Articles | Volume 20, issue 1
https://doi.org/10.5194/acp-20-267-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-267-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Jan 2020
Research article |
| 07 Jan 2020
| 07 Jan 2020
The changing role of organic nitrates in the removal and transport of NOx
Paul S. Romer Present
Department of Chemistry, University of California Berkeley, Berkeley, CA 94720, USA
Azimeh Zare
Department of Chemistry, University of California Berkeley, Berkeley, CA 94720, USA
Department of Chemistry, University of California Berkeley, Berkeley, CA 94720, USA
Department of Earth and Planetary Sciences, University of California Berkeley, Berkeley, CA 94720, USA
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Cited
32 citations as recorded by crossref.
- Sensitivity of Tropospheric Ozone Over the Southeast USA to Dry Deposition C. Baublitz et al. 10.1029/2020GL087158
- Leaf Stomatal Uptake of Alkyl Nitrates B. Place et al. 10.1021/acs.estlett.1c00793
- Direct estimates of biomass burning NO<sub><i>x</i></sub> emissions and lifetimes using daily observations from TROPOMI X. Jin et al. 10.5194/acp-21-15569-2021
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
- Quantifying NOx emissions in Egypt using TROPOMI observations A. Rey-Pommier et al. 10.5194/acp-22-11505-2022
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Estimation of OH in urban plumes using TROPOMI-inferred NO2 ∕ CO S. Lama et al. 10.5194/acp-22-16053-2022
- Diagnosing the Sensitivity of Particulate Nitrate to Precursor Emissions Using Satellite Observations of Ammonia and Nitrogen Dioxide R. Dang et al. 10.1029/2023GL105761
- Direct formation of HONO through aqueous-phase photolysis of organic nitrates J. González-Sánchez et al. 10.5194/acp-23-15135-2023
- Unveiling the overlooked direct emissions of particulate organic nitrates from ship J. Chen et al. 10.1016/j.envint.2024.108487
- Evidence of Nighttime Production of Organic Nitrates During SEAC4RS, FRAPPÉ, and KORUS‐AQ H. Kenagy et al. 10.1029/2020GL087860
- A study of the conformational isomerism of n-propyl nitrate by microwave spectroscopy W. Orellana et al. 10.1016/j.jms.2020.111376
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al. 10.1029/2021GL097472
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al. 10.5194/acp-21-4915-2021
- Measurements of Atmosphere–Biosphere Exchange of Oxidized Nitrogen and Implications for the Chemistry of Atmospheric NOx E. Delaria & R. Cohen 10.1021/acs.accounts.3c00090
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Remotely sensed and surface measurement- derived mass-conserving inversion of daily NOx emissions and inferred combustion technologies in energy-rich northern China X. Li et al. 10.5194/acp-23-8001-2023
- Surface ozone in the North American pollution outflow region of Nova Scotia: Long-term analysis of surface concentrations, precursor emissions and long-range transport influence M. Mitchell et al. 10.1016/j.atmosenv.2021.118536
- Impacts of sectoral, regional, species, and day-specific emissions on air pollution and public health in Washington, DC M. Nawaz et al. 10.1525/elementa.2021.00043
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al. 10.5194/acp-23-5851-2023
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- Theoretical investigation on the atmospheric degradation mechanism, kinetics, and fate of hydroxymethyl nitrate initiated by ˙OH radicals X. Liu et al. 10.1039/D3NJ01628E
- An inversion of NO<sub><i>x</i></sub> and non-methane volatile organic compound (NMVOC) emissions using satellite observations during the KORUS-AQ campaign and implications for surface ozone over East Asia A. Souri et al. 10.5194/acp-20-9837-2020
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al. 10.5194/amt-14-3693-2021
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Quantifying burning efficiency in megacities using the NO2∕CO ratio from the Tropospheric Monitoring Instrument (TROPOMI) S. Lama et al. 10.5194/acp-20-10295-2020
- Variable effects of spatial resolution on modeling of nitrogen oxides C. Li et al. 10.5194/acp-23-3031-2023
32 citations as recorded by crossref.
- Sensitivity of Tropospheric Ozone Over the Southeast USA to Dry Deposition C. Baublitz et al. 10.1029/2020GL087158
- Leaf Stomatal Uptake of Alkyl Nitrates B. Place et al. 10.1021/acs.estlett.1c00793
- Direct estimates of biomass burning NO<sub><i>x</i></sub> emissions and lifetimes using daily observations from TROPOMI X. Jin et al. 10.5194/acp-21-15569-2021
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
- Quantifying NOx emissions in Egypt using TROPOMI observations A. Rey-Pommier et al. 10.5194/acp-22-11505-2022
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Estimation of OH in urban plumes using TROPOMI-inferred NO2 ∕ CO S. Lama et al. 10.5194/acp-22-16053-2022
- Diagnosing the Sensitivity of Particulate Nitrate to Precursor Emissions Using Satellite Observations of Ammonia and Nitrogen Dioxide R. Dang et al. 10.1029/2023GL105761
- Direct formation of HONO through aqueous-phase photolysis of organic nitrates J. González-Sánchez et al. 10.5194/acp-23-15135-2023
- Unveiling the overlooked direct emissions of particulate organic nitrates from ship J. Chen et al. 10.1016/j.envint.2024.108487
- Evidence of Nighttime Production of Organic Nitrates During SEAC4RS, FRAPPÉ, and KORUS‐AQ H. Kenagy et al. 10.1029/2020GL087860
- A study of the conformational isomerism of n-propyl nitrate by microwave spectroscopy W. Orellana et al. 10.1016/j.jms.2020.111376
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al. 10.1029/2021GL097472
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Metal-free catalysis on the reactions of nitric acid with aliphatic aldehydes: A new potential source of organic nitrates F. Bai et al. 10.1016/j.atmosenv.2023.119673
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al. 10.5194/acp-21-4915-2021
- Measurements of Atmosphere–Biosphere Exchange of Oxidized Nitrogen and Implications for the Chemistry of Atmospheric NOx E. Delaria & R. Cohen 10.1021/acs.accounts.3c00090
- Reaction of Organic Matter with Nitronium Ion as a Source of Organic Nitrate Esters in Proxies for Organic Aerosols R. Hansen et al. 10.1021/acsearthspacechem.3c00111
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Remotely sensed and surface measurement- derived mass-conserving inversion of daily NOx emissions and inferred combustion technologies in energy-rich northern China X. Li et al. 10.5194/acp-23-8001-2023
- Surface ozone in the North American pollution outflow region of Nova Scotia: Long-term analysis of surface concentrations, precursor emissions and long-range transport influence M. Mitchell et al. 10.1016/j.atmosenv.2021.118536
- Impacts of sectoral, regional, species, and day-specific emissions on air pollution and public health in Washington, DC M. Nawaz et al. 10.1525/elementa.2021.00043
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al. 10.5194/acp-23-5851-2023
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- Theoretical investigation on the atmospheric degradation mechanism, kinetics, and fate of hydroxymethyl nitrate initiated by ˙OH radicals X. Liu et al. 10.1039/D3NJ01628E
- An inversion of NO<sub><i>x</i></sub> and non-methane volatile organic compound (NMVOC) emissions using satellite observations during the KORUS-AQ campaign and implications for surface ozone over East Asia A. Souri et al. 10.5194/acp-20-9837-2020
- Estimation of particulate organic nitrates from thermodenuder–aerosol mass spectrometer measurements in the North China Plain W. Xu et al. 10.5194/amt-14-3693-2021
- Observation and modeling of organic nitrates on a suburban site in southwest China C. Li et al. 10.1016/j.scitotenv.2022.160287
- Measurement of NO<sub><i>x</i></sub> and NO<sub><i>y</i></sub> with a thermal dissociation cavity ring-down spectrometer (TD-CRDS): instrument characterisation and first deployment N. Friedrich et al. 10.5194/amt-13-5739-2020
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Quantifying burning efficiency in megacities using the NO2∕CO ratio from the Tropospheric Monitoring Instrument (TROPOMI) S. Lama et al. 10.5194/acp-20-10295-2020
- Variable effects of spatial resolution on modeling of nitrogen oxides C. Li et al. 10.5194/acp-23-3031-2023
Latest update: 26 Jul 2024
Short summary
The chemistry of nitrogen oxides (NOx) affects both air quality and climate through its role in the production of ozone and secondary aerosols. We find that recent changes in emissions have caused a significant shift in the chemical loss of NOx away from direct production of HNO3 and towards production of organic nitrates. This shift is leading to a flatter distribution of NOx across the United States and helping transform air pollution from a local issue into a broader regional concern.
The chemistry of nitrogen oxides (NOx) affects both air quality and climate through its role in...
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