Articles | Volume 19, issue 19
https://doi.org/10.5194/acp-19-12515-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-12515-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Oct 2019
Research article |
| 08 Oct 2019
| 08 Oct 2019
Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors
Mijung Song
Department of Earth and Environmental Sciences, Chonbuk
National University, Jeollabuk-do, 54896, Republic of Korea
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Adrian M. Maclean
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Yuanzhou Huang
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
Natalie R. Smith
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Sandra L. Blair
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Julia Laskin
Department of Chemistry, Purdue University, West
Lafayette, IN 47907, USA
Alexander Laskin
Department of Chemistry, Purdue University, West
Lafayette, IN 47907, USA
Wing-Sy Wong DeRieux
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Manabu Shiraiwa
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Sergey A. Nizkorodov
Department of Chemistry, University of California Irvine,
Irvine, CA 92697, USA
Department of Chemistry, University of British Columbia,
Vancouver, BC, V6T 1Z1, Canada
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Cited
36 citations as recorded by crossref.
- Microscopic observation of a liquid-liquid-(semi)solid phase in polluted PM2.5 S. Gaikwad et al. https://doi.org/10.3389/fenvs.2022.947924
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. https://doi.org/10.5194/acp-24-5549-2024
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al. https://doi.org/10.1021/acs.est.4c06235
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al. https://doi.org/10.1016/j.atmosenv.2024.120985
- Highly viscous phase behavior of organic-rich urban PM2.5 A. Ullah et al. https://doi.org/10.5194/acp-26-7311-2026
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. https://doi.org/10.5194/acp-22-805-2022
- Morphology and phase state of PM2.5 in urban and coastal-rural areas during summer S. Gaikwad et al. https://doi.org/10.3389/fenvs.2023.1142941
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa https://doi.org/10.1039/D1EA00090J
- Temperature-Dependent Phase Transitions of Aqueous Aerosol Droplet Systems in Microfluidic Traps P. Roy et al. https://doi.org/10.1021/acsearthspacechem.0c00114
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and α-pinene T. Galeazzo et al. https://doi.org/10.5194/acp-21-10199-2021
- Phase Behavior of Polluted and Clean Urban Winter PM2.5 from Optical Observations and Thermodynamic Equilibrium Modeling T. Do et al. https://doi.org/10.1021/acs.est.5c16878
- A new hot-stage microscopy technique for measuring temperature-dependent viscosities of aerosol particles and its application to farnesene secondary organic aerosol K. Kiland et al. https://doi.org/10.5194/amt-15-5545-2022
- Effects of Sucrose on Phase Transitions of Organic/Inorganic Aerosols E. Ott et al. https://doi.org/10.1021/acsearthspacechem.0c00006
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. https://doi.org/10.5194/acp-20-8103-2020
- Viscosity and phase state of aerosol particles consisting of sucrose mixed with inorganic salts Y. Song et al. https://doi.org/10.5194/acp-21-10215-2021
- Viscosity and physical state of sucrose mixed with ammonium sulfate droplets R. Jeong et al. https://doi.org/10.5194/acp-22-8805-2022
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.1c00296
- A generic framework for understanding the hygroscopic cycle of atmospheric aerosol: Ammonium sulfate, ammonium nitrate, and organic mixtures S. Kim et al. https://doi.org/10.1016/j.jaerosci.2026.106841
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. https://doi.org/10.1021/acs.est.0c05796
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.0c00296
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. https://doi.org/10.1021/acsearthspacechem.4c00019
- Direct observation for relative-humidity-dependent mixing states of submicron particles containing organic surfactants and inorganic salts C. Xiong et al. https://doi.org/10.5194/acp-23-8979-2023
- Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types F. Mahrt et al. https://doi.org/10.5194/acp-22-13783-2022
- Molecular dynamics investigation on structural and interfacial characteristics of aerosol particles containing mixed organic components C. Zhang et al. https://doi.org/10.1016/j.atmosenv.2023.120305
- Temperature–RH dependent viscosity of organic aerosols from 273 to 303 K: implications for global N2O5 uptake A. Ullah et al. https://doi.org/10.5194/acp-26-2319-2026
- Comparison of Phase States of PM2.5 over Megacities, Seoul and Beijing, and Their Implications on Particle Size Distribution M. Song et al. https://doi.org/10.1021/acs.est.2c06377
- Viscosity Variability from Smoldering Eucalyptus Smoke: From High Viscosity Tar Balls to Low Viscosity Organic Aerosol C. Wu et al. https://doi.org/10.1021/acsestair.5c00271
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. https://doi.org/10.1039/D2CP04407B
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. https://doi.org/10.1146/annurev-physchem-083122-115909
- Hygroscopic behavior of aerosols generated from solutions of 3-methyl-1,2,3-butanetricarboxylic acid, its sodium salts, and its mixtures with NaCl L. Wu et al. https://doi.org/10.5194/acp-20-14103-2020
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. https://doi.org/10.1073/pnas.2208121119
- Ammonium Chloride Associated Aerosol Liquid Water Enhances Haze in Delhi, India Y. Chen et al. https://doi.org/10.1021/acs.est.2c00650
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. https://doi.org/10.1039/D0EA00020E
- Humidity-Dependent Phase State of Gasoline Vehicle Emission-Related Aerosols X. Meng et al. https://doi.org/10.1021/acs.est.0c05478
- Analysis of aerosol liquid water content and its role in visibility reduction in Delhi U. Ali et al. https://doi.org/10.1016/j.scitotenv.2023.161484
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. https://doi.org/10.1038/s41612-025-01199-2
36 citations as recorded by crossref.
- Microscopic observation of a liquid-liquid-(semi)solid phase in polluted PM2.5 S. Gaikwad et al. https://doi.org/10.3389/fenvs.2022.947924
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. https://doi.org/10.5194/acp-24-5549-2024
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al. https://doi.org/10.1021/acs.est.4c06235
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al. https://doi.org/10.1016/j.atmosenv.2024.120985
- Highly viscous phase behavior of organic-rich urban PM2.5 A. Ullah et al. https://doi.org/10.5194/acp-26-7311-2026
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. https://doi.org/10.5194/acp-22-805-2022
- Morphology and phase state of PM2.5 in urban and coastal-rural areas during summer S. Gaikwad et al. https://doi.org/10.3389/fenvs.2023.1142941
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa https://doi.org/10.1039/D1EA00090J
- Temperature-Dependent Phase Transitions of Aqueous Aerosol Droplet Systems in Microfluidic Traps P. Roy et al. https://doi.org/10.1021/acsearthspacechem.0c00114
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and α-pinene T. Galeazzo et al. https://doi.org/10.5194/acp-21-10199-2021
- Phase Behavior of Polluted and Clean Urban Winter PM2.5 from Optical Observations and Thermodynamic Equilibrium Modeling T. Do et al. https://doi.org/10.1021/acs.est.5c16878
- A new hot-stage microscopy technique for measuring temperature-dependent viscosities of aerosol particles and its application to farnesene secondary organic aerosol K. Kiland et al. https://doi.org/10.5194/amt-15-5545-2022
- Effects of Sucrose on Phase Transitions of Organic/Inorganic Aerosols E. Ott et al. https://doi.org/10.1021/acsearthspacechem.0c00006
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. https://doi.org/10.5194/acp-20-8103-2020
- Viscosity and phase state of aerosol particles consisting of sucrose mixed with inorganic salts Y. Song et al. https://doi.org/10.5194/acp-21-10215-2021
- Viscosity and physical state of sucrose mixed with ammonium sulfate droplets R. Jeong et al. https://doi.org/10.5194/acp-22-8805-2022
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.1c00296
- A generic framework for understanding the hygroscopic cycle of atmospheric aerosol: Ammonium sulfate, ammonium nitrate, and organic mixtures S. Kim et al. https://doi.org/10.1016/j.jaerosci.2026.106841
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. https://doi.org/10.1021/acs.est.0c05796
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.0c00296
- Influence of Relative Humidity and Composition on PM2.5 Phases in Northeast Asia C. Seong et al. https://doi.org/10.1021/acsearthspacechem.4c00019
- Direct observation for relative-humidity-dependent mixing states of submicron particles containing organic surfactants and inorganic salts C. Xiong et al. https://doi.org/10.5194/acp-23-8979-2023
- Not all types of secondary organic aerosol mix: two phases observed when mixing different secondary organic aerosol types F. Mahrt et al. https://doi.org/10.5194/acp-22-13783-2022
- Molecular dynamics investigation on structural and interfacial characteristics of aerosol particles containing mixed organic components C. Zhang et al. https://doi.org/10.1016/j.atmosenv.2023.120305
- Temperature–RH dependent viscosity of organic aerosols from 273 to 303 K: implications for global N2O5 uptake A. Ullah et al. https://doi.org/10.5194/acp-26-2319-2026
- Comparison of Phase States of PM2.5 over Megacities, Seoul and Beijing, and Their Implications on Particle Size Distribution M. Song et al. https://doi.org/10.1021/acs.est.2c06377
- Viscosity Variability from Smoldering Eucalyptus Smoke: From High Viscosity Tar Balls to Low Viscosity Organic Aerosol C. Wu et al. https://doi.org/10.1021/acsestair.5c00271
- Does liquid–liquid phase separation impact ice nucleation in mixed polyethylene glycol and ammonium sulfate droplets? Y. Yao et al. https://doi.org/10.1039/D2CP04407B
- Phase Transitions in Organic and Organic/Inorganic Aerosol Particles M. Freedman et al. https://doi.org/10.1146/annurev-physchem-083122-115909
- Hygroscopic behavior of aerosols generated from solutions of 3-methyl-1,2,3-butanetricarboxylic acid, its sodium salts, and its mixtures with NaCl L. Wu et al. https://doi.org/10.5194/acp-20-14103-2020
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. https://doi.org/10.1073/pnas.2208121119
- Ammonium Chloride Associated Aerosol Liquid Water Enhances Haze in Delhi, India Y. Chen et al. https://doi.org/10.1021/acs.est.2c00650
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. https://doi.org/10.1039/D0EA00020E
- Humidity-Dependent Phase State of Gasoline Vehicle Emission-Related Aerosols X. Meng et al. https://doi.org/10.1021/acs.est.0c05478
- Analysis of aerosol liquid water content and its role in visibility reduction in Delhi U. Ali et al. https://doi.org/10.1016/j.scitotenv.2023.161484
- Atmospheric organic aerosols: online molecular characterization and environmental impacts Y. Sun et al. https://doi.org/10.1038/s41612-025-01199-2
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