Articles | Volume 19, issue 6
https://doi.org/10.5194/acp-19-3981-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-3981-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
The role of chlorine in global tropospheric chemistry
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts, USA
Daniel J. Jacob
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts, USA
Department of Earth and Planetary Sciences, Harvard
University, Cambridge, Massachusetts, USA
Sebastian D. Eastham
Laboratory for Aviation and the Environment, Massachusetts
Institute of Technology, Cambridge, Massachusetts, USA
Melissa P. Sulprizio
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts, USA
School of Engineering and Applied Sciences, Harvard University,
Cambridge, Massachusetts, USA
Qianjie Chen
Department of Chemistry, University of Michigan, Ann Arbor, Michigan,
USA
Becky Alexander
Department of Atmospheric Sciences, University of Washington,
Seattle, USA
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York,
UK
Mathew J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, UK
National Centre for Atmospheric Science, University of York, York,
UK
Ben H. Lee
Department of Atmospheric Sciences, University of Washington,
Seattle, USA
Jessica D. Haskins
Department of Atmospheric Sciences, University of Washington,
Seattle, USA
Felipe D. Lopez-Hilfiker
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, Villigen, Switzerland
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington,
Seattle, USA
Gregory L. Huey
School of Earth and Atmospheric Science, Georgia Institute of
Technology, Atlanta, GA, USA
Hong Liao
School of Environmental Science and Engineering, Nanjing
University
of Information Science and Technology, Nanjing, China
Viewed
Total article views: 9,904 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Oct 2018)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
6,436 | 3,369 | 99 | 9,904 | 352 | 113 | 205 |
- HTML: 6,436
- PDF: 3,369
- XML: 99
- Total: 9,904
- Supplement: 352
- BibTeX: 113
- EndNote: 205
Total article views: 8,135 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 29 Mar 2019)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
5,592 | 2,465 | 78 | 8,135 | 352 | 103 | 190 |
- HTML: 5,592
- PDF: 2,465
- XML: 78
- Total: 8,135
- Supplement: 352
- BibTeX: 103
- EndNote: 190
Total article views: 1,769 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Oct 2018)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
844 | 904 | 21 | 1,769 | 10 | 15 |
- HTML: 844
- PDF: 904
- XML: 21
- Total: 1,769
- BibTeX: 10
- EndNote: 15
Viewed (geographical distribution)
Total article views: 9,904 (including HTML, PDF, and XML)
Thereof 9,688 with geography defined
and 216 with unknown origin.
Total article views: 8,135 (including HTML, PDF, and XML)
Thereof 8,002 with geography defined
and 133 with unknown origin.
Total article views: 1,769 (including HTML, PDF, and XML)
Thereof 1,686 with geography defined
and 83 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
181 citations as recorded by crossref.
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Cl atom initiated tropospheric chemistry of ethyl butyrate C. Ramya & B. Rajakumar 10.1016/j.cplett.2019.136594
- Significant chlorine emissions from biomass burning affect the long-term atmospheric chemistry in Asia D. Chang et al. 10.1093/nsr/nwae285
- Is oxidation of atmospheric mercury controlled by different mechanisms in the polluted continental boundary layer vs. remote marine boundary layer? M. Gabay et al. 10.1088/1748-9326/ab7b26
- Clumped‐Isotope Constraint on Upper‐Tropospheric Cooling During the Last Glacial Maximum A. Banerjee et al. 10.1029/2022AV000688
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. 10.1029/2023JD039091
- Significant Decrease in Wet Deposition of Anthropogenic Chloride Across the Eastern United States, 1998–2018 J. Haskins et al. 10.1029/2020GL090195
- Product State-Resolved Reactive Scattering Studies of the H + Cl2 (v0 = 1–3, j0 = 0) → HCl + Cl Reaction by the Time-Dependent Wave Packet Method H. Chang et al. 10.1021/acs.jpca.4c01062
- Potential Effect of Halogens on Atmospheric Oxidation and Air Quality in China Q. Li et al. 10.1029/2019JD032058
- N<sub>2</sub>O<sub>5</sub> uptake onto saline mineral dust: a potential missing source of tropospheric ClNO<sub>2</sub> in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- On the Causes and Consequences of Recent Trends in Atmospheric Methane H. Schaefer 10.1007/s40641-019-00140-z
- Tropospheric chemistry of ethyl tiglate initiated by Cl atoms C. Ramya & B. Rajakumar 10.1016/j.cplett.2020.137371
- Formation and impacts of nitryl chloride in Pearl River Delta H. Wang et al. 10.5194/acp-22-14837-2022
- Global methane budget and trend, 2010–2017: complementarity of inverse analyses using in situ (GLOBALVIEWplus CH<sub>4</sub> ObsPack) and satellite (GOSAT) observations X. Lu et al. 10.5194/acp-21-4637-2021
- Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates T. Yang et al. 10.1021/acs.estlett.4c00522
- Attribution of the accelerating increase in atmospheric methane during 2010–2018 by inverse analysis of GOSAT observations Y. Zhang et al. 10.5194/acp-21-3643-2021
- Wintertime Particulate Matter Decrease Buffered by Unfavorable Chemical Processes Despite Emissions Reductions in China D. Leung et al. 10.1029/2020GL087721
- Fast near-surface ClNO2 production and its impact on O3 formation during a heavy pollution event in South China X. Chen et al. 10.1016/j.scitotenv.2022.159998
- Opinion: A research roadmap for exploring atmospheric methane removal via iron salt aerosol K. Gorham et al. 10.5194/acp-24-5659-2024
- Wet deposition chemistry and neutralization potential in oil producing region of southern Nigeria E. Ubuoh et al. 10.1016/j.jenvman.2021.112431
- Underestimated Passive Volcanic Sulfur Degassing Implies Overestimated Anthropogenic Aerosol Forcing U. Jongebloed et al. 10.1029/2022GL102061
- Increasing contribution of nighttime nitrogen chemistry to wintertime haze formation in Beijing observed during COVID-19 lockdowns C. Yan et al. 10.1038/s41561-023-01285-1
- Cl atoms-initiated degradation of 1-Chlorobutane and 2-Chlorobutane: Kinetics, product analysis and atmospheric implications B. Kar & B. Rajakumar 10.1016/j.chemosphere.2023.139664
- Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial S. Zhai et al. 10.1029/2021GL093808
- CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e) E. Hoffmann et al. 10.5194/gmd-13-2587-2020
- Characteristics of PM2.5 Pollution in Osorno, Chile: Ion Chromatography and Meteorological Data Analyses A. Nakamura et al. 10.3390/atmos13020168
- Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation R. Cheramangalath Balan & B. Rajakumar 10.1021/acs.jpca.9b02225
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
- Comparison of model and ground observations finds snowpack and blowing snow aerosols both contribute to Arctic tropospheric reactive bromine W. Swanson et al. 10.5194/acp-22-14467-2022
- Photochemical activity of water-soluble organic compounds in motor vehicle exhaust particulate matter Y. Huang et al. 10.1016/j.chemosphere.2024.143270
- Diurnal photodegradation of fluorinated diketones (FDKs) by OH radicals using different atmospheric simulation chambers: Role of keto-enol tautomerization on reactivity P. Lugo et al. 10.1016/j.chemosphere.2021.131562
- Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere G. Novak et al. 10.5194/acp-22-6309-2022
- Modeling the Oxygen Isotope Anomaly (Δ17O) of Reactive Nitrogen in the Community Multiscale Air Quality Model: Insights into Nitrogen Oxide Chemistry in the Northeastern United States W. Walters et al. 10.1021/acsestair.3c00056
- Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century Q. Li et al. 10.1038/s41467-022-30456-8
- Photochemistry of the Cloud Aqueous Phase: A Review A. Bianco et al. 10.3390/molecules25020423
- Shipborne measurements of ClNO<sub>2</sub> in the Mediterranean Sea and around the Arabian Peninsula during summer P. Eger et al. 10.5194/acp-19-12121-2019
- Theoretical study on the mechanisms, kinetics and risk assessment of OH radicals and Cl atom initiated transformation of HCFC-235fa in the atmosphere T. Chi et al. 10.1039/D4CP02323D
- Kinetic study of the atmospheric oxidation of a series of epoxy compounds by OH radicals C. Tovar et al. 10.5194/acp-22-6989-2022
- New Potential Energy Surface for the H + Cl2 Reaction and Quantum Dynamics Studies H. Chang et al. 10.1021/acs.jpca.4c00542
- Rapid cloud removal of dimethyl sulfide oxidation products limits SO 2 and cloud condensation nuclei production in the marine atmosphere G. Novak et al. 10.1073/pnas.2110472118
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- Significant production of ClNO<sub>2</sub> and possible source of Cl<sub>2</sub> from N<sub>2</sub>O<sub>5</sub> uptake at a suburban site in eastern China M. Xia et al. 10.5194/acp-20-6147-2020
- Impacts of ocean biogeochemistry on atmospheric chemistry L. Tinel et al. 10.1525/elementa.2023.00032
- Anthropogenic Photolabile Chlorine in the Cold-Climate City of Montreal R. Hall et al. 10.3390/atmos11080812
- Global Emissions of Hydrogen Chloride and Particulate Chloride from Continental Sources B. Zhang et al. 10.1021/acs.est.1c05634
- Impact and pathway of halogens on atmospheric oxidants in coastal city clusters in the Yangtze River Delta region in China H. Chen et al. 10.1016/j.apr.2023.101979
- An experimental study of the gas-phase reaction between Cl atoms and trans-2-pentenal: Kinetics, products and SOA formation A. Grira et al. 10.1016/j.chemosphere.2021.130193
- How do Cl concentrations matter for the simulation of CH4 and δ13C(CH4) and estimation of the CH4 budget through atmospheric inversions? J. Thanwerdas et al. 10.5194/acp-22-15489-2022
- Air Pollution and Climate Forcing of the Charcoal Industry in Africa A. Bockarie et al. 10.1021/acs.est.0c03754
- A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases T. Ming et al. 10.1016/j.apr.2021.02.017
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS J. Halfacre et al. 10.5194/amt-16-1407-2023
- Large Daytime Molecular Chlorine Missing Source at a Suburban Site in East China Q. Chen et al. 10.1029/2021JD035796
- The impact of chlorine chemistry combined with heterogeneous N<sub>2</sub>O<sub>5</sub> reactions on air quality in China X. Yang et al. 10.5194/acp-22-3743-2022
- Inverse modeling of 2010–2022 satellite observations shows that inundation of the wet tropics drove the 2020–2022 methane surge Z. Qu et al. 10.1073/pnas.2402730121
- Rainwater chemistry of acid precipitation occurrences due to long-range transboundary haze pollution and prolonged drought events during southwest monsoon season: climate change driven C. Payus et al. 10.1016/j.heliyon.2020.e04997
- What do we know about the global methane budget? Results from four decades of atmospheric CH4observations and the way forward X. Lan et al. 10.1098/rsta.2020.0440
- Atmospheric-methane source and sink sensitivity analysis using Gaussian process emulation A. Stell et al. 10.5194/acp-21-1717-2021
- Amazon methane budget derived from multi-year airborne observations highlights regional variations in emissions L. Basso et al. 10.1038/s43247-021-00314-4
- Impact of interannual and multidecadal trends on methane-climate feedbacks and sensitivity C. Cheng & S. Redfern 10.1038/s41467-022-31345-w
- Chemical characteristics of wintertime aerosol and cloud over the Sea of Japan based on aircraft and ground measurements M. Kagawa et al. 10.1016/j.apr.2023.101650
- Efficient Production of Carbonyl Sulfide in the Low‐NOx Oxidation of Dimethyl Sulfide C. Jernigan et al. 10.1029/2021GL096838
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Atmospheric fate of formyl chloride and mechanisms of the gas-phase reactions with OH radicals and Cl atoms S. Vijayakumar & D. Wilmouth 10.1016/j.cplett.2021.138709
- Physical and practical constraints on atmospheric methane removal technologies L. Pennacchio et al. 10.1088/1748-9326/ad7041
- Multidecadal increases in global tropospheric ozone derived from ozonesonde and surface site observations: can models reproduce ozone trends? A. Christiansen et al. 10.5194/acp-22-14751-2022
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Reaction of Cl Atom with c-C5F8 and c-C5HF7: Relative and Absolute Measurements of Rate Coefficients and Identification of Degradation Products T. Gierczak et al. 10.1021/acs.jpca.2c05041
- Description of the NASA GEOS Composition Forecast Modeling System GEOS‐CF v1.0 C. Keller et al. 10.1029/2020MS002413
- Trends in atmospheric methane concentrations since 1990 were driven and modified by anthropogenic emissions R. Skeie et al. 10.1038/s43247-023-00969-1
- Comparing the Importance of Iodine and Isoprene on Tropospheric Photochemistry R. Pound et al. 10.1029/2022GL100997
- A combined experimental and computational investigation on the OH radical and Cl atom-initiated reaction of 2,3-dichloropropene in troposphere G. Madhu & B. Rajakumar 10.1016/j.chemosphere.2024.142566
- Daytime Atmospheric Halogen Cycling through Aqueous-Phase Oxygen Atom Chemistry E. Dalton et al. 10.1021/jacs.3c03112
- Identifying Driving Factors of Atmospheric N2O5 with Machine Learning X. Chen et al. 10.1021/acs.est.4c00651
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
- Potential environmental impact of the chlorine-containing disinfectants usage during the COVID-19 X. Yi et al. 10.1016/j.atmosenv.2024.120734
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Effects of Anthropogenic Chlorine on PM2.5 and Ozone Air Quality in China X. Wang et al. 10.1021/acs.est.0c02296
- OH radical and Cl atom initiated Reactions of Methyl n-propyl ether: Kinetics and Atmospheric Implications B. Kar & B. Rajakumar 10.1016/j.atmosenv.2024.120717
- Ammonium Chloride Associated Aerosol Liquid Water Enhances Haze in Delhi, India Y. Chen et al. 10.1021/acs.est.2c00650
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
- Trends in global tropospheric hydroxyl radical and methane lifetime since 1850 from AerChemMIP D. Stevenson et al. 10.5194/acp-20-12905-2020
- Atmospheric gaseous hydrochloric and hydrobromic acid in urban Beijing, China: detection, source identification and potential atmospheric impacts X. Fan et al. 10.5194/acp-21-11437-2021
- Local and regional air pollution characteristics in Cyprus: A long-term trace gases observations analysis M. Vrekoussis et al. 10.1016/j.scitotenv.2022.157315
- The role of sources and meteorology in driving PM2.5-bound chlorine X. Wang et al. 10.1016/j.jhazmat.2022.129910
- Effect of bromine and iodine chemistry on tropospheric ozone over Asia-Pacific using the CMAQ model Y. Huang et al. 10.1016/j.chemosphere.2020.127595
- Heterogeneous Reactions of Methane with Cl Radicals on Large ArN Clusters V. Poterya et al. 10.1021/acs.jpca.1c08476
- Global environmental implications of atmospheric methane removal through chlorine-mediated chemistry-climate interactions Q. Li et al. 10.1038/s41467-023-39794-7
- Hydrogen peroxide serves as pivotal fountainhead for aerosol aqueous sulfate formation from a global perspective J. Gao et al. 10.1038/s41467-024-48793-1
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Observation of Road Salt Aerosol Driving Inland Wintertime Atmospheric Chlorine Chemistry S. McNamara et al. 10.1021/acscentsci.9b00994
- The consolidated European synthesis of CH4 and N2O emissions for the European Union and United Kingdom: 1990–2019 A. Petrescu et al. 10.5194/essd-15-1197-2023
- Integration of airborne and ground observations of nitryl chloride in the Seoul metropolitan area and the implications on regional oxidation capacity during KORUS-AQ 2016 D. Jeong et al. 10.5194/acp-19-12779-2019
- GCAP 2.0: a global 3-D chemical-transport model framework for past, present, and future climate scenarios L. Murray et al. 10.5194/gmd-14-5789-2021
- Atmospheric chemistry of (Z)‐CF2HCF=CHCl: Kinetics and products of reaction with Cl atoms and OH radicals M. Sulbaek Andersen et al. 10.1002/kin.21763
- The Global Methane Budget 2000–2017 M. Saunois et al. 10.5194/essd-12-1561-2020
- Atmospheric Chemistry of Oxalate: Insight Into the Role of Relative Humidity and Aerosol Acidity From High‐Resolution Observation C. Yang et al. 10.1029/2021JD035364
- Measurements and Modeling of the Interhemispheric Differences of Atmospheric Chlorinated Very Short‐Lived Substances B. Roozitalab et al. 10.1029/2023JD039518
- Technical note: Influence of different averaging metrics and temporal resolutions on the aerosol pH calculated by thermodynamic modeling H. Wang et al. 10.5194/acp-24-6583-2024
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Atmospheric Research Over the Western North Atlantic Ocean Region and North American East Coast: A Review of Past Work and Challenges Ahead A. Sorooshian et al. 10.1029/2019JD031626
- Improved Mechanistic Model of the Atmospheric Redox Chemistry of Mercury V. Shah et al. 10.1021/acs.est.1c03160
- Understanding Sources of Atmospheric Hydrogen Chloride in Coastal Spring and Continental Winter A. Angelucci et al. 10.1021/acsearthspacechem.1c00193
- Simulations of aerosol pH in China using WRF-Chem (v4.0): sensitivities of aerosol pH and its temporal variations during haze episodes X. Ruan et al. 10.5194/gmd-15-6143-2022
- Strong sensitivity of the isotopic composition of methane to the plausible range of tropospheric chlorine S. Strode et al. 10.5194/acp-20-8405-2020
- Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks A. Christiansen et al. 10.5194/acp-24-4569-2024
- Impact of halogen chemistry on summertime air quality in coastal and continental Europe: application of the CMAQ model and implications for regulation Q. Li et al. 10.5194/acp-19-15321-2019
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
- The Role of Emission Sources and Atmospheric Sink in the Seasonal Cycle of CH4 and δ13-CH4: Analysis Based on the Atmospheric Chemistry Transport Model TM5 V. Kangasaho et al. 10.3390/atmos13060888
- Evaluating the Atmospheric Loss of H2 by NO3 Radicals: A Theoretical Study M. Romanias & T. Nguyen 10.3390/atmos13081313
- Retrieval of Stratospheric HNO3 and HCl Based on Ground-Based High-Resolution Fourier Transform Spectroscopy C. Shan et al. 10.3390/rs13112159
- Impacts of chlorine emissions on secondary pollutants in China Y. Zhang et al. 10.1016/j.atmosenv.2020.118177
- Performance and application of air quality models on ozone simulation in China – A review J. Yang & Y. Zhao 10.1016/j.atmosenv.2022.119446
- Methane emissions decreased in fossil fuel exploitation and sustainably increased in microbial source sectors during 1990–2020 N. Chandra et al. 10.1038/s43247-024-01286-x
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- Quantifying the Contributions of Aerosol- and Snow-Produced ClNO2 through Observations and 1D Modeling D. Jeong et al. 10.1021/acsearthspacechem.3c00237
- Natural short-lived halogens exert an indirect cooling effect on climate A. Saiz-Lopez et al. 10.1038/s41586-023-06119-z
- Estimating future climate change impacts on human mortality and crop yields via air pollution L. Murray et al. 10.1073/pnas.2400117121
- Bleach Emissions Interact Substantially with Surgical and KN95 Mask Surfaces N. Bhattacharyya et al. 10.1021/acs.est.2c07937
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Pre-deliquescent water uptake in deposited nanoparticles observed with in situ ambient pressure X-ray photoelectron spectroscopy J. Lin et al. 10.5194/acp-21-4709-2021
- The role of anthropogenic chlorine emission in surface ozone formation during different seasons over eastern China Y. Hong et al. 10.1016/j.scitotenv.2020.137697
- A machine-learning-guided adaptive algorithm to reduce the computational cost of integrating kinetics in global atmospheric chemistry models: application to GEOS-Chem versions 12.0.0 and 12.9.1 L. Shen et al. 10.5194/gmd-15-1677-2022
- OH + HCl Reaction on the Surface of Ice: An Ab Initio Molecular Dynamics Study A. Kumar & P. Kumar 10.1021/acs.jpca.1c10837
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- ACEIC: a comprehensive anthropogenic chlorine emission inventory for China S. Li et al. 10.5194/acp-24-11521-2024
- Atmospheric chemistry of molecular chlorine Q. Zang et al. 10.1360/TB-2024-0465
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride Y. Li et al. 10.1021/acs.estlett.9b00704
- Hydrogen Chloride (HCl) at Ground Sites During CalNex 2010 and Insight Into Its Thermodynamic Properties Y. Tao et al. 10.1029/2021JD036062
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Modelling wintertime sea-spray aerosols under Arctic haze conditions E. Ioannidis et al. 10.5194/acp-23-5641-2023
- Investigation of the global methane budget over 1980–2017 using GFDL-AM4.1 J. He et al. 10.5194/acp-20-805-2020
- Global Atmospheric Budget of Acetone: Air‐Sea Exchange and the Contribution to Hydroxyl Radicals S. Wang et al. 10.1029/2020JD032553
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al. 10.1029/2021GL097472
- The impact of sea-salt chloride on ozone through heterogeneous reaction with N2O5 in a coastal region of south China J. Dai et al. 10.1016/j.atmosenv.2020.117604
- Enhanced aerosol particle growth sustained by high continental chlorine emission in India S. Gunthe et al. 10.1038/s41561-020-00677-x
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Kinetics of hypochlorous acid reactions with organic and chloride-containing tropospheric aerosol S. Jorga et al. 10.1039/D3EM00292F
- Evaluating the potential of iron-based interventions in methane reduction and climate mitigation D. Meidan et al. 10.1088/1748-9326/ad3d72
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Isotope Data Constrains Redox Chemistry of Atmospheric Mercury Z. Song et al. 10.1021/acs.est.4c02600
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Impacts of global NO<sub><i>x</i></sub> inversions on NO<sub>2</sub> and ozone simulations Z. Qu et al. 10.5194/acp-20-13109-2020
- The consolidated European synthesis of CH4 and N2O emissions for the European Union and United Kingdom: 1990–2017 A. Petrescu et al. 10.5194/essd-13-2307-2021
- Application of Satellite‐Based Detections of Arctic Bromine Explosion Events Within GEOS‐Chem P. Wales et al. 10.1029/2022MS003465
- Observation of nitrogen oxide-influenced chlorine chemistry and source analysis of Cl2 in the Yangtze River Delta, China F. Li et al. 10.1016/j.atmosenv.2023.119829
- Global modeling of cloud water acidity, precipitation acidity, and acid inputs to ecosystems V. Shah et al. 10.5194/acp-20-12223-2020
- Interpretation of the effects of anthropogenic chlorine on nitrate formation over northeast Asia during KORUS-AQ 2016 H. Jo et al. 10.1016/j.scitotenv.2023.164920
- Implications of Snowpack Reactive Bromine Production for Arctic Ice Core Bromine Preservation S. Zhai et al. 10.1029/2023JD039257
- The driving effects of common atmospheric molecules for formation of clusters: the case of sulfuric acid, formic acid, hydrochloric acid, ammonia, and dimethylamine O. Longsworth et al. 10.1039/D3EA00087G
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al. 10.1016/j.atmosenv.2024.120747
- Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O<sub>3</sub> in the Arctic J. Huang et al. 10.5194/acp-20-7335-2020
- An unexpected large continental source of reactive bromine and chlorine with significant impact on wintertime air quality X. Peng et al. 10.1093/nsr/nwaa304
- Elevated levels of chloramines and chlorine detected near an indoor sports complex A. Angelucci et al. 10.1039/D2EM00411A
- Photodissociation of particulate nitrate as a source of daytime tropospheric Cl2 X. Peng et al. 10.1038/s41467-022-28383-9
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
- Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms: Reactivity trends, mechanism, and acid formation yields P. Lugo et al. 10.1016/j.jes.2024.02.033
- Atmospheric loss of nitrous oxide (N2O) is not influenced by its potential reactions with OH and NO3radicals A. Ravishankara et al. 10.1039/C9CP04818A
- Significant Impact of Reactive Chlorine on Complex Air Pollution Over the Yangtze River Delta Region, China X. Yi et al. 10.1029/2023JD038898
- Removal of Atmospheric Methane by Increasing Hydroxyl Radicals via a Water Vapor Enhancement Strategy Y. Liu et al. 10.3390/atmos15091046
- Global distribution of methane emissions, emission trends, and OH concentrations and trends inferred from an inversion of GOSAT satellite data for 2010–2015 J. Maasakkers et al. 10.5194/acp-19-7859-2019
- A review of atmospheric aging of sea spray aerosols: Potential factors affecting chloride depletion B. Su et al. 10.1016/j.atmosenv.2022.119365
- Mechanistic Insights into N2O5-Halide Ions Chemistry at the Air–Water Interface B. Tang et al. 10.1021/jacs.4c05850
- Photocatalytic chloride-to-chlorine conversion by ionic iron in aqueous aerosols: a combined experimental, quantum chemical, and chemical equilibrium model study M. Mikkelsen et al. 10.5194/ar-2-31-2024
- Development of the adjoint of the unified tropospheric–stratospheric chemistry extension (UCX) in GEOS-Chem adjoint v36 I. Dedoussi et al. 10.5194/gmd-17-5689-2024
- Impact of Molecular Chlorine Production from Aerosol Iron Photochemistry on Atmospheric Oxidative Capacity in North China Q. Chen et al. 10.1021/acs.est.4c02534
- Chlorinated and brominated polycyclic aromatic hydrocarbons: Sources, formation mechanisms, and occurrence in the environment R. Jin et al. 10.1016/j.pecs.2019.100803
- Photocatalytic chlorine atom production on mineral dust–sea spray aerosols over the North Atlantic M. van Herpen et al. 10.1073/pnas.2303974120
- Implementation and evaluation of the GEOS-Chem chemistry module version 13.1.2 within the Community Earth System Model v2.1 T. Fritz et al. 10.5194/gmd-15-8669-2022
- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
- Atmospheric methane and nitrous oxide: challenges alongthe path to Net Zero E. Nisbet et al. 10.1098/rsta.2020.0457
- Global distribution of methane emissions: a comparative inverse analysis of observations from the TROPOMI and GOSAT satellite instruments Z. Qu et al. 10.5194/acp-21-14159-2021
- Effect of sea salt aerosol on tropospheric bromine chemistry L. Zhu et al. 10.5194/acp-19-6497-2019
- Changes in atmospheric oxidants over Arctic Ocean atmosphere: evidence of oxygen isotope anomaly in nitrate aerosols Y. Zhang et al. 10.1038/s41612-023-00447-7
- Extracting a History of Global Fire Emissions for the Past Millennium From Ice Core Records of Acetylene, Ethane, and Methane M. Nicewonger et al. 10.1029/2020JD032932
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
- Observational Constraints on the Formation of Cl2 From the Reactive Uptake of ClNO2 on Aerosols in the Polluted Marine Boundary Layer J. Haskins et al. 10.1029/2019JD030627
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
179 citations as recorded by crossref.
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Cl atom initiated tropospheric chemistry of ethyl butyrate C. Ramya & B. Rajakumar 10.1016/j.cplett.2019.136594
- Significant chlorine emissions from biomass burning affect the long-term atmospheric chemistry in Asia D. Chang et al. 10.1093/nsr/nwae285
- Is oxidation of atmospheric mercury controlled by different mechanisms in the polluted continental boundary layer vs. remote marine boundary layer? M. Gabay et al. 10.1088/1748-9326/ab7b26
- Clumped‐Isotope Constraint on Upper‐Tropospheric Cooling During the Last Glacial Maximum A. Banerjee et al. 10.1029/2022AV000688
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. 10.1029/2023JD039091
- Significant Decrease in Wet Deposition of Anthropogenic Chloride Across the Eastern United States, 1998–2018 J. Haskins et al. 10.1029/2020GL090195
- Product State-Resolved Reactive Scattering Studies of the H + Cl2 (v0 = 1–3, j0 = 0) → HCl + Cl Reaction by the Time-Dependent Wave Packet Method H. Chang et al. 10.1021/acs.jpca.4c01062
- Potential Effect of Halogens on Atmospheric Oxidation and Air Quality in China Q. Li et al. 10.1029/2019JD032058
- N<sub>2</sub>O<sub>5</sub> uptake onto saline mineral dust: a potential missing source of tropospheric ClNO<sub>2</sub> in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- On the Causes and Consequences of Recent Trends in Atmospheric Methane H. Schaefer 10.1007/s40641-019-00140-z
- Tropospheric chemistry of ethyl tiglate initiated by Cl atoms C. Ramya & B. Rajakumar 10.1016/j.cplett.2020.137371
- Formation and impacts of nitryl chloride in Pearl River Delta H. Wang et al. 10.5194/acp-22-14837-2022
- Global methane budget and trend, 2010–2017: complementarity of inverse analyses using in situ (GLOBALVIEWplus CH<sub>4</sub> ObsPack) and satellite (GOSAT) observations X. Lu et al. 10.5194/acp-21-4637-2021
- Field Evidence for Constraints of Nearly Dry and Weakly Acidic Aerosol Conditions on the Formation of Organosulfates T. Yang et al. 10.1021/acs.estlett.4c00522
- Attribution of the accelerating increase in atmospheric methane during 2010–2018 by inverse analysis of GOSAT observations Y. Zhang et al. 10.5194/acp-21-3643-2021
- Wintertime Particulate Matter Decrease Buffered by Unfavorable Chemical Processes Despite Emissions Reductions in China D. Leung et al. 10.1029/2020GL087721
- Fast near-surface ClNO2 production and its impact on O3 formation during a heavy pollution event in South China X. Chen et al. 10.1016/j.scitotenv.2022.159998
- Opinion: A research roadmap for exploring atmospheric methane removal via iron salt aerosol K. Gorham et al. 10.5194/acp-24-5659-2024
- Wet deposition chemistry and neutralization potential in oil producing region of southern Nigeria E. Ubuoh et al. 10.1016/j.jenvman.2021.112431
- Underestimated Passive Volcanic Sulfur Degassing Implies Overestimated Anthropogenic Aerosol Forcing U. Jongebloed et al. 10.1029/2022GL102061
- Increasing contribution of nighttime nitrogen chemistry to wintertime haze formation in Beijing observed during COVID-19 lockdowns C. Yan et al. 10.1038/s41561-023-01285-1
- Cl atoms-initiated degradation of 1-Chlorobutane and 2-Chlorobutane: Kinetics, product analysis and atmospheric implications B. Kar & B. Rajakumar 10.1016/j.chemosphere.2023.139664
- Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial S. Zhai et al. 10.1029/2021GL093808
- CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e) E. Hoffmann et al. 10.5194/gmd-13-2587-2020
- Characteristics of PM2.5 Pollution in Osorno, Chile: Ion Chromatography and Meteorological Data Analyses A. Nakamura et al. 10.3390/atmos13020168
- Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation R. Cheramangalath Balan & B. Rajakumar 10.1021/acs.jpca.9b02225
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
- Comparison of model and ground observations finds snowpack and blowing snow aerosols both contribute to Arctic tropospheric reactive bromine W. Swanson et al. 10.5194/acp-22-14467-2022
- Photochemical activity of water-soluble organic compounds in motor vehicle exhaust particulate matter Y. Huang et al. 10.1016/j.chemosphere.2024.143270
- Diurnal photodegradation of fluorinated diketones (FDKs) by OH radicals using different atmospheric simulation chambers: Role of keto-enol tautomerization on reactivity P. Lugo et al. 10.1016/j.chemosphere.2021.131562
- Oceanic emissions of dimethyl sulfide and methanethiol and their contribution to sulfur dioxide production in the marine atmosphere G. Novak et al. 10.5194/acp-22-6309-2022
- Modeling the Oxygen Isotope Anomaly (Δ17O) of Reactive Nitrogen in the Community Multiscale Air Quality Model: Insights into Nitrogen Oxide Chemistry in the Northeastern United States W. Walters et al. 10.1021/acsestair.3c00056
- Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century Q. Li et al. 10.1038/s41467-022-30456-8
- Photochemistry of the Cloud Aqueous Phase: A Review A. Bianco et al. 10.3390/molecules25020423
- Shipborne measurements of ClNO<sub>2</sub> in the Mediterranean Sea and around the Arabian Peninsula during summer P. Eger et al. 10.5194/acp-19-12121-2019
- Theoretical study on the mechanisms, kinetics and risk assessment of OH radicals and Cl atom initiated transformation of HCFC-235fa in the atmosphere T. Chi et al. 10.1039/D4CP02323D
- Kinetic study of the atmospheric oxidation of a series of epoxy compounds by OH radicals C. Tovar et al. 10.5194/acp-22-6989-2022
- New Potential Energy Surface for the H + Cl2 Reaction and Quantum Dynamics Studies H. Chang et al. 10.1021/acs.jpca.4c00542
- Rapid cloud removal of dimethyl sulfide oxidation products limits SO 2 and cloud condensation nuclei production in the marine atmosphere G. Novak et al. 10.1073/pnas.2110472118
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- Significant production of ClNO<sub>2</sub> and possible source of Cl<sub>2</sub> from N<sub>2</sub>O<sub>5</sub> uptake at a suburban site in eastern China M. Xia et al. 10.5194/acp-20-6147-2020
- Impacts of ocean biogeochemistry on atmospheric chemistry L. Tinel et al. 10.1525/elementa.2023.00032
- Anthropogenic Photolabile Chlorine in the Cold-Climate City of Montreal R. Hall et al. 10.3390/atmos11080812
- Global Emissions of Hydrogen Chloride and Particulate Chloride from Continental Sources B. Zhang et al. 10.1021/acs.est.1c05634
- Impact and pathway of halogens on atmospheric oxidants in coastal city clusters in the Yangtze River Delta region in China H. Chen et al. 10.1016/j.apr.2023.101979
- An experimental study of the gas-phase reaction between Cl atoms and trans-2-pentenal: Kinetics, products and SOA formation A. Grira et al. 10.1016/j.chemosphere.2021.130193
- How do Cl concentrations matter for the simulation of CH4 and δ13C(CH4) and estimation of the CH4 budget through atmospheric inversions? J. Thanwerdas et al. 10.5194/acp-22-15489-2022
- Air Pollution and Climate Forcing of the Charcoal Industry in Africa A. Bockarie et al. 10.1021/acs.est.0c03754
- A nature-based negative emissions technology able to remove atmospheric methane and other greenhouse gases T. Ming et al. 10.1016/j.apr.2021.02.017
- Tropospheric Ozone Assessment Report A. Archibald et al. 10.1525/elementa.2020.034
- Using tunable infrared laser direct absorption spectroscopy for ambient hydrogen chloride detection: HCl-TILDAS J. Halfacre et al. 10.5194/amt-16-1407-2023
- Large Daytime Molecular Chlorine Missing Source at a Suburban Site in East China Q. Chen et al. 10.1029/2021JD035796
- The impact of chlorine chemistry combined with heterogeneous N<sub>2</sub>O<sub>5</sub> reactions on air quality in China X. Yang et al. 10.5194/acp-22-3743-2022
- Inverse modeling of 2010–2022 satellite observations shows that inundation of the wet tropics drove the 2020–2022 methane surge Z. Qu et al. 10.1073/pnas.2402730121
- Rainwater chemistry of acid precipitation occurrences due to long-range transboundary haze pollution and prolonged drought events during southwest monsoon season: climate change driven C. Payus et al. 10.1016/j.heliyon.2020.e04997
- What do we know about the global methane budget? Results from four decades of atmospheric CH4observations and the way forward X. Lan et al. 10.1098/rsta.2020.0440
- Atmospheric-methane source and sink sensitivity analysis using Gaussian process emulation A. Stell et al. 10.5194/acp-21-1717-2021
- Amazon methane budget derived from multi-year airborne observations highlights regional variations in emissions L. Basso et al. 10.1038/s43247-021-00314-4
- Impact of interannual and multidecadal trends on methane-climate feedbacks and sensitivity C. Cheng & S. Redfern 10.1038/s41467-022-31345-w
- Chemical characteristics of wintertime aerosol and cloud over the Sea of Japan based on aircraft and ground measurements M. Kagawa et al. 10.1016/j.apr.2023.101650
- Efficient Production of Carbonyl Sulfide in the Low‐NOx Oxidation of Dimethyl Sulfide C. Jernigan et al. 10.1029/2021GL096838
- Contribution of expanded marine sulfur chemistry to the seasonal variability of dimethyl sulfide oxidation products and size-resolved sulfate aerosol L. Tashmim et al. 10.5194/acp-24-3379-2024
- Atmospheric fate of formyl chloride and mechanisms of the gas-phase reactions with OH radicals and Cl atoms S. Vijayakumar & D. Wilmouth 10.1016/j.cplett.2021.138709
- Physical and practical constraints on atmospheric methane removal technologies L. Pennacchio et al. 10.1088/1748-9326/ad7041
- Multidecadal increases in global tropospheric ozone derived from ozonesonde and surface site observations: can models reproduce ozone trends? A. Christiansen et al. 10.5194/acp-22-14751-2022
- Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements V. Shah et al. 10.5194/acp-23-1227-2023
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Reaction of Cl Atom with c-C5F8 and c-C5HF7: Relative and Absolute Measurements of Rate Coefficients and Identification of Degradation Products T. Gierczak et al. 10.1021/acs.jpca.2c05041
- Description of the NASA GEOS Composition Forecast Modeling System GEOS‐CF v1.0 C. Keller et al. 10.1029/2020MS002413
- Trends in atmospheric methane concentrations since 1990 were driven and modified by anthropogenic emissions R. Skeie et al. 10.1038/s43247-023-00969-1
- Comparing the Importance of Iodine and Isoprene on Tropospheric Photochemistry R. Pound et al. 10.1029/2022GL100997
- A combined experimental and computational investigation on the OH radical and Cl atom-initiated reaction of 2,3-dichloropropene in troposphere G. Madhu & B. Rajakumar 10.1016/j.chemosphere.2024.142566
- Daytime Atmospheric Halogen Cycling through Aqueous-Phase Oxygen Atom Chemistry E. Dalton et al. 10.1021/jacs.3c03112
- Identifying Driving Factors of Atmospheric N2O5 with Machine Learning X. Chen et al. 10.1021/acs.est.4c00651
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
- Potential environmental impact of the chlorine-containing disinfectants usage during the COVID-19 X. Yi et al. 10.1016/j.atmosenv.2024.120734
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Effects of Anthropogenic Chlorine on PM2.5 and Ozone Air Quality in China X. Wang et al. 10.1021/acs.est.0c02296
- OH radical and Cl atom initiated Reactions of Methyl n-propyl ether: Kinetics and Atmospheric Implications B. Kar & B. Rajakumar 10.1016/j.atmosenv.2024.120717
- Ammonium Chloride Associated Aerosol Liquid Water Enhances Haze in Delhi, India Y. Chen et al. 10.1021/acs.est.2c00650
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
- Trends in global tropospheric hydroxyl radical and methane lifetime since 1850 from AerChemMIP D. Stevenson et al. 10.5194/acp-20-12905-2020
- Atmospheric gaseous hydrochloric and hydrobromic acid in urban Beijing, China: detection, source identification and potential atmospheric impacts X. Fan et al. 10.5194/acp-21-11437-2021
- Local and regional air pollution characteristics in Cyprus: A long-term trace gases observations analysis M. Vrekoussis et al. 10.1016/j.scitotenv.2022.157315
- The role of sources and meteorology in driving PM2.5-bound chlorine X. Wang et al. 10.1016/j.jhazmat.2022.129910
- Effect of bromine and iodine chemistry on tropospheric ozone over Asia-Pacific using the CMAQ model Y. Huang et al. 10.1016/j.chemosphere.2020.127595
- Heterogeneous Reactions of Methane with Cl Radicals on Large ArN Clusters V. Poterya et al. 10.1021/acs.jpca.1c08476
- Global environmental implications of atmospheric methane removal through chlorine-mediated chemistry-climate interactions Q. Li et al. 10.1038/s41467-023-39794-7
- Hydrogen peroxide serves as pivotal fountainhead for aerosol aqueous sulfate formation from a global perspective J. Gao et al. 10.1038/s41467-024-48793-1
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Observation of Road Salt Aerosol Driving Inland Wintertime Atmospheric Chlorine Chemistry S. McNamara et al. 10.1021/acscentsci.9b00994
- The consolidated European synthesis of CH4 and N2O emissions for the European Union and United Kingdom: 1990–2019 A. Petrescu et al. 10.5194/essd-15-1197-2023
- Integration of airborne and ground observations of nitryl chloride in the Seoul metropolitan area and the implications on regional oxidation capacity during KORUS-AQ 2016 D. Jeong et al. 10.5194/acp-19-12779-2019
- GCAP 2.0: a global 3-D chemical-transport model framework for past, present, and future climate scenarios L. Murray et al. 10.5194/gmd-14-5789-2021
- Atmospheric chemistry of (Z)‐CF2HCF=CHCl: Kinetics and products of reaction with Cl atoms and OH radicals M. Sulbaek Andersen et al. 10.1002/kin.21763
- The Global Methane Budget 2000–2017 M. Saunois et al. 10.5194/essd-12-1561-2020
- Atmospheric Chemistry of Oxalate: Insight Into the Role of Relative Humidity and Aerosol Acidity From High‐Resolution Observation C. Yang et al. 10.1029/2021JD035364
- Measurements and Modeling of the Interhemispheric Differences of Atmospheric Chlorinated Very Short‐Lived Substances B. Roozitalab et al. 10.1029/2023JD039518
- Technical note: Influence of different averaging metrics and temporal resolutions on the aerosol pH calculated by thermodynamic modeling H. Wang et al. 10.5194/acp-24-6583-2024
- Enhanced wintertime oxidation of VOCs via sustained radical sources in the urban atmosphere R. Sommariva et al. 10.1016/j.envpol.2021.116563
- Atmospheric Research Over the Western North Atlantic Ocean Region and North American East Coast: A Review of Past Work and Challenges Ahead A. Sorooshian et al. 10.1029/2019JD031626
- Improved Mechanistic Model of the Atmospheric Redox Chemistry of Mercury V. Shah et al. 10.1021/acs.est.1c03160
- Understanding Sources of Atmospheric Hydrogen Chloride in Coastal Spring and Continental Winter A. Angelucci et al. 10.1021/acsearthspacechem.1c00193
- Simulations of aerosol pH in China using WRF-Chem (v4.0): sensitivities of aerosol pH and its temporal variations during haze episodes X. Ruan et al. 10.5194/gmd-15-6143-2022
- Strong sensitivity of the isotopic composition of methane to the plausible range of tropospheric chlorine S. Strode et al. 10.5194/acp-20-8405-2020
- Constraining long-term NOx emissions over the United States and Europe using nitrate wet deposition monitoring networks A. Christiansen et al. 10.5194/acp-24-4569-2024
- Impact of halogen chemistry on summertime air quality in coastal and continental Europe: application of the CMAQ model and implications for regulation Q. Li et al. 10.5194/acp-19-15321-2019
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
- The Role of Emission Sources and Atmospheric Sink in the Seasonal Cycle of CH4 and δ13-CH4: Analysis Based on the Atmospheric Chemistry Transport Model TM5 V. Kangasaho et al. 10.3390/atmos13060888
- Evaluating the Atmospheric Loss of H2 by NO3 Radicals: A Theoretical Study M. Romanias & T. Nguyen 10.3390/atmos13081313
- Retrieval of Stratospheric HNO3 and HCl Based on Ground-Based High-Resolution Fourier Transform Spectroscopy C. Shan et al. 10.3390/rs13112159
- Impacts of chlorine emissions on secondary pollutants in China Y. Zhang et al. 10.1016/j.atmosenv.2020.118177
- Performance and application of air quality models on ozone simulation in China – A review J. Yang & Y. Zhao 10.1016/j.atmosenv.2022.119446
- Methane emissions decreased in fossil fuel exploitation and sustainably increased in microbial source sectors during 1990–2020 N. Chandra et al. 10.1038/s43247-024-01286-x
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- Quantifying the Contributions of Aerosol- and Snow-Produced ClNO2 through Observations and 1D Modeling D. Jeong et al. 10.1021/acsearthspacechem.3c00237
- Natural short-lived halogens exert an indirect cooling effect on climate A. Saiz-Lopez et al. 10.1038/s41586-023-06119-z
- Estimating future climate change impacts on human mortality and crop yields via air pollution L. Murray et al. 10.1073/pnas.2400117121
- Bleach Emissions Interact Substantially with Surgical and KN95 Mask Surfaces N. Bhattacharyya et al. 10.1021/acs.est.2c07937
- Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations B. Alexander et al. 10.5194/acp-20-3859-2020
- Pre-deliquescent water uptake in deposited nanoparticles observed with in situ ambient pressure X-ray photoelectron spectroscopy J. Lin et al. 10.5194/acp-21-4709-2021
- The role of anthropogenic chlorine emission in surface ozone formation during different seasons over eastern China Y. Hong et al. 10.1016/j.scitotenv.2020.137697
- A machine-learning-guided adaptive algorithm to reduce the computational cost of integrating kinetics in global atmospheric chemistry models: application to GEOS-Chem versions 12.0.0 and 12.9.1 L. Shen et al. 10.5194/gmd-15-1677-2022
- OH + HCl Reaction on the Surface of Ice: An Ab Initio Molecular Dynamics Study A. Kumar & P. Kumar 10.1021/acs.jpca.1c10837
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- ACEIC: a comprehensive anthropogenic chlorine emission inventory for China S. Li et al. 10.5194/acp-24-11521-2024
- Atmospheric chemistry of molecular chlorine Q. Zang et al. 10.1360/TB-2024-0465
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride Y. Li et al. 10.1021/acs.estlett.9b00704
- Hydrogen Chloride (HCl) at Ground Sites During CalNex 2010 and Insight Into Its Thermodynamic Properties Y. Tao et al. 10.1029/2021JD036062
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Modelling wintertime sea-spray aerosols under Arctic haze conditions E. Ioannidis et al. 10.5194/acp-23-5641-2023
- Investigation of the global methane budget over 1980–2017 using GFDL-AM4.1 J. He et al. 10.5194/acp-20-805-2020
- Global Atmospheric Budget of Acetone: Air‐Sea Exchange and the Contribution to Hydroxyl Radicals S. Wang et al. 10.1029/2020JD032553
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al. 10.1029/2021GL097472
- The impact of sea-salt chloride on ozone through heterogeneous reaction with N2O5 in a coastal region of south China J. Dai et al. 10.1016/j.atmosenv.2020.117604
- Enhanced aerosol particle growth sustained by high continental chlorine emission in India S. Gunthe et al. 10.1038/s41561-020-00677-x
- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Chemical precursors of new particle formation in coastal New Zealand M. Peltola et al. 10.5194/acp-23-3955-2023
- Kinetics of hypochlorous acid reactions with organic and chloride-containing tropospheric aerosol S. Jorga et al. 10.1039/D3EM00292F
- Evaluating the potential of iron-based interventions in methane reduction and climate mitigation D. Meidan et al. 10.1088/1748-9326/ad3d72
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Isotope Data Constrains Redox Chemistry of Atmospheric Mercury Z. Song et al. 10.1021/acs.est.4c02600
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- Impacts of global NO<sub><i>x</i></sub> inversions on NO<sub>2</sub> and ozone simulations Z. Qu et al. 10.5194/acp-20-13109-2020
- The consolidated European synthesis of CH4 and N2O emissions for the European Union and United Kingdom: 1990–2017 A. Petrescu et al. 10.5194/essd-13-2307-2021
- Application of Satellite‐Based Detections of Arctic Bromine Explosion Events Within GEOS‐Chem P. Wales et al. 10.1029/2022MS003465
- Observation of nitrogen oxide-influenced chlorine chemistry and source analysis of Cl2 in the Yangtze River Delta, China F. Li et al. 10.1016/j.atmosenv.2023.119829
- Global modeling of cloud water acidity, precipitation acidity, and acid inputs to ecosystems V. Shah et al. 10.5194/acp-20-12223-2020
- Interpretation of the effects of anthropogenic chlorine on nitrate formation over northeast Asia during KORUS-AQ 2016 H. Jo et al. 10.1016/j.scitotenv.2023.164920
- Implications of Snowpack Reactive Bromine Production for Arctic Ice Core Bromine Preservation S. Zhai et al. 10.1029/2023JD039257
- The driving effects of common atmospheric molecules for formation of clusters: the case of sulfuric acid, formic acid, hydrochloric acid, ammonia, and dimethylamine O. Longsworth et al. 10.1039/D3EA00087G
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al. 10.1016/j.atmosenv.2024.120747
- Evaluating the impact of blowing-snow sea salt aerosol on springtime BrO and O<sub>3</sub> in the Arctic J. Huang et al. 10.5194/acp-20-7335-2020
- An unexpected large continental source of reactive bromine and chlorine with significant impact on wintertime air quality X. Peng et al. 10.1093/nsr/nwaa304
- Elevated levels of chloramines and chlorine detected near an indoor sports complex A. Angelucci et al. 10.1039/D2EM00411A
- Photodissociation of particulate nitrate as a source of daytime tropospheric Cl2 X. Peng et al. 10.1038/s41467-022-28383-9
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
- Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms: Reactivity trends, mechanism, and acid formation yields P. Lugo et al. 10.1016/j.jes.2024.02.033
- Atmospheric loss of nitrous oxide (N2O) is not influenced by its potential reactions with OH and NO3radicals A. Ravishankara et al. 10.1039/C9CP04818A
- Significant Impact of Reactive Chlorine on Complex Air Pollution Over the Yangtze River Delta Region, China X. Yi et al. 10.1029/2023JD038898
- Removal of Atmospheric Methane by Increasing Hydroxyl Radicals via a Water Vapor Enhancement Strategy Y. Liu et al. 10.3390/atmos15091046
- Global distribution of methane emissions, emission trends, and OH concentrations and trends inferred from an inversion of GOSAT satellite data for 2010–2015 J. Maasakkers et al. 10.5194/acp-19-7859-2019
- A review of atmospheric aging of sea spray aerosols: Potential factors affecting chloride depletion B. Su et al. 10.1016/j.atmosenv.2022.119365
- Mechanistic Insights into N2O5-Halide Ions Chemistry at the Air–Water Interface B. Tang et al. 10.1021/jacs.4c05850
- Photocatalytic chloride-to-chlorine conversion by ionic iron in aqueous aerosols: a combined experimental, quantum chemical, and chemical equilibrium model study M. Mikkelsen et al. 10.5194/ar-2-31-2024
- Development of the adjoint of the unified tropospheric–stratospheric chemistry extension (UCX) in GEOS-Chem adjoint v36 I. Dedoussi et al. 10.5194/gmd-17-5689-2024
- Impact of Molecular Chlorine Production from Aerosol Iron Photochemistry on Atmospheric Oxidative Capacity in North China Q. Chen et al. 10.1021/acs.est.4c02534
- Chlorinated and brominated polycyclic aromatic hydrocarbons: Sources, formation mechanisms, and occurrence in the environment R. Jin et al. 10.1016/j.pecs.2019.100803
- Photocatalytic chlorine atom production on mineral dust–sea spray aerosols over the North Atlantic M. van Herpen et al. 10.1073/pnas.2303974120
- Implementation and evaluation of the GEOS-Chem chemistry module version 13.1.2 within the Community Earth System Model v2.1 T. Fritz et al. 10.5194/gmd-15-8669-2022
- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
- Atmospheric methane and nitrous oxide: challenges alongthe path to Net Zero E. Nisbet et al. 10.1098/rsta.2020.0457
- Global distribution of methane emissions: a comparative inverse analysis of observations from the TROPOMI and GOSAT satellite instruments Z. Qu et al. 10.5194/acp-21-14159-2021
- Effect of sea salt aerosol on tropospheric bromine chemistry L. Zhu et al. 10.5194/acp-19-6497-2019
- Changes in atmospheric oxidants over Arctic Ocean atmosphere: evidence of oxygen isotope anomaly in nitrate aerosols Y. Zhang et al. 10.1038/s41612-023-00447-7
- Extracting a History of Global Fire Emissions for the Past Millennium From Ice Core Records of Acetylene, Ethane, and Methane M. Nicewonger et al. 10.1029/2020JD032932
- Concentrations of Volatile Methyl Siloxanes in New York City Reflect Emissions from Personal Care and Industrial Use C. Brunet et al. 10.1021/acs.est.3c10752
2 citations as recorded by crossref.
- Observational Constraints on the Formation of Cl2 From the Reactive Uptake of ClNO2 on Aerosols in the Polluted Marine Boundary Layer J. Haskins et al. 10.1029/2019JD030627
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
Latest update: 20 Nov 2024
Short summary
Chlorine radicals have a broad range of implications for tropospheric chemistry, air quality, and climate. We present a comprehensive simulation of tropospheric chlorine in a global 3-D model, which includes explicit accounting of chloride mobilization from sea salt aerosol. We find the chlorine chemistry contributes 1.0 % of the global oxidation of methane and decreases global burdens of tropospheric ozone by 7 % and OH by 3 % through the associated bromine radical chemistry.
Chlorine radicals have a broad range of implications for tropospheric chemistry, air quality,...
Altmetrics
Final-revised paper
Preprint