Articles | Volume 19, issue 3
https://doi.org/10.5194/acp-19-2001-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-2001-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Feb 2019
Research article |
| 14 Feb 2019
| 14 Feb 2019
Rate constant and secondary organic aerosol formation from the gas-phase reaction of eugenol with hydroxyl radicals
Changgeng Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
School of Biological and Chemical Engineering, Panzhihua University,
Panzhihua 617000, China
Beijing Advanced Innovation Center for Soft Matter Science and
Engineering, Beijing University of Chemical Technology, Beijing 100029,
China
Tianzeng Chen
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
Jun Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
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Cited
21 citations as recorded by crossref.
- Effect of pH on ·OH-induced degradation progress of syringol/syringaldehyde and health effect Z. An et al. 10.1016/j.chemosphere.2020.126893
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- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Five-Membered Heterocycles as Potential Photosensitizers in the Tropospheric Aqueous Phase: Photophysical Properties of Imidazole-2-carboxaldehyde, 2-Furaldehyde, and 2-Acetylfuran T. Felber et al. 10.1021/acs.jpca.0c07028
- Oxidation Potential Reduction of Carbon Nanomaterials during Atmospheric-Relevant Aging: Role of Surface Coating H. Jiang et al. 10.1021/acs.est.9b02062
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
- Effects of driving conditions on secondary aerosol formation from a GDI vehicle using an oxidation flow reactor N. Kuittinen et al. 10.1016/j.envpol.2021.117069
- Theoretical Study on the Mechanisms, Kinetics, and Toxicity Evaluation of OH-Initiated Atmospheric Oxidation Reactions of Coniferyl Alcohol Y. Zhang et al. 10.3390/atmos14060976
- Atmospheric Reactivity of Methoxyphenols: A Review C. Liu et al. 10.1021/acs.est.1c06535
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Relating satellite NO2 tropospheric columns to near-surface concentrations: implications from ground-based MAX-DOAS NO2 vertical profile observations B. Chang et al. 10.1038/s41612-024-00891-z
- Increased primary and secondary H2SO4 showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Aromatic Carbonyl and Nitro Compounds as Photosensitizers and Their Photophysical Properties in the Tropospheric Aqueous Phase T. Felber et al. 10.1021/acs.jpca.1c03503
- Aqueous-phase oxidation of three phenolic compounds by hydroxyl radical: Insight into secondary organic aerosol formation yields, mechanisms, products and optical properties Z. Ye et al. 10.1016/j.atmosenv.2019.117240
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Mechanisms and kinetics studies of the atmospheric oxidation of eugenol by hydroxyl radicals and ozone molecules Y. Sun et al. 10.1016/j.scitotenv.2021.145203
- Aqueous-phase chemistry of atmospheric phenolic compounds: A critical review of laboratory studies F. Li et al. 10.1016/j.scitotenv.2022.158895
- Secondary organic aerosol formation from styrene photolysis and photooxidation with hydroxyl radicals M. Tajuelo et al. 10.1016/j.chemosphere.2019.05.136
- Mechanisms and kinetic studies of OH-initiated atmospheric oxidation of methoxyphenols in the presence of O2 and NOx Y. Sun et al. 10.1039/C9CP03246K
- Single Droplet Tweezer Revealing the Reaction Mechanism of Mn(II)-Catalyzed SO2 Oxidation X. Cao et al. 10.1021/acs.est.4c00309
- Kinetic study on the heterogeneous degradation of coniferyl alcohol by OH radicals C. Liu et al. 10.1016/j.chemosphere.2019.125088
21 citations as recorded by crossref.
- Effect of pH on ·OH-induced degradation progress of syringol/syringaldehyde and health effect Z. An et al. 10.1016/j.chemosphere.2020.126893
- Characterizing water-soluble brown carbon in fine particles in four typical cities in northwestern China during wintertime: integrating optical properties with chemical processes M. Zhong et al. 10.5194/acp-23-12609-2023
- Secondary organic aerosol formation from α-methylstyrene atmospheric degradation: Role of NO level, relative humidity and inorganic seed aerosol M. Tajuelo et al. 10.1016/j.atmosres.2019.104631
- Five-Membered Heterocycles as Potential Photosensitizers in the Tropospheric Aqueous Phase: Photophysical Properties of Imidazole-2-carboxaldehyde, 2-Furaldehyde, and 2-Acetylfuran T. Felber et al. 10.1021/acs.jpca.0c07028
- Oxidation Potential Reduction of Carbon Nanomaterials during Atmospheric-Relevant Aging: Role of Surface Coating H. Jiang et al. 10.1021/acs.est.9b02062
- New mechanism for the participation of aromatic oxidation products in atmospheric nucleation H. Zhang et al. 10.1016/j.scitotenv.2024.170487
- Effects of driving conditions on secondary aerosol formation from a GDI vehicle using an oxidation flow reactor N. Kuittinen et al. 10.1016/j.envpol.2021.117069
- Theoretical Study on the Mechanisms, Kinetics, and Toxicity Evaluation of OH-Initiated Atmospheric Oxidation Reactions of Coniferyl Alcohol Y. Zhang et al. 10.3390/atmos14060976
- Atmospheric Reactivity of Methoxyphenols: A Review C. Liu et al. 10.1021/acs.est.1c06535
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Relating satellite NO2 tropospheric columns to near-surface concentrations: implications from ground-based MAX-DOAS NO2 vertical profile observations B. Chang et al. 10.1038/s41612-024-00891-z
- Increased primary and secondary H2SO4 showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Aromatic Carbonyl and Nitro Compounds as Photosensitizers and Their Photophysical Properties in the Tropospheric Aqueous Phase T. Felber et al. 10.1021/acs.jpca.1c03503
- Aqueous-phase oxidation of three phenolic compounds by hydroxyl radical: Insight into secondary organic aerosol formation yields, mechanisms, products and optical properties Z. Ye et al. 10.1016/j.atmosenv.2019.117240
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Mechanisms and kinetics studies of the atmospheric oxidation of eugenol by hydroxyl radicals and ozone molecules Y. Sun et al. 10.1016/j.scitotenv.2021.145203
- Aqueous-phase chemistry of atmospheric phenolic compounds: A critical review of laboratory studies F. Li et al. 10.1016/j.scitotenv.2022.158895
- Secondary organic aerosol formation from styrene photolysis and photooxidation with hydroxyl radicals M. Tajuelo et al. 10.1016/j.chemosphere.2019.05.136
- Mechanisms and kinetic studies of OH-initiated atmospheric oxidation of methoxyphenols in the presence of O2 and NOx Y. Sun et al. 10.1039/C9CP03246K
- Single Droplet Tweezer Revealing the Reaction Mechanism of Mn(II)-Catalyzed SO2 Oxidation X. Cao et al. 10.1021/acs.est.4c00309
- Kinetic study on the heterogeneous degradation of coniferyl alcohol by OH radicals C. Liu et al. 10.1016/j.chemosphere.2019.125088
Latest update: 31 Oct 2025
Short summary
The rate constant and SOA formation for the OH-initiated reaction of eugenol were studied for the first time in an oxidation flow reactor. Significant SOA formation was observed, and SOA yield depended on precursor concentration and OH exposure. SO2 and NO2 both enhanced SOA yields. In addition, NO2 participated in OH-initiated reaction and produced organic nitrates. The results could be helpful for further understanding SOA formation from the atmospheric oxidation of methoxyphenols.
The rate constant and SOA formation for the OH-initiated reaction of eugenol were studied for...
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