Articles | Volume 19, issue 18
https://doi.org/10.5194/acp-19-11953-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-11953-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
25 Sep 2019
Research article |
| 25 Sep 2019
| 25 Sep 2019
Diurnal variability, photochemical production and loss processes of hydrogen peroxide in the boundary layer over Europe
Horst Fischer
CORRESPONDING AUTHOR
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Raoul Axinte
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Heiko Bozem
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
now at: Institute for Atmospheric Physics, Johannes Gutenberg University,
Mainz, Germany
John N. Crowley
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Cheryl Ernest
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
now at: Dept. of Neurology, Johannes Gutenberg University, Mainz, Germany
Stefan Gilge
German Weather Service, Hohenpeißenberg, Germany
Sascha Hafermann
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Hartwig Harder
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Korbinian Hens
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Ruud H. H. Janssen
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
now at: TNO, Department of Climate, Air and Sustainability, Utrecht,
the Netherlands
Rainer Königstedt
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Dagmar Kubistin
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
German Weather Service, Hohenpeißenberg, Germany
Chinmay Mallik
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Department of Atmospheric Science, Central University of Rajasthan, India
Monica Martinez
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Anna Novelli
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
now at: Institute for Energy and Climate Research, Forschungszentrum Jülich, Germany
Uwe Parchatka
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Christian Plass-Dülmer
German Weather Service, Hohenpeißenberg, Germany
Andrea Pozzer
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Eric Regelin
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Andreas Reiffs
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Torsten Schmidt
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Jan Schuladen
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
Jos Lelieveld
Atmospheric Chemistry Division, Max Planck Institute for Chemistry, POB 3060, 55020 Mainz, Germany
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Cited
13 citations as recorded by crossref.
- Quantitative Kinetics of the Reaction between CH2OO and H2O2 in the Atmosphere Y. Zhao et al. 10.1021/acs.jpca.2c04408
- Measurement report: Production and loss of atmospheric formaldehyde at a suburban site of Shanghai in summertime Y. Wu et al. 10.5194/acp-23-2997-2023
- HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere Z. Hamryszczak et al. 10.5194/amt-16-4741-2023
- Sampling and analysis techniques for inorganic air pollutants in indoor air F. Villanueva et al. 10.1080/05704928.2021.2020807
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Addressing the urgent need for direct climate cooling: Rationale and options R. Baiman et al. 10.1093/oxfclm/kgae014
- Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS D. SUN et al. 10.1088/2058-6272/ac7639
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Strong impacts of biomass burning, nitrogen fertilization, and fine particles on gas-phase hydrogen peroxide (H2O2) C. Ye et al. 10.1016/j.scitotenv.2022.156997
- Atmospheric Hydrogen Peroxide (H2O2) at the Foot and Summit of Mt. Tai: Variations, Sources and Sinks, and Implications for Ozone Formation Chemistry C. Ye et al. 10.1029/2020JD033975
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Heterogeneous Processes in the Atmosphere of Mars and Impact on H2O2 and O3 Abundances F. Daerden et al. 10.1029/2023JE008014
13 citations as recorded by crossref.
- Quantitative Kinetics of the Reaction between CH2OO and H2O2 in the Atmosphere Y. Zhao et al. 10.1021/acs.jpca.2c04408
- Measurement report: Production and loss of atmospheric formaldehyde at a suburban site of Shanghai in summertime Y. Wu et al. 10.5194/acp-23-2997-2023
- HYPHOP: a tool for high-altitude, long-range monitoring of hydrogen peroxide and higher organic peroxides in the atmosphere Z. Hamryszczak et al. 10.5194/amt-16-4741-2023
- Sampling and analysis techniques for inorganic air pollutants in indoor air F. Villanueva et al. 10.1080/05704928.2021.2020807
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Addressing the urgent need for direct climate cooling: Rationale and options R. Baiman et al. 10.1093/oxfclm/kgae014
- Improved sensitivity on detection of Cu and Cr in liquids using glow discharge technology assisted with LIBS D. SUN et al. 10.1088/2058-6272/ac7639
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Strong impacts of biomass burning, nitrogen fertilization, and fine particles on gas-phase hydrogen peroxide (H2O2) C. Ye et al. 10.1016/j.scitotenv.2022.156997
- Atmospheric Hydrogen Peroxide (H2O2) at the Foot and Summit of Mt. Tai: Variations, Sources and Sinks, and Implications for Ozone Formation Chemistry C. Ye et al. 10.1029/2020JD033975
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Heterogeneous Processes in the Atmosphere of Mars and Impact on H2O2 and O3 Abundances F. Daerden et al. 10.1029/2023JE008014
Latest update: 20 Nov 2024
Short summary
We use in situ observations of H2O2 to study the interplay between photochemistry, transport and deposition processes. The data were obtained during five ground-based field campaigns across Europe. A budget calculation indicates that the photochemical production rate was much larger than photochemical loss and that dry deposition is the dominant loss process. To reproduce the change in H2O2 mixing ratios after sunrise, a variable contribution of entrainment from the residual layer is required.
We use in situ observations of H2O2 to study the interplay between photochemistry, transport and...
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