Articles | Volume 20, issue 17
https://doi.org/10.5194/acp-20-10125-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-10125-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Impact of NOx on secondary organic aerosol (SOA) formation from α-pinene and β-pinene photooxidation: the role of highly oxygenated organic nitrates
Iida Pullinen
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
present address: Department of Applied Physics, University of Eastern Finland, Kuopio, Finland
Sebastian Schmitt
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
present address: TSI GmbH, 52068 Aachen, Germany
Sungah Kang
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Mehrnaz Sarrafzadeh
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Centre for Atmospheric Chemistry, York University, 4700 Keele St.,
Toronto, ON M3J 1P3, Canada
present address: PerkinElmer, 501 Rowntree Dairy Rd, Woodbridge, ON, L4L 8H1, Canada
Patrick Schlag
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
present address: Shimadzu Deutschland GmbH, 47269 Duisburg, Germany
Stefanie Andres
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Einhard Kleist
Institute of Bio- and Geosciences, IBG-2, Forschungszentrum
Jülich, 52425 Jülich, Germany
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Franz Rohrer
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Monika Springer
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Ralf Tillmann
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Jürgen Wildt
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Institute of Bio- and Geosciences, IBG-2, Forschungszentrum
Jülich, 52425 Jülich, Germany
Cheng Wu
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
present address: Department of Environmental Science, Stockholm
University, 11418 Stockholm, Sweden
Defeng Zhao
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
present address: Dept. of Atmos. and Oceanic Sci. & Inst. of Atmos. Sci., Fudan University, Shanghai, 200438, China
Andreas Wahner
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
Astrid Kiendler-Scharr
Institute for Energy and Climate Research, IEK-8, Forschungszentrum
Jülich, 52425 Jülich, Germany
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Cited
47 citations as recorded by crossref.
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- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
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- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
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47 citations as recorded by crossref.
- Efficient alkane oxidation under combustion engine and atmospheric conditions Z. Wang et al. 10.1038/s42004-020-00445-3
- Modelling the influence of biotic plant stress on atmospheric aerosol particle processes throughout a growing season D. Taipale et al. 10.5194/acp-21-17389-2021
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al. 10.5194/acp-23-8993-2023
- Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors Y. Shao et al. 10.5194/acp-22-9799-2022
- Particle-Bound Highly Oxidized Organic Molecules Derived from Aromatic Hydrocarbons in an Urban Atmosphere M. Zhu et al. 10.1021/acs.estlett.2c00841
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. 10.1016/j.scitotenv.2024.173327
- Effects of NOx and NH3 on the secondary organic aerosol formation from α-pinene photooxidation Y. Zhao et al. 10.1016/j.atmosenv.2024.120778
- Monoterpene Photooxidation in a Continuous-Flow Chamber: SOA Yields and Impacts of Oxidants, NOx, and VOC Precursors J. Liu et al. 10.1021/acs.est.2c02630
- Influence of anthropogenic emissions on the composition of highly oxygenated organic molecules in Helsinki: a street canyon and urban background station comparison M. Okuljar et al. 10.5194/acp-23-12965-2023
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Research and Application of Hybrid Adaptive Forecasting Method Based on SOA D. Liu & X. Wei 10.1051/e3sconf/202021302007
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Toxicological Effects of Secondary Air Pollutants W. Xiang et al. 10.1007/s40242-023-3050-0
- Theoretical study of the reaction of organic peroxyl radicals with alkenes and their accretion products involved in the atmospheric nucleation B. Dong et al. 10.1016/j.atmosenv.2024.120718
- Effect of NOx and RH on the secondary organic aerosol formation from toluene photooxidation S. Liu et al. 10.1016/j.jes.2021.06.017
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Applications of environmental mass spectrometry in atmospheric haze chemistry T. Chen et al. 10.1016/j.trac.2024.117614
- Isothermal evaporation of α-pinene secondary organic aerosol particles formed under low NOx and high NOx conditions Z. Li et al. 10.5194/acp-23-203-2023
- Unexpected significance of a minor reaction pathway in daytime formation of biogenic highly oxygenated organic compounds H. Shen et al. 10.1126/sciadv.abp8702
- Review of Smog Chamber Experiments for Secondary Organic Aerosol Formation H. Kim et al. 10.3390/atmos15010115
- Nitrogen-containing organic aerosols and highly oxidized molecules produced by reaction of ozone with floor cleaning detergent J. Xu et al. 10.1039/D4EA00076E
- Impact of HO2∕RO2 ratio on highly oxygenated α-pinene photooxidation products and secondary organic aerosol formation potential Y. Baker et al. 10.5194/acp-24-4789-2024
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Partitioning of Organonitrates in the Production of Secondary Organic Aerosols from α-Pinene Photo-Oxidation E. Aruffo et al. 10.1021/acs.est.1c08380
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- Impact of urbanization on fine particulate matter concentrations over central Europe P. Huszar et al. 10.5194/acp-24-397-2024
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Global PM2.5 and secondary organic aerosols (SOA) levels with sectorial contribution to anthropogenic and biogenic SOA formation S. Azmi & M. Sharma 10.1016/j.chemosphere.2023.139195
- A nitrate ion chemical-ionization atmospheric-pressure-interface time-of-flight mass spectrometer (NO3− ToFCIMS) sensitivity study S. Alage et al. 10.5194/amt-17-4709-2024
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- The formation mechanism of highly oxygenated organic molecules produced by toluene in the urban atmosphere Z. Dong et al. 10.1016/j.atmosenv.2022.119555
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Quantifying organic matter and functional groups in particulate matter filter samples from the southeastern United States – Part 2: Spatiotemporal trends A. Boris et al. 10.5194/amt-14-4355-2021
- Global simulations of monoterpene-derived peroxy radical fates and the distributions of highly oxygenated organic molecules (HOMs) and accretion products R. Xu et al. 10.5194/acp-22-5477-2022
- Secondary organic aerosol formation from camphene oxidation: measurements and modeling Q. Li et al. 10.5194/acp-22-3131-2022
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- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
- Advances in Adsorption, Absorption, and Catalytic Materials for VOCs Generated in Typical Industries L. Wu et al. 10.3390/en17081861
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
Latest update: 20 Nov 2024
Short summary
Biogenic and anthropogenic air masses mix in the atmosphere, bringing plant-emitted monoterpenes and traffic-related nitrogen oxides together. There is debate whether the presence of nitrogen oxides reduces or increases secondary aerosol formation. This is important as secondary aerosols have cooling effects in the climate system but also constitute a health risk in populated areas. We show that the presence of NOx alone should not much affect the mass yields of secondary organic aerosols.
Biogenic and anthropogenic air masses mix in the atmosphere, bringing plant-emitted monoterpenes...
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