Articles | Volume 19, issue 17
https://doi.org/10.5194/acp-19-11525-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-11525-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Sep 2019
Research article |
| 12 Sep 2019
| 12 Sep 2019
Vertical profile observations of water vapor deuterium excess in the lower troposphere
Olivia E. Salmon
Department of Chemistry, Purdue University, 560 Oval Dr, West
Lafayette, IN 47907, USA
now at: Lake Michigan Air Directors Consortium, 101 S Webster St,
Madison, WI 53703, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, 550 Stadium Mall Dr., West Lafayette, IN 47907, USA
Purdue Climate Change Research Center, 203 S Martin Jischke Dr, West
Lafayette, IN 47907, USA
Michael E. Baldwin
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, 550 Stadium Mall Dr., West Lafayette, IN 47907, USA
Purdue Climate Change Research Center, 203 S Martin Jischke Dr, West
Lafayette, IN 47907, USA
Kristian D. Hajny
Department of Chemistry, Purdue University, 560 Oval Dr, West
Lafayette, IN 47907, USA
Brian H. Stirm
School of Aviation and Transportation Technology, Purdue University,
1401 Aviation Dr, West Lafayette, IN 47907, USA
Paul B. Shepson
Department of Chemistry, Purdue University, 560 Oval Dr, West
Lafayette, IN 47907, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, 550 Stadium Mall Dr., West Lafayette, IN 47907, USA
Purdue Climate Change Research Center, 203 S Martin Jischke Dr, West
Lafayette, IN 47907, USA
now at: School of Marine and Atmospheric Sciences, Stony Brook University,
145 Endeavour Hall, Stony Brook, NY 11794, USA
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Cited
19 citations as recorded by crossref.
- Determining the Isotopic Composition of Surface Water Vapor Flux From High‐Frequency Observations Using Flux‐Gradient and Keeling Plot Methods Y. Hu et al. 10.1029/2020EA001304
- What causes site-specific intra-event variations of stable isotopes in precipitation in Beijing? Y. Tang et al. 10.1016/j.atmosres.2023.107052
- Isotopic Signature of Precipitation in the Elbrus Region J. Chizhova et al. 10.1134/S0001433823130054
- Water isotopic characterisation of the cloud–circulation coupling in the North Atlantic trades – Part 1: A process-oriented evaluation of COSMOiso simulations with EUREC4A observations L. Villiger et al. 10.5194/acp-23-14643-2023
- Isotopic measurements in water vapor, precipitation, and seawater during EUREC4A A. Bailey et al. 10.5194/essd-15-465-2023
- A set of methods to evaluate the below-cloud evaporation effect on local precipitation isotopic composition: a case study for Xi'an, China M. Xing et al. 10.5194/acp-23-9123-2023
- Is the deuterium excess in precipitation a reliable tracer of moisture sources and water resources fate in the western Mediterranean? New insights from Apuan Alps (Italy) S. Natali et al. 10.1016/j.jhydrol.2022.128497
- Lake Spray Aerosol Incorporated into Great Lakes Clouds N. Olson et al. 10.1021/acsearthspacechem.9b00258
- Toward a process-oriented understanding of water in the climate system: recent insights from stable isotopes A. Bailey et al. 10.1088/2752-5295/ada17b
- Meridional and vertical variations of the water vapour isotopic composition in the marine boundary layer over the Atlantic and Southern Ocean I. Thurnherr et al. 10.5194/acp-20-5811-2020
- The role of air–sea fluxes for the water vapour isotope signals in the cold and warm sectors of extratropical cyclones over the Southern Ocean I. Thurnherr et al. 10.5194/wcd-2-331-2021
- Water vapor stable isotope memory effects of common tubing materials A. Meyer & L. Welp 10.5194/amt-17-6193-2024
- Disentangling the impact of air–sea interaction and boundary layer cloud formation on stable water isotope signals in the warm sector of a Southern Ocean cyclone I. Thurnherr & F. Aemisegger 10.5194/acp-22-10353-2022
- What Controls the Water Vapor Isotopic Composition Near the Surface of Tropical Oceans? Results From an Analytical Model Constrained by Large‐Eddy Simulations C. Risi et al. 10.1029/2020MS002106
- Experimental investigation of the stable water isotope distribution in an Alpine lake environment (L-WAIVE) P. Chazette et al. 10.5194/acp-21-10911-2021
- Deuterium excess and <sup>17</sup>O-excess variability in meteoric water across the Pacific Northwest, USA J. Bershaw et al. 10.1080/16000889.2020.1773722
- Isotopic Signature of Precipitation in the Elbrus Region J. Chizhova et al. 10.31857/S2076673423010052
- Vehicle-based in situ observations of the water vapor isotopic composition across China: spatial and seasonal distributions and controls D. Wang et al. 10.5194/acp-23-3409-2023
- Vertical profile observations of water vapor deuterium excess in the lower troposphere O. Salmon et al. 10.5194/acp-19-11525-2019
18 citations as recorded by crossref.
- Determining the Isotopic Composition of Surface Water Vapor Flux From High‐Frequency Observations Using Flux‐Gradient and Keeling Plot Methods Y. Hu et al. 10.1029/2020EA001304
- What causes site-specific intra-event variations of stable isotopes in precipitation in Beijing? Y. Tang et al. 10.1016/j.atmosres.2023.107052
- Isotopic Signature of Precipitation in the Elbrus Region J. Chizhova et al. 10.1134/S0001433823130054
- Water isotopic characterisation of the cloud–circulation coupling in the North Atlantic trades – Part 1: A process-oriented evaluation of COSMOiso simulations with EUREC4A observations L. Villiger et al. 10.5194/acp-23-14643-2023
- Isotopic measurements in water vapor, precipitation, and seawater during EUREC4A A. Bailey et al. 10.5194/essd-15-465-2023
- A set of methods to evaluate the below-cloud evaporation effect on local precipitation isotopic composition: a case study for Xi'an, China M. Xing et al. 10.5194/acp-23-9123-2023
- Is the deuterium excess in precipitation a reliable tracer of moisture sources and water resources fate in the western Mediterranean? New insights from Apuan Alps (Italy) S. Natali et al. 10.1016/j.jhydrol.2022.128497
- Lake Spray Aerosol Incorporated into Great Lakes Clouds N. Olson et al. 10.1021/acsearthspacechem.9b00258
- Toward a process-oriented understanding of water in the climate system: recent insights from stable isotopes A. Bailey et al. 10.1088/2752-5295/ada17b
- Meridional and vertical variations of the water vapour isotopic composition in the marine boundary layer over the Atlantic and Southern Ocean I. Thurnherr et al. 10.5194/acp-20-5811-2020
- The role of air–sea fluxes for the water vapour isotope signals in the cold and warm sectors of extratropical cyclones over the Southern Ocean I. Thurnherr et al. 10.5194/wcd-2-331-2021
- Water vapor stable isotope memory effects of common tubing materials A. Meyer & L. Welp 10.5194/amt-17-6193-2024
- Disentangling the impact of air–sea interaction and boundary layer cloud formation on stable water isotope signals in the warm sector of a Southern Ocean cyclone I. Thurnherr & F. Aemisegger 10.5194/acp-22-10353-2022
- What Controls the Water Vapor Isotopic Composition Near the Surface of Tropical Oceans? Results From an Analytical Model Constrained by Large‐Eddy Simulations C. Risi et al. 10.1029/2020MS002106
- Experimental investigation of the stable water isotope distribution in an Alpine lake environment (L-WAIVE) P. Chazette et al. 10.5194/acp-21-10911-2021
- Deuterium excess and <sup>17</sup>O-excess variability in meteoric water across the Pacific Northwest, USA J. Bershaw et al. 10.1080/16000889.2020.1773722
- Isotopic Signature of Precipitation in the Elbrus Region J. Chizhova et al. 10.31857/S2076673423010052
- Vehicle-based in situ observations of the water vapor isotopic composition across China: spatial and seasonal distributions and controls D. Wang et al. 10.5194/acp-23-3409-2023
1 citations as recorded by crossref.
Latest update: 09 Jul 2025
Short summary
We conducted airborne vertical profile measurements of water vapor stable isotopes to examine how boundary layer, cloud, and mixing processes influence the vertical structure of deuterium excess in the lower troposphere. We discuss reasons our observations are consistent with water vapor isotope theory on some days and not others. Deuterium excess may be useful for understanding complex processes occurring at the top of the boundary layer, including cloud formation, evaporation, and air mixing.
We conducted airborne vertical profile measurements of water vapor stable isotopes to examine...
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