Articles | Volume 20, issue 21
https://doi.org/10.5194/acp-20-12921-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-12921-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
05 Nov 2020
Research article |
| 05 Nov 2020
| 05 Nov 2020
Estimation of rate coefficients for the reactions of O3 with unsaturated organic compounds for use in automated mechanism construction
Michael E. Jenkin
CORRESPONDING AUTHOR
Atmospheric Chemistry Services, Okehampton, Devon, EX20 4QB, UK
Richard Valorso
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Bernard Aumont
LISA, UMR CNRS 7583, Université Paris-Est Créteil,
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Mike J. Newland
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, YO10 5DD, UK
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, York,
YO10 5DD, UK
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- INCHEM-Py v1.2: a community box model for indoor air chemistry D. Shaw et al. 10.5194/gmd-16-7411-2023
- Gas-phase reactivity of acyclic α,β-unsaturated carbonyls towards ozone J. Illmann et al. 10.1039/D0CP05881E
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Latest update: 13 Dec 2024
Short summary
Unsaturated organic compounds are emitted in large quantities from natural and human-influenced sources. Atmospheric removal occurs significantly by reaction with ozone, initiating reaction sequences forming free radicals and organic pollutants in the gaseous and particulate phases. Due to their very large number, it is impossible to study the reaction rate for every compound, and most have to be estimated. Updated and extended estimation methods are reported for use in atmospheric models.
Unsaturated organic compounds are emitted in large quantities from natural and human-influenced...
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