Articles | Volume 19, issue 19
https://doi.org/10.5194/acp-19-12749-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-12749-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Chemical composition and hydrolysis of organic nitrate aerosol formed from hydroxyl and nitrate radical oxidation of α-pinene and β-pinene
Masayuki Takeuchi
School of Civil and Environmental Engineering, Georgia Institute of
Technology, Atlanta, Georgia 30332, USA
School of Chemical and Bimolecular Engineering, Georgia Institute of
Technology, Atlanta, Georgia 30332, USA
School of Earth and Atmospheric Sciences, Georgia Institute of
Technology, Atlanta, Georgia 30332, USA
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71 citations as recorded by crossref.
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- Formation of condensable organic vapors from anthropogenic and biogenic volatile organic compounds (VOCs) is strongly perturbed by NO<sub><i>x</i></sub> in eastern China Y. Liu et al. 10.5194/acp-21-14789-2021
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- Incorporating Oxygen Isotopes of Oxidized Reactive Nitrogen in the Regional Atmospheric Chemistry Mechanism, version 2 (ICOIN-RACM2) W. Walters et al. 10.5194/gmd-17-4673-2024
- Photochemical Degradation of Organic Matter in the Atmosphere W. Hu et al. 10.1002/adsu.202100027
- Enhanced formation of nitrogenous organic aerosols and brown carbon after aging in the planetary boundary layer Y. Wu et al. 10.1038/s41612-024-00726-x
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Y. Chen et al. 10.5194/acp-20-8421-2020
- Light absorption and scattering properties of indole secondary organic aerosol prepared under various oxidant and relative humidity conditions V. Baboomian et al. 10.1080/02786826.2023.2193235
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
- Resolving Ambient Organic Aerosol Formation and Aging Pathways with Simultaneous Molecular Composition and Volatility Observations B. Lee et al. 10.1021/acsearthspacechem.9b00302
- Optical Properties of Secondary Organic Aerosol Produced by Nitrate Radical Oxidation of Biogenic Volatile Organic Compounds Q. He et al. 10.1021/acs.est.0c06838
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- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
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- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- Zinc-catalyzed asymmetric nitrooxylation of β-keto esters/amides with a benziodoxole-derived nitrooxy transfer reagent B. Li et al. 10.1039/D0QO01022G
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- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al. 10.5194/acp-23-8993-2023
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- Gas-Particle Partitioning and SOA Yields of Organonitrate Products from NO3-Initiated Oxidation of Isoprene under Varied Chemical Regimes B. Brownwood et al. 10.1021/acsearthspacechem.0c00311
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- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al. 10.5194/acp-21-4915-2021
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- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
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- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. 10.5194/acp-23-13869-2023
- Heterogeneous Reactions of α-Pinene on Mineral Surfaces: Formation of Organonitrates and α-Pinene Oxidation Products E. Hettiarachchi & V. Grassian 10.1021/acs.jpca.2c02663
- Night-time oxidation at the air–water interface: co-surfactant effects in binary mixtures F. Sebastiani et al. 10.1039/D2EA00056C
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- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Tethered balloon system and High-Resolution Mass Spectrometry Reveal Increased Organonitrates Aloft Compared to the Ground Level G. Vandergrift et al. 10.1021/acs.est.4c02090
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
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- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al. 10.5194/acp-23-5851-2023
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
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- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Chemical characterization of secondary organic aerosol at a rural site in the southeastern US: insights from simultaneous high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) and FIGAERO chemical ionization mass spectrometer (CIMS) measurements Y. Chen et al. 10.5194/acp-20-8421-2020
- Light absorption and scattering properties of indole secondary organic aerosol prepared under various oxidant and relative humidity conditions V. Baboomian et al. 10.1080/02786826.2023.2193235
- Photolysis of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.jpca.2c04307
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- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. 10.1021/acs.jpca.2c04419
- Comprehensive isoprene and terpene gas-phase chemistry improves simulated surface ozone in the southeastern US R. Schwantes et al. 10.5194/acp-20-3739-2020
- Evolution of Aerosol Under Moist and Fog Conditions in a Rural Forest Environment: Insights From High‐Resolution Aerosol Mass Spectrometry J. Zhang et al. 10.1029/2020GL089714
- A combined gas- and particle-phase analysis of highly oxygenated organic molecules (HOMs) from α-pinene ozonolysis J. Zhao et al. 10.5194/acp-23-3707-2023
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Contrasting Influence of Nitrogen Oxides on the Cloud Condensation Nuclei Activity of Monoterpene‐Derived Secondary Organic Aerosol in Daytime and Nighttime Oxidation C. Zhang et al. 10.1029/2022GL102110
- Molecular composition of secondary organic aerosol from styrene under different NO and humidity conditions S. Yu et al. 10.1016/j.atmosres.2021.105950
- Zinc-catalyzed asymmetric nitrooxylation of β-keto esters/amides with a benziodoxole-derived nitrooxy transfer reagent B. Li et al. 10.1039/D0QO01022G
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al. 10.5194/acp-23-8855-2023
- Chemical Insights into the Molecular Composition of Organic Aerosols in the Urban Region of Houston, Texas T. Gautam et al. 10.1021/acsestair.4c00141
- Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO<sub>3</sub>) oxidation of alpha-pinene from various RO<sub>2</sub> fates K. Bates et al. 10.5194/acp-22-1467-2022
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Significant impacts of anthropogenic activities on monoterpene and oleic acid-derived particulate organic nitrates in the North China Plain J. Zhang et al. 10.1016/j.atmosres.2021.105585
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Source characterization of volatile organic compounds in urban Beijing and its links to secondary organic aerosol formation Q. Liu et al. 10.1016/j.scitotenv.2022.160469
- Influence of Ammonia and Relative Humidity on the Formation and Composition of Secondary Brown Carbon from Oxidation of 1-Methylnaphthalene and Longifolene Y. Cui et al. 10.1021/acsearthspacechem.0c00353
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Anthropogenic amplification of biogenic secondary organic aerosol production Y. Zheng et al. 10.5194/acp-23-8993-2023
- Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent X. Cheng et al. 10.1002/anie.202302521
- The production and hydrolysis of organic nitrates from OH radical oxidation of <i>β</i>-ocimene A. Morales et al. 10.5194/acp-21-129-2021
- Gas-Particle Partitioning and SOA Yields of Organonitrate Products from NO3-Initiated Oxidation of Isoprene under Varied Chemical Regimes B. Brownwood et al. 10.1021/acsearthspacechem.0c00311
- Evaluating the response of the Aerodyne aerosol mass spectrometer to monoterpene- and isoprene-derived organic nitrate standards M. Takeuchi et al. 10.1080/02786826.2024.2389183
- Impact of NO<sub><i>x</i></sub> on secondary organic aerosol (SOA) formation from <i>α</i>-pinene and <i>β</i>-pinene photooxidation: the role of highly oxygenated organic nitrates I. Pullinen et al. 10.5194/acp-20-10125-2020
- Novel Application of Machine Learning Techniques for Rapid Source Apportionment of Aerosol Mass Spectrometer Datasets P. Pande et al. 10.1021/acsearthspacechem.1c00344
- Vertical Variations in Biogenic Organic Nitrates at Two Temperate Forest Sites D. Wei et al. 10.1021/acsestair.4c00123
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Detecting and Characterizing Particulate Organic Nitrates with an Aerodyne Long-ToF Aerosol Mass Spectrometer F. Graeffe et al. 10.1021/acsearthspacechem.2c00314
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al. 10.5194/acp-21-4915-2021
- Stability of α-Pinene and d-Limonene Ozonolysis Secondary Organic Aerosol Compounds Toward Hydrolysis and Hydration C. Wong et al. 10.1021/acsearthspacechem.1c00171
- Particle-phase processing of α-pinene NO3 secondary organic aerosol in the dark D. Bell et al. 10.5194/acp-22-13167-2022
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Nontargeted Tandem Mass Spectrometry Analysis Reveals Diversity and Variability in Aerosol Functional Groups across Multiple Sites, Seasons, and Times of Day J. Ditto et al. 10.1021/acs.estlett.9b00702
- Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing A. Mehra et al. 10.1039/D0FD00080A
- Metal-free visible-light-mediated aerobic nitrooxylation for the synthesis of nitrate esters with t-BuONO Y. Lv et al. 10.1039/D4CC03272A
- Evaluation of the chemical composition of gas- and particle-phase products of aromatic oxidation A. Mehra et al. 10.5194/acp-20-9783-2020
- A thermal-dissociation–cavity ring-down spectrometer (TD-CRDS) for the detection of organic nitrates in gas and particle phases N. Keehan et al. 10.5194/amt-13-6255-2020
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Technical note: Gas-phase nitrate radical generation via irradiation of aerated ceric ammonium nitrate mixtures A. Lambe et al. 10.5194/acp-23-13869-2023
- Heterogeneous Reactions of α-Pinene on Mineral Surfaces: Formation of Organonitrates and α-Pinene Oxidation Products E. Hettiarachchi & V. Grassian 10.1021/acs.jpca.2c02663
- Night-time oxidation at the air–water interface: co-surfactant effects in binary mixtures F. Sebastiani et al. 10.1039/D2EA00056C
- Dissecting the contributions of organic nitrogen aerosols to global atmospheric nitrogen deposition and implications for ecosystems Y. Li et al. 10.1093/nsr/nwad244
- Heterogeneous Formation of Organonitrates (ON) and Nitroxy-Organosulfates (NOS) from Adsorbed α-Pinene-Derived Organosulfates (OS) on Mineral Surfaces E. Hettiarachchi & V. Grassian 10.1021/acsearthspacechem.2c00259
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Tethered balloon system and High-Resolution Mass Spectrometry Reveal Increased Organonitrates Aloft Compared to the Ground Level G. Vandergrift et al. 10.1021/acs.est.4c02090
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent X. Cheng et al. 10.1002/ange.202302521
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al. 10.5194/acp-23-5851-2023
- Particulate organic nitrates at Mount Tai in winter and spring: Variation characteristics and effects of mountain-valley breezes and elevated emission sources J. Chen et al. 10.1016/j.envres.2022.113182
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Collection of Nitrogen Dioxide for Nitrogen and Oxygen Isotope Determination─Laboratory and Environmental Chamber Evaluation D. Blum et al. 10.1021/acs.analchem.2c04672
- Kinetic modeling of formation and evaporation of secondary organic aerosol from NO<sub>3</sub> oxidation of pure and mixed monoterpenes T. Berkemeier et al. 10.5194/acp-20-15513-2020
Latest update: 20 Nov 2024
Short summary
Organic nitrate is ubiquitous in the atmosphere and impacts the formation of aerosol and ozone, two leading air pollutants of concern worldwide. We conducted a comprehensive laboratory study to investigate the hydrolysis process of organic nitrate aerosol formed from monoterpenes, which are important reactive chemicals emitted by plants. Our results provide experimentally constrained parameters required to assess the role of organic nitrate in the formation of the air pollutants of our concern.
Organic nitrate is ubiquitous in the atmosphere and impacts the formation of aerosol and ozone,...
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