Rate constant and secondary organic aerosol formation from the gas-phase reaction of eugenol with hydroxyl radicals
Changgeng Liu,Yongchun Liu,Tianzeng Chen,Jun Liu,and Hong He
Changgeng Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
School of Biological and Chemical Engineering, Panzhihua University,
Panzhihua 617000, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
Jun Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
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The rate constant and SOA formation for the OH-initiated reaction of eugenol were studied for the first time in an oxidation flow reactor. Significant SOA formation was observed, and SOA yield depended on precursor concentration and OH exposure. SO2 and NO2 both enhanced SOA yields. In addition, NO2 participated in OH-initiated reaction and produced organic nitrates. The results could be helpful for further understanding SOA formation from the atmospheric oxidation of methoxyphenols.
The rate constant and SOA formation for the OH-initiated reaction of eugenol were studied for...
