Articles | Volume 19, issue 23
https://doi.org/10.5194/acp-19-15117-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-15117-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Mechanistic study of the formation of ring-retaining and ring-opening products from the oxidation of aromatic compounds under urban atmospheric conditions
Alexander Zaytsev
CORRESPONDING AUTHOR
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Abigail R. Koss
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
now at: TOFWERK USA, Boulder, CO 80301, USA
Martin Breitenlechner
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Jordan E. Krechmer
Aerodyne Research Inc., Billerica, MA 01821, USA
Kevin J. Nihill
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Christopher Y. Lim
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
James C. Rowe
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Joshua L. Cox
Department of Chemistry and Chemical Biology, Harvard University,
Cambridge, MA 02138, USA
Joshua Moss
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Joseph R. Roscioli
Aerodyne Research Inc., Billerica, MA 01821, USA
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, MA 01821, USA
Douglas R. Worsnop
Aerodyne Research Inc., Billerica, MA 01821, USA
Jesse H. Kroll
Department of Civil and Environmental Engineering, Massachusetts
Institute of Technology, Cambridge, MA 02139, USA
Frank N. Keutsch
CORRESPONDING AUTHOR
John A. Paulson School of Engineering and Applied Sciences, Harvard
University, Cambridge, MA 02138, USA
Department of Chemistry and Chemical Biology, Harvard University,
Cambridge, MA 02138, USA
Department of Earth and Planetary Sciences, Harvard University,
Cambridge, MA 02138, USA
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Latest update: 17 Apr 2024
Short summary
Aromatic hydrocarbons contribute significantly to the production of tropospheric ozone and secondary organic aerosol (SOA). Here later-generation low-volatility oxygenated products from toluene and 1,2,4-TMB oxidation by OH are detected in the gas and particle phases. We show that these products, previously identified as highly oxygenated molecules (HOMs), are formed in more than one pathway with differing numbers of reaction steps with OH. They also make up a significant fraction of SOA.
Aromatic hydrocarbons contribute significantly to the production of tropospheric ozone and...
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