Articles | Volume 19, issue 9
https://doi.org/10.5194/acp-19-6579-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-6579-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| Highlight paper
| 
17 May 2019
Research article | Highlight paper |
| 17 May 2019
| 17 May 2019
Photooxidants from brown carbon and other chromophores in illuminated particle extracts
Richie Kaur
Department of Land, Air and Water Resources, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Jacqueline R. Labins
Department of Land, Air and Water Resources, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Scarlett S. Helbock
Department of Land, Air and Water Resources, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Wenqing Jiang
Department of Environmental Toxicology, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Keith J. Bein
Center for Health and the Environment, University of California, Davis,
One Shields Avenue, Davis, CA 95616-8627, USA
Department of Environmental Toxicology, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Department of Land, Air and Water Resources, University of
California, Davis, One Shields Avenue, Davis, CA 95616-8627, USA
Viewed
Total article views: 4,924 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Dec 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,907 | 941 | 76 | 4,924 | 498 | 71 | 94 |
- HTML: 3,907
- PDF: 941
- XML: 76
- Total: 4,924
- Supplement: 498
- BibTeX: 71
- EndNote: 94
Total article views: 4,336 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 17 May 2019)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,576 | 689 | 71 | 4,336 | 343 | 68 | 89 |
- HTML: 3,576
- PDF: 689
- XML: 71
- Total: 4,336
- Supplement: 343
- BibTeX: 68
- EndNote: 89
Total article views: 588 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Dec 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 331 | 252 | 5 | 588 | 155 | 3 | 5 |
- HTML: 331
- PDF: 252
- XML: 5
- Total: 588
- Supplement: 155
- BibTeX: 3
- EndNote: 5
Viewed (geographical distribution)
Total article views: 4,924 (including HTML, PDF, and XML)
Thereof 4,653 with geography defined
and 271 with unknown origin.
Total article views: 4,336 (including HTML, PDF, and XML)
Thereof 4,192 with geography defined
and 144 with unknown origin.
Total article views: 588 (including HTML, PDF, and XML)
Thereof 461 with geography defined
and 127 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
55 citations as recorded by crossref.
- Effect of ozone aging on light absorption and fluorescence of brown carbon in soot particles: The important role of polycyclic aromatic hydrocarbons Y. Kuang et al. 10.1016/j.jhazmat.2021.125406
- Significantly Accelerated Photosensitized Formation of Atmospheric Sulfate at the Air–Water Interface of Microdroplets W. Wang et al. 10.1021/jacs.3c11892
- Influence of Fuel Properties on the Light Absorption of Fresh and Laboratory-Aged Atmospheric Brown Carbon Produced from Realistic Combustion of Boreal Peat and Spruce Foliage M. Lyu et al. 10.1021/acs.est.1c07091
- Kinetics and Mass Yields of Aqueous Secondary Organic Aerosol from Highly Substituted Phenols Reacting with a Triplet Excited State L. Ma et al. 10.1021/acs.est.1c00575
- Chemical and Light-Absorption Properties of Water-Soluble Organic Aerosols in Northern California and Photooxidant Production by Brown Carbon Components W. Jiang et al. 10.1021/acsearthspacechem.3c00022
- Chemical Differences between Phenolic Secondary Organic Aerosol Formed through Gas-Phase and Aqueous-Phase Reactions W. Jiang et al. 10.1021/acsearthspacechem.4c00204
- Reactive Oxygen Species Production from Secondary Organic Aerosols: The Importance of Singlet Oxygen A. Manfrin et al. 10.1021/acs.est.9b01609
- Singlet Oxygen Quantum Yields in Environmental Waters R. Ossola et al. 10.1021/acs.chemrev.0c00781
- Sulfur radical formation from the tropospheric irradiation of aqueous sulfate aerosols J. Cope et al. 10.1073/pnas.2202857119
- Evaluation of Probes to Measure Oxidizing Organic Triplet Excited States in Aerosol Liquid Water L. Ma et al. 10.1021/acs.est.2c09672
- Singlet Oxygen Seasonality in Aqueous PM10 is Driven by Biomass Burning and Anthropogenic Secondary Organic Aerosol S. Bogler et al. 10.1021/acs.est.2c04554
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Aqueous ·OH Oxidation of Highly Substituted Phenols as a Source of Secondary Organic Aerosol S. Arciva et al. 10.1021/acs.est.2c02225
- Photosensitized Reactions of a Phenolic Carbonyl from Wood Combustion in the Aqueous Phase—Chemical Evolution and Light Absorption Properties of AqSOA W. Jiang et al. 10.1021/acs.est.0c07581
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al. 10.1029/2022JD038382
- Light Exposure of Wood Smoke Aerosol: Connecting Optical Properties, Oxidation, Radical Formation, and Chemical Composition C. Liu-Kang et al. 10.1021/acsestair.3c00063
- Modeling Novel Aqueous Particle and Cloud Chemistry Processes of Biomass Burning Phenols and Their Potential to Form Secondary Organic Aerosols J. Zhang et al. 10.1021/acs.est.3c07762
- Coupling Effect of Elemental Carbon and Organic Carbon on the Changes of Optical Properties and Oxidative Potential of Soot Particles under Visible Light R. Tang et al. 10.1021/acs.est.4c09217
- pH-Dependent Chemical Transformations of Humic-Like Substances and Further Cognitions Revealed by Optical Methods J. Qin et al. 10.1021/acs.est.1c07729
- Photochemical Aging of Atmospheric Particulate Matter in the Aqueous Phase F. Leresche et al. 10.1021/acs.est.1c00978
- Aqueous secondary organic aerosol formation attributed to phenols from biomass burning Y. Xiao et al. 10.1016/j.scitotenv.2022.157582
- Statistical analysis of experimental factors for synthesis of copper oxide and tin oxide for antibacterial applications M. Rezayat et al. 10.1007/s00170-023-11728-z
- Complexities of Photosensitization in Atmospheric Particles Z. Liang et al. 10.1021/acsestair.4c00112
- Predicting photooxidant concentrations in aerosol liquid water based on laboratory extracts of ambient particles L. Ma et al. 10.5194/acp-23-8805-2023
- Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles L. Ma et al. 10.5194/acp-24-1-2024
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al. 10.1016/j.scitotenv.2023.164455
- Formation and loss of light absorbance by phenolic aqueous SOA by ●OH and an organic triplet excited state S. Arciva et al. 10.5194/acp-24-4473-2024
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Aqueous Radical Initiated Oxidation of an Organic Monolayer at the Air–Water Interface as a Proxy for Thin Films on Atmospheric Aerosol Studied with Neutron Reflectometry S. Jones et al. 10.1021/acs.jpca.3c03846
- Atmospheric Photosensitization: A New Pathway for Sulfate Formation X. Wang et al. 10.1021/acs.est.9b06347
- Wildfire particulate matter as a source of environmentally persistent free radicals and reactive oxygen species T. Fang et al. 10.1039/D2EA00170E
- Evaluating the potential secondary contribution of photosensitized chemistry to OH production in aqueous aerosols E. Petersen-Sonn et al. 10.1039/D4EA00103F
- Asphalt-related emissions are a major missing nontraditional source of secondary organic aerosol precursors P. Khare et al. 10.1126/sciadv.abb9785
- Interparticle Delivery and Detection of Volatile Singlet Oxygen at Air/Solid Interfaces A. Durantini & A. Greer 10.1021/acs.est.0c07922
- Singlet oxygen is produced from brown carbon-containing cooking organic aerosols (BrCOA) under indoor lighting N. Borduas-Dedekind et al. 10.1039/D3EA00167A
- Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol L. Fleming et al. 10.5194/acp-20-1105-2020
- Optical and chemical properties and oxidative potential of aqueous-phase products from OH and <sup>3</sup>C<sup>∗</sup>-initiated photooxidation of eugenol X. Li et al. 10.5194/acp-22-7793-2022
- Effect of Ammonium Salts on the Decarboxylation of Oxaloacetic Acid in Atmospheric Particles A. Klodt et al. 10.1021/acsearthspacechem.1c00025
- Sulfate formation via aerosol-phase SO2 oxidation by model biomass burning photosensitizers: 3,4-dimethoxybenzaldehyde, vanillin and syringaldehyde using single-particle mixing-state analysis L. Zhou et al. 10.5194/acp-23-5251-2023
- Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants W. Jiang et al. 10.5194/acp-23-7103-2023
- Effects of copper on chemical kinetics and brown carbon formation in the aqueous ˙OH oxidation of phenolic compounds J. Yang et al. 10.1039/D4EM00191E
- Photoenhanced Radical Formation in Aqueous Mixtures of Levoglucosan and Benzoquinone: Implications to Photochemical Aging of Biomass-Burning Organic Aerosols L. Gerritz et al. 10.1021/acs.jpca.3c01794
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Aqueous secondary organic aerosol formation from the direct photosensitized oxidation of vanillin in the absence and presence of ammonium nitrate B. Go et al. 10.5194/acp-22-273-2022
- Seasonal variations in the production of singlet oxygen and organic triplet excited states in aqueous PM2.5 in Hong Kong SAR, South China Y. Lyu et al. 10.5194/acp-23-9245-2023
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Characteristics, primary sources and secondary formation of water-soluble organic aerosols in downtown Beijing Q. Yu et al. 10.5194/acp-21-1775-2021
- Gas-phase brown carbon: Absorbance and chromophore types Q. Chen et al. 10.1016/j.atmosenv.2021.118646
- Five-Membered Heterocycles as Potential Photosensitizers in the Tropospheric Aqueous Phase: Photophysical Properties of Imidazole-2-carboxaldehyde, 2-Furaldehyde, and 2-Acetylfuran T. Felber et al. 10.1021/acs.jpca.0c07028
- Aqueous-phase chemistry of atmospheric phenolic compounds: A critical review of laboratory studies F. Li et al. 10.1016/j.scitotenv.2022.158895
- Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols R. Lai et al. 10.1016/j.atmosenv.2024.120895
- New formation and fate of Isoprene SOA markers revealed by field data-constrained modeling J. Zhang et al. 10.1038/s41612-023-00394-3
- Triplet-state organic matter in atmospheric aerosols: Formation characteristics and potential effects on aerosol aging Q. Chen et al. 10.1016/j.atmosenv.2021.118343
- Photosensitized Reactions of a Phenolic Carbonyl from Wood Combustion in the Aqueous Phase—Chemical Evolution and Light Absorption Properties of AqSOA W. Jiang et al. 10.1021/acs.est.0c07581
- Aqueous reactions of organic triplet excited states with atmospheric alkenes R. Kaur et al. 10.5194/acp-19-5021-2019
53 citations as recorded by crossref.
- Effect of ozone aging on light absorption and fluorescence of brown carbon in soot particles: The important role of polycyclic aromatic hydrocarbons Y. Kuang et al. 10.1016/j.jhazmat.2021.125406
- Significantly Accelerated Photosensitized Formation of Atmospheric Sulfate at the Air–Water Interface of Microdroplets W. Wang et al. 10.1021/jacs.3c11892
- Influence of Fuel Properties on the Light Absorption of Fresh and Laboratory-Aged Atmospheric Brown Carbon Produced from Realistic Combustion of Boreal Peat and Spruce Foliage M. Lyu et al. 10.1021/acs.est.1c07091
- Kinetics and Mass Yields of Aqueous Secondary Organic Aerosol from Highly Substituted Phenols Reacting with a Triplet Excited State L. Ma et al. 10.1021/acs.est.1c00575
- Chemical and Light-Absorption Properties of Water-Soluble Organic Aerosols in Northern California and Photooxidant Production by Brown Carbon Components W. Jiang et al. 10.1021/acsearthspacechem.3c00022
- Chemical Differences between Phenolic Secondary Organic Aerosol Formed through Gas-Phase and Aqueous-Phase Reactions W. Jiang et al. 10.1021/acsearthspacechem.4c00204
- Reactive Oxygen Species Production from Secondary Organic Aerosols: The Importance of Singlet Oxygen A. Manfrin et al. 10.1021/acs.est.9b01609
- Singlet Oxygen Quantum Yields in Environmental Waters R. Ossola et al. 10.1021/acs.chemrev.0c00781
- Sulfur radical formation from the tropospheric irradiation of aqueous sulfate aerosols J. Cope et al. 10.1073/pnas.2202857119
- Evaluation of Probes to Measure Oxidizing Organic Triplet Excited States in Aerosol Liquid Water L. Ma et al. 10.1021/acs.est.2c09672
- Singlet Oxygen Seasonality in Aqueous PM10 is Driven by Biomass Burning and Anthropogenic Secondary Organic Aerosol S. Bogler et al. 10.1021/acs.est.2c04554
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Aqueous ·OH Oxidation of Highly Substituted Phenols as a Source of Secondary Organic Aerosol S. Arciva et al. 10.1021/acs.est.2c02225
- Photosensitized Reactions of a Phenolic Carbonyl from Wood Combustion in the Aqueous Phase—Chemical Evolution and Light Absorption Properties of AqSOA W. Jiang et al. 10.1021/acs.est.0c07581
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al. 10.1029/2022JD038382
- Light Exposure of Wood Smoke Aerosol: Connecting Optical Properties, Oxidation, Radical Formation, and Chemical Composition C. Liu-Kang et al. 10.1021/acsestair.3c00063
- Modeling Novel Aqueous Particle and Cloud Chemistry Processes of Biomass Burning Phenols and Their Potential to Form Secondary Organic Aerosols J. Zhang et al. 10.1021/acs.est.3c07762
- Coupling Effect of Elemental Carbon and Organic Carbon on the Changes of Optical Properties and Oxidative Potential of Soot Particles under Visible Light R. Tang et al. 10.1021/acs.est.4c09217
- pH-Dependent Chemical Transformations of Humic-Like Substances and Further Cognitions Revealed by Optical Methods J. Qin et al. 10.1021/acs.est.1c07729
- Photochemical Aging of Atmospheric Particulate Matter in the Aqueous Phase F. Leresche et al. 10.1021/acs.est.1c00978
- Aqueous secondary organic aerosol formation attributed to phenols from biomass burning Y. Xiao et al. 10.1016/j.scitotenv.2022.157582
- Statistical analysis of experimental factors for synthesis of copper oxide and tin oxide for antibacterial applications M. Rezayat et al. 10.1007/s00170-023-11728-z
- Complexities of Photosensitization in Atmospheric Particles Z. Liang et al. 10.1021/acsestair.4c00112
- Predicting photooxidant concentrations in aerosol liquid water based on laboratory extracts of ambient particles L. Ma et al. 10.5194/acp-23-8805-2023
- Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles L. Ma et al. 10.5194/acp-24-1-2024
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al. 10.1016/j.scitotenv.2023.164455
- Formation and loss of light absorbance by phenolic aqueous SOA by ●OH and an organic triplet excited state S. Arciva et al. 10.5194/acp-24-4473-2024
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Aqueous Radical Initiated Oxidation of an Organic Monolayer at the Air–Water Interface as a Proxy for Thin Films on Atmospheric Aerosol Studied with Neutron Reflectometry S. Jones et al. 10.1021/acs.jpca.3c03846
- Atmospheric Photosensitization: A New Pathway for Sulfate Formation X. Wang et al. 10.1021/acs.est.9b06347
- Wildfire particulate matter as a source of environmentally persistent free radicals and reactive oxygen species T. Fang et al. 10.1039/D2EA00170E
- Evaluating the potential secondary contribution of photosensitized chemistry to OH production in aqueous aerosols E. Petersen-Sonn et al. 10.1039/D4EA00103F
- Asphalt-related emissions are a major missing nontraditional source of secondary organic aerosol precursors P. Khare et al. 10.1126/sciadv.abb9785
- Interparticle Delivery and Detection of Volatile Singlet Oxygen at Air/Solid Interfaces A. Durantini & A. Greer 10.1021/acs.est.0c07922
- Singlet oxygen is produced from brown carbon-containing cooking organic aerosols (BrCOA) under indoor lighting N. Borduas-Dedekind et al. 10.1039/D3EA00167A
- Molecular composition and photochemical lifetimes of brown carbon chromophores in biomass burning organic aerosol L. Fleming et al. 10.5194/acp-20-1105-2020
- Optical and chemical properties and oxidative potential of aqueous-phase products from OH and <sup>3</sup>C<sup>∗</sup>-initiated photooxidation of eugenol X. Li et al. 10.5194/acp-22-7793-2022
- Effect of Ammonium Salts on the Decarboxylation of Oxaloacetic Acid in Atmospheric Particles A. Klodt et al. 10.1021/acsearthspacechem.1c00025
- Sulfate formation via aerosol-phase SO2 oxidation by model biomass burning photosensitizers: 3,4-dimethoxybenzaldehyde, vanillin and syringaldehyde using single-particle mixing-state analysis L. Zhou et al. 10.5194/acp-23-5251-2023
- Photoaging of phenolic secondary organic aerosol in the aqueous phase: evolution of chemical and optical properties and effects of oxidants W. Jiang et al. 10.5194/acp-23-7103-2023
- Effects of copper on chemical kinetics and brown carbon formation in the aqueous ˙OH oxidation of phenolic compounds J. Yang et al. 10.1039/D4EM00191E
- Photoenhanced Radical Formation in Aqueous Mixtures of Levoglucosan and Benzoquinone: Implications to Photochemical Aging of Biomass-Burning Organic Aerosols L. Gerritz et al. 10.1021/acs.jpca.3c01794
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Aqueous secondary organic aerosol formation from the direct photosensitized oxidation of vanillin in the absence and presence of ammonium nitrate B. Go et al. 10.5194/acp-22-273-2022
- Seasonal variations in the production of singlet oxygen and organic triplet excited states in aqueous PM2.5 in Hong Kong SAR, South China Y. Lyu et al. 10.5194/acp-23-9245-2023
- Overview of the Alaskan Layered Pollution and Chemical Analysis (ALPACA) Field Experiment W. Simpson et al. 10.1021/acsestair.3c00076
- Characteristics, primary sources and secondary formation of water-soluble organic aerosols in downtown Beijing Q. Yu et al. 10.5194/acp-21-1775-2021
- Gas-phase brown carbon: Absorbance and chromophore types Q. Chen et al. 10.1016/j.atmosenv.2021.118646
- Five-Membered Heterocycles as Potential Photosensitizers in the Tropospheric Aqueous Phase: Photophysical Properties of Imidazole-2-carboxaldehyde, 2-Furaldehyde, and 2-Acetylfuran T. Felber et al. 10.1021/acs.jpca.0c07028
- Aqueous-phase chemistry of atmospheric phenolic compounds: A critical review of laboratory studies F. Li et al. 10.1016/j.scitotenv.2022.158895
- Deciphering the key drivers of oxidative potential during ammonium nitrate-mediated aqueous-phase photoreaction of methoxyphenols R. Lai et al. 10.1016/j.atmosenv.2024.120895
- New formation and fate of Isoprene SOA markers revealed by field data-constrained modeling J. Zhang et al. 10.1038/s41612-023-00394-3
- Triplet-state organic matter in atmospheric aerosols: Formation characteristics and potential effects on aerosol aging Q. Chen et al. 10.1016/j.atmosenv.2021.118343
2 citations as recorded by crossref.
- Photosensitized Reactions of a Phenolic Carbonyl from Wood Combustion in the Aqueous Phase—Chemical Evolution and Light Absorption Properties of AqSOA W. Jiang et al. 10.1021/acs.est.0c07581
- Aqueous reactions of organic triplet excited states with atmospheric alkenes R. Kaur et al. 10.5194/acp-19-5021-2019
Latest update: 25 Dec 2024
Short summary
We measured hydroxyl radical (•OH), singlet oxygen (1O2*), and organic triplets (3C*) in illuminated aqueous particle extracts. After measuring the impact of dilution on oxidant concentrations, we extrapolated our results to predict them in ambient particles – 1O2* and 3C* concentrations appear to be greatly enhanced, while •OH appears largely unchanged. Two of these oxidants (1O2*, 3C*) are not yet included in atmospheric models, and our results make it possible to include them in the future.
We measured hydroxyl radical (•OH), singlet oxygen (1O2*), and organic triplets (3C*) in...
Altmetrics
Final-revised paper
Preprint