soluble organic carbon associated with aerosol particles in the
eastern United States, Atmos. Environ., 46, 181–188,
https://doi.org/10.1016/j.atmosenv.2011.10.001, 2012.
Yan, G. and Kim, G.: Dissolved organic carbon in the precipitation of Seoul,
Korea: Implications for global wet depositional flux of fossil-fuel derived
organic carbon, Atmos. Environ., 59, 117–124,
https://doi.org/10.1016/j.atmosenv.2012.05.044, 2012.
Yan, G. and Kim, G.: Sources and fluxes of organic nitrogen in precipitation
over the southern East Sea/Sea of Japan, Atmos. Chem. Phys., 15, 2761–2774,
https://doi.org/10.5194/acp-15-2761-2015, 2015.
Yan, G. and Kim, G.: Speciation and sources of brown carbon in precipitation
at Seoul, Korea: Insights from excitation-emission matrix spectroscopy and
carbon isotopic analysis, Environ. Sci. Technol., 51, 11580–11587,
https://doi.org/10.1021/acs.est.7b02892, 2017.
Yan, G., Cho, H.-M., Lee, I., and Kim, G.: Significant emissions of
210Po by coal burning into the urban atmosphere of Seoul, Korea, Atmos.
Environ., 54, 80–85, https://doi.org/10.1016/j.atmosenv.2012.02.090, 2012.
Zepp, R. G., Sheldon, W. M., and Moran, M. A.: Dissolved organic
fluorophores in southeastern US coastal waters: correction method for
eliminating Rayleigh and Raman scattering peaks in excitation-emission
matrices, Mar. Chem., 89, 15–36,
https://doi.org/10.1016/j.marchem.2004.02.006, 2004.
Short summary
We found significant seasonal variations in optical and chemical properties of organic aerosols in the urban region and changes in
photo-resistivity of light-absorbing organic aerosols (e.g., brown carbon) owing to the high UV radiation in the atmosphere. Our results suggest that photochemical degradation plays a significant role in light-absorbing organic aerosol abundances and might be an important removal mechanism of
light-absorbing aerosols in the atmosphere.
We found significant seasonal variations in optical and chemical properties of organic aerosols...
Altmetrics
Final-revised paper
Preprint