Articles | Volume 20, issue 20
https://doi.org/10.5194/acp-20-11809-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-11809-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Molecular understanding of the suppression of new-particle formation by isoprene
Martin Heinritzi
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Lubna Dada
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Mario Simon
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Dominik Stolzenburg
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Andrea C. Wagner
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Department of Chemistry & CIRES, University of Colorado at Boulder,
Boulder, CO 80309-0215, USA
Lukas Fischer
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Lauri R. Ahonen
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Stavros Amanatidis
California Institute of Technology, Pasadena, CA 91125, USA
Rima Baalbaki
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Andrea Baccarini
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Paulus S. Bauer
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Bernhard Baumgartner
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Federico Bianchi
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Science and Engineering, Beijing University of Chemical
Technology, Beijing, 100029, China
Sophia Brilke
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Dexian Chen
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Randall Chiu
Department of Chemistry & CIRES, University of Colorado at Boulder,
Boulder, CO 80309-0215, USA
Antonio Dias
CENTRA and FCUL, University of Lisbon, 1749-016 Lisbon, Portugal
CERN, 1211 Geneva, Switzerland
Josef Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Jonathan Duplissy
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Henning Finkenzeller
Department of Chemistry & CIRES, University of Colorado at Boulder,
Boulder, CO 80309-0215, USA
Carla Frege
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Claudia Fuchs
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Olga Garmash
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Hamish Gordon
CERN, 1211 Geneva, Switzerland
School of Earth and Environment, University of Leeds, Leeds, LS 9JT, UK
Manuel Granzin
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Imad El Haddad
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Xucheng He
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Johanna Helm
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Victoria Hofbauer
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Christopher R. Hoyle
Institute for Atmospheric and Climate Science, ETH Zurich, Zurich,
Switzerland
Juha Kangasluoma
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Science and Engineering, Beijing University of Chemical
Technology, Beijing, 100029, China
Timo Keber
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Changhyuk Kim
California Institute of Technology, Pasadena, CA 91125, USA
Department of Environmental Engineering, Pusan National University,
Busan 46241, Republic of Korea
Andreas Kürten
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Houssni Lamkaddam
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Tiia M. Laurila
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Janne Lampilahti
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Chuan Ping Lee
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Katrianne Lehtipalo
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Markus Leiminger
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Huajun Mai
California Institute of Technology, Pasadena, CA 91125, USA
Vladimir Makhmutov
Lebedev Physical Institute, Russian Academy of Sciences, 119991,
Moscow, Russia
Hanna Elina Manninen
CERN, 1211 Geneva, Switzerland
Ruby Marten
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Serge Mathot
CERN, 1211 Geneva, Switzerland
Roy Lee Mauldin
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Department of Atmospheric and Oceanic Sciences, University of
Colorado at Boulder, Boulder, CO 80309, USA
Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA
15213, USA
Bernhard Mentler
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Ugo Molteni
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Tatjana Müller
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Wei Nie
Joint International Research Laboratory of Atmospheric and Earth
System Sciences, School of Atmospheric Sciences, Nanjing University,
Nanjing, 210023, China
Tuomo Nieminen
Department of Applied Physics, University of Eastern Finland, P.O. Box
1627, 70211 Kuopio, Finland
Antti Onnela
CERN, 1211 Geneva, Switzerland
Eva Partoll
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Monica Passananti
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Tuukka Petäjä
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Joschka Pfeifer
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
Veronika Pospisilova
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Lauriane L. J. Quéléver
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Matti P. Rissanen
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Clémence Rose
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Laboratory for physical meteorology, UMR6016, University Clermont
Auvergne-CNRS, 63178, Aubière, France
Siegfried Schobesberger
Department of Applied Physics, University of Eastern Finland, P.O. Box
1627, 70211 Kuopio, Finland
Wiebke Scholz
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Kay Scholze
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Mikko Sipilä
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Gerhard Steiner
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Yuri Stozhkov
Lebedev Physical Institute, Russian Academy of Sciences, 119991,
Moscow, Russia
Christian Tauber
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Yee Jun Tham
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Miguel Vazquez-Pufleau
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Annele Virtanen
Department of Applied Physics, University of Eastern Finland, P.O. Box
1627, 70211 Kuopio, Finland
Alexander L. Vogel
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
Rainer Volkamer
Department of Chemistry & CIRES, University of Colorado at Boulder,
Boulder, CO 80309-0215, USA
Robert Wagner
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Mingyi Wang
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Lena Weitz
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Daniela Wimmer
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Mao Xiao
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Penglin Ye
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Aerodyne Research, Inc., Billerica, MA 01821, USA
Qiaozhi Zha
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Xueqin Zhou
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Antonio Amorim
CENTRA and FCUL, University of Lisbon, 1749-016 Lisbon, Portugal
Urs Baltensperger
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Armin Hansel
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
Markku Kulmala
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Science and Engineering, Beijing University of Chemical
Technology, Beijing, 100029, China
Helsinki Institute of Physics, University of Helsinki, 00014
Helsinki, Finland
António Tomé
IDL-University of Beira Interior, Covilhã, Portugal
Paul M. Winkler
Faculty of Physics, University of Vienna, 1090 Vienna, Austria
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research (INAR)/Physics,
Faculty of Science, University of Helsinki, 00014 Helsinki, Finland
Aerodyne Research, Inc., Billerica, MA 01821, USA
Neil M. Donahue
Center for Atmospheric Particle Studies, Carnegie Mellon University,
Pittsburgh, PA 15213, USA
Jasper Kirkby
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
Joachim Curtius
CORRESPONDING AUTHOR
Institute for Atmospheric and Environmental Sciences, Goethe
University Frankfurt, 60438 Frankfurt am Main, Germany
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- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
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Short summary
With experiments performed at CLOUD, we show how isoprene interferes in monoterpene oxidation via RO2 termination at atmospherically relevant concentrations. This interference shifts the distribution of highly oxygenated organic molecules (HOMs) away from C20 class dimers towards C15 class dimers, which subsequently reduces both biogenic nucleation and early growth rates. Our results may help to understand the absence of new-particle formation in isoprene-rich environments.
With experiments performed at CLOUD, we show how isoprene interferes in monoterpene oxidation...
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