Articles | Volume 19, issue 5
https://doi.org/10.5194/acp-19-3161-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-3161-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Mar 2019
Research article |
| 12 Mar 2019
| 12 Mar 2019
Importance of reactive halogens in the tropical marine atmosphere: a regional modelling study using WRF-Chem
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, UK
now at: Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, Madrid, Spain
Claire E. Reeves
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, UK
Alex R. Baker
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, UK
Alfonso Saiz-Lopez
Department of Atmospheric Chemistry and Climate, Institute of Physical Chemistry Rocasolano, CSIC, Madrid, Spain
Rainer Volkamer
Department of Chemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
Theodore K. Koenig
Department of Chemistry, University of Colorado, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences (CIRES), University of Colorado, Boulder, CO, USA
Eric C. Apel
Earth System Laboratory, Atmospheric Chemistry Division, National Center for Atmospheric Research (NCAR), Boulder, CO, USA
Rebecca S. Hornbrook
Earth System Laboratory, Atmospheric Chemistry Division, National Center for Atmospheric Research (NCAR), Boulder, CO, USA
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of Chemistry, University of York, York, UK
Stephen J. Andrews
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of Chemistry, University of York, York, UK
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories (WACL), Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science (NCAS), Department of Chemistry, University of York, York, UK
Roland von Glasow
Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich, UK
deceased, 6 September 2015
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- Constraining the budget of NOx and volatile organic compounds at a remote tropical island using multi-platform observations and WRF-Chem model simulations C. Poraicu et al. 10.5194/acp-25-6903-2025
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42 citations as recorded by crossref.
- Investigation into the Reaction of Hydrogen Iodide with a Chlorine Atom in the Atmosphere above the Sea I. Larin et al. 10.1134/S0001433824700178
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Influence of bromine and iodine chemistry on annual, seasonal, diurnal, and background ozone: CMAQ simulations over the Northern Hemisphere G. Sarwar et al. 10.1016/j.atmosenv.2019.06.020
- Role of Iodine Recycling on Sea‐Salt Aerosols in the Global Marine Boundary Layer Q. Li et al. 10.1029/2021GL097567
- Kinetics and mechanism of I(+ 3) reactions and consequences for other iodine reactions G. Schmitz & S. Furrow 10.1007/s11144-022-02155-4
- Spontaneous Molecular Bromine Production in Sea‐Salt Aerosols Y. Cao et al. 10.1002/anie.202409779
- Intercomparison Between Surrogate, Explicit, and Full Treatments of VSL Bromine Chemistry Within the CAM‐Chem Chemistry‐Climate Model R. Fernandez et al. 10.1029/2020GL091125
- Chemical Interactions Between Ship‐Originated Air Pollutants and Ocean‐Emitted Halogens Q. Li et al. 10.1029/2020JD034175
- Limonene: A scented and versatile tropospheric free radical deactivator M. Francisco‐Márquez & A. Galano 10.1002/qua.27103
- Kinetics of hypochlorous acid reactions with organic and chloride-containing tropospheric aerosol S. Jorga et al. 10.1039/D3EM00292F
- Constraining the budget of NOx and volatile organic compounds at a remote tropical island using multi-platform observations and WRF-Chem model simulations C. Poraicu et al. 10.5194/acp-25-6903-2025
- Influence of the Sea Surface Microlayer on Oceanic Iodine Emissions L. Tinel et al. 10.1021/acs.est.0c02736
- Compilation of Henry's law constants (version 5.0.0) for water as solvent R. Sander 10.5194/acp-23-10901-2023
- Global Observations of Tropospheric Bromine Monoxide (BrO) Columns From TROPOMI Y. Chen et al. 10.1029/2023JD039091
- Sensitivity of tropospheric ozone to halogen chemistry in the chemistry–climate model LMDZ-INCA vNMHC C. Caram et al. 10.5194/gmd-16-4041-2023
- CAPRAM reduction towards an operational multiphase halogen and dimethyl sulfide chemistry treatment in the chemistry transport model COSMO-MUSCAT(5.04e) E. Hoffmann et al. 10.5194/gmd-13-2587-2020
- Implementation and Impacts of Surface and Blowing Snow Sources of Arctic Bromine Activation Within WRF‐Chem 4.1.1 L. Marelle et al. 10.1029/2020MS002391
- Observation and modelling of ozone-destructive halogen chemistry in a passively degassing volcanic plume L. Surl et al. 10.5194/acp-21-12413-2021
- Impact of marine chlorine emissions on secondary organic aerosols in North China Plain Z. Gao et al. 10.1016/j.envpol.2025.126524
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- The Role of Natural Halogens in Global Tropospheric Ozone Chemistry and Budget Under Different 21st Century Climate Scenarios A. Badia et al. 10.1029/2021JD034859
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
- Effect of sea salt aerosol on tropospheric bromine chemistry L. Zhu et al. 10.5194/acp-19-6497-2019
- An observation-based, reduced-form model for oxidation in the remote marine troposphere C. Baublitz et al. 10.1073/pnas.2209735120
- Impact and pathway of halogens on atmospheric oxidants in coastal city clusters in the Yangtze River Delta region in China H. Chen et al. 10.1016/j.apr.2023.101979
- Photocatalytic chloride-to-chlorine conversion by ionic iron in aqueous aerosols: a combined experimental, quantum chemical, and chemical equilibrium model study M. Mikkelsen et al. 10.5194/ar-2-31-2024
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
- Spontaneous Molecular Bromine Production in Sea‐Salt Aerosols Y. Cao et al. 10.1002/ange.202409779
- Comparing the Effect of Anthropogenically Amplified Halogen Natural Emissions on Tropospheric Ozone Chemistry Between Pre‐Industrial and Present‐Day J. Barrera et al. 10.1029/2022JD038283
- A first comprehensive insight into the sesquiterpene oxidation and sequential HOMs formation in the marine atmosphere: A case study of α-Cedrene H. Wu et al. 10.1016/j.jece.2024.112098
- Investigation of the reaction of hydrogen iodide with a chlorine atom in the atmosphere above the sea I. Larin et al. 10.31857/S0002351524020123
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Latest update: 13 Jul 2025
Short summary
The oceans have an impact on the composition and reactivity of the troposphere through the emission of gases and particles. Thus, a quantitative understanding of the marine atmosphere is crucial to examine the oxidative capacity and climate forcing. This study investigates the impact of halogens in the tropical troposphere and explores the sensitivity of this to uncertainties in the fluxes and their chemical processing. Our modelled tropospheric Ox loss due to halogens ranges from 20 % to 60 %.
The oceans have an impact on the composition and reactivity of the troposphere through the...
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