Articles | Volume 20, issue 22
https://doi.org/10.5194/acp-20-13701-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-13701-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR
Michael Rolletter
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Marion Blocquet
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Ministère de l'Education Nationale et de la Jeunesse, 110 rue de Grenelle, 75357 Paris SP 07, France
Martin Kaminski
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Federal Office of Consumer Protection and Food Safety, Department 5: Method Standardization, Reference Laboratories, Resistance to Antibiotics, Berlin, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Hans-Peter Dorn
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Frank Holland
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Xin Li
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: College of Environmental Sciences and
Engineering, Peking University, Beijing, China
Franz Rohrer
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Robert Wegener
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
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Cited
6 citations as recorded by crossref.
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al.
- α-Pinene Secondary Organic Aerosol (SOA) Formation through Interconnected Day- and Nighttime Chemistry A. Błaziak et al.
- Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products B. Witkowski et al.
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al.
- Unappreciated Role of Photochemical Aging of Biogenic Organic Nitrates in Atmospheric Ozone Formation S. Zhang et al.
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al.
6 citations as recorded by crossref.
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al.
- α-Pinene Secondary Organic Aerosol (SOA) Formation through Interconnected Day- and Nighttime Chemistry A. Błaziak et al.
- Aging of α-Pinene Secondary Organic Aerosol by Hydroxyl Radicals in the Aqueous Phase: Kinetics and Products B. Witkowski et al.
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al.
- Unappreciated Role of Photochemical Aging of Biogenic Organic Nitrates in Atmospheric Ozone Formation S. Zhang et al.
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al.
Saved (final revised paper)
Latest update: 09 May 2026
Short summary
The photooxidation of pinonaldehyde is investigated in a chamber study under natural sunlight and low NO conditions with and without an added hydroxyl radical (OH) scavenger. The experimentally determined pinonaldehyde photolysis frequency is faster by a factor of 3.5 than currently used parameterizations in atmospheric models. Yields of degradation products are measured in the presence and absence of OH. Measurements are compared to current atmospheric models and a theory-based mechanism.
The photooxidation of pinonaldehyde is investigated in a chamber study under natural sunlight...
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