Articles | Volume 18, issue 13
https://doi.org/10.5194/acp-18-9297-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-9297-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Estimation of rate coefficients and branching ratios for gas-phase reactions of OH with aliphatic organic compounds for use in automated mechanism construction
Michael E. Jenkin
CORRESPONDING AUTHOR
Atmospheric Chemistry Services, Okehampton, Devon, EX20 4QB, UK
School of Chemistry, University of Bristol, Cantock's Close, Bristol,
BS8 1TS, UK
Richard Valorso
LISA, UMR CNRS 7583, Université Paris Est Créteil et
Université Paris Diderot, Institut Pierre Simon Laplace, 94010
Créteil, France
Bernard Aumont
LISA, UMR CNRS 7583, Université Paris Est Créteil et
Université Paris Diderot, Institut Pierre Simon Laplace, 94010
Créteil, France
Andrew R. Rickard
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York, YO10 5DD, UK
National Centre for Atmospheric Science, University of York, York,
YO10 5DD, UK
Timothy J. Wallington
Research and Advanced Engineering, Ford Motor Company, SRL-3083,
P.O. Box 2053, Dearborn, MI 48121-2053, USA
Viewed
Total article views: 5,508 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Feb 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,175 | 2,167 | 166 | 5,508 | 445 | 164 | 200 |
- HTML: 3,175
- PDF: 2,167
- XML: 166
- Total: 5,508
- Supplement: 445
- BibTeX: 164
- EndNote: 200
Total article views: 4,623 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 04 Jul 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,809 | 1,665 | 149 | 4,623 | 294 | 155 | 188 |
- HTML: 2,809
- PDF: 1,665
- XML: 149
- Total: 4,623
- Supplement: 294
- BibTeX: 155
- EndNote: 188
Total article views: 885 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Feb 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 366 | 502 | 17 | 885 | 151 | 9 | 12 |
- HTML: 366
- PDF: 502
- XML: 17
- Total: 885
- Supplement: 151
- BibTeX: 9
- EndNote: 12
Viewed (geographical distribution)
Total article views: 5,508 (including HTML, PDF, and XML)
Thereof 5,467 with geography defined
and 41 with unknown origin.
Total article views: 4,623 (including HTML, PDF, and XML)
Thereof 4,607 with geography defined
and 16 with unknown origin.
Total article views: 885 (including HTML, PDF, and XML)
Thereof 860 with geography defined
and 25 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
80 citations as recorded by crossref.
- Estimation of rate coefficients and branching ratios for reactions of organic peroxy radicals for use in automated mechanism construction M. Jenkin et al.
- Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen) W. Carter et al.
- Rate coefficients of hydroxyl radical reaction with 1-chlorocyclopentene over a temperature range of 262–335 K A. Sharma et al.
- Estimation of mechanistic parameters in the gas-phase reactions of ozone with alkenes for use in automated mechanism construction M. Newland et al.
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al.
- Atmospheric Autoxidation Chemistry of Diethyl Ether H. Yu et al.
- Rate coefficients for the reactions of OH radical and ozone with a series of unsaturated esters Y. Ren et al.
- Atmospheric reactions of substituted butanes with OH radicals: kinetics and atmospheric implications B. Kar & B. Rajakumar
- OH radical and Cl atom initiated Reactions of Methyl n-propyl ether: Kinetics and Atmospheric Implications B. Kar & B. Rajakumar
- Rate coefficients for the reactions of OH radicals with C3–C11 alkanes determined by the relative-rate technique Y. Xin et al.
- Extension, development, and evaluation of the representation of the OH-initiated dimethyl sulfide (DMS) oxidation mechanism in the Master Chemical Mechanism (MCM) v3.3.1 framework L. Jacob et al.
- Evolution of Atmospheric Total Organic Carbon from Petrochemical Mixtures K. Li et al.
- Estimation of Rate Constants for Reactions of Organic Compounds under Atmospheric Conditions W. Carter
- Theoretical analysis of the OH-initiated atmospheric oxidation reactions of imidazole T. Golin Almeida et al.
- Detailed Investigation of 2,3-Dimethyl-2-butene Ozonolysis-Derived Hydroxyl, Peroxy, and Alkoxy Radical Chemistry B. Frandsen et al.
- Pesticide fate and transport in the atmosphere and implications for risk assessment C. Bedos et al.
- Tropospheric degradation of nerol: Kinetics with OH radicals, product distribution in the presence of NOx and atmospheric implications G. Mahecha et al.
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al.
- Investigating the Impacts of Nonacyl Peroxy Nitrates on the Global Composition of the Troposphere Using a 3-D Chemical Transport Model, STOCHEM-CRI M. Khan et al.
- Diurnal photodegradation of fluorinated diketones (FDKs) by OH radicals using different atmospheric simulation chambers: Role of keto-enol tautomerization on reactivity P. Lugo et al.
- Estimation of rate coefficients and branching ratios for gas-phase reactions of OH with aromatic organic compounds for use in automated mechanism construction M. Jenkin et al.
- Reactions of tropospheric oxidants- Cl, OH and O3 with cyclic hydrocarbons with eight carbon atoms at 298 K A. Sharma et al.
- Opinion: Challenges and needs of tropospheric chemical mechanism development B. Ervens et al.
- Practical atmospheric photochemical kinetics for undergraduate teaching and research J. D'Souza Metcalf et al.
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al.
- Temperature-Dependent, Site-Specific Rate Coefficients for the Reaction of OH (OD) with Methyl Formate Isotopologues via Experimental and Theoretical Studies N. Robertson et al.
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al.
- Atmospheric oxidation of hydroxymethyl methyl α-lactone (HMML), initiated by OH radicals and Cl atoms S. Daimari et al.
- Reactivity study of 3,3-dimethylbutanal and 3,3-dimethylbutanone: kinetics, reaction products, mechanisms, and atmospheric implications I. Aranda et al.
- Atmospheric Autoxidation of Amines K. Møller et al.
- Relative Rate Coefficients for the Reactions of HO2 Radicals with Hydroxy-Substituted Alkyl Peroxy Radicals, and for Reactions of OH Radicals with Hydroxy Hydroperoxides G. Tyndall et al.
- Atmospheric oxidation of new “green” solvents – Part 2: methyl pivalate and pinacolone C. Mapelli et al.
- An aldehyde as a rapid source of secondary aerosol precursors: theoretical and experimental study of hexanal autoxidation S. Barua et al.
- Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures L. Han et al.
- Gas-Phase Kinetics of a Series of cis-3-Hexenyl Esters with OH Radicals under Simulated Atmospheric Conditions C. Mairean et al.
- Aqueous OH kinetics of saturated C6–C10 dicarboxylic acids under acidic and basic conditions between 283 and 318 K; new structure-activity relationship parameters B. Witkowski et al.
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al.
- Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique J. Shaw et al.
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al.
- Estimation of rate coefficients for the reactions of O3 with unsaturated organic compounds for use in automated mechanism construction M. Jenkin et al.
- Kinetic study of the atmospheric oxidation of a series of epoxy compounds by OH radicals C. Tovar et al.
- Impact of organic molecular structure on the estimation of atmospherically relevant physicochemical parameters G. Isaacman-VanWertz & B. Aumont
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al.
- Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis L. Franzon et al.
- Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms: Reactivity trends, mechanism, and acid formation yields P. Lugo et al.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al.
- The gas-phase reaction kinetics of different structure of unsaturated alcohols and ketones with O3 W. Li et al.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al.
- Estimating rate coefficients for the reactions of ethers + OH from atmospheric to combustion temperatures: an extension of the electrotopological state method L. Michelat et al.
- Formation of highly oxygenated organic molecules from α-pinene photooxidation: evidence for the importance of highly oxygenated alkoxy radicals S. Kang et al.
- Atmospheric oxidation of α,β-unsaturated ketones: kinetics and mechanism of the OH radical reaction N. Illmann et al.
- Developing the Maximum Incremental Reactivity for Volatile Organic Compounds in Major Cities of Central‐Eastern China Y. Zhang et al.
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet
- Stealing from a distant neighbor: an unexpectedly fast long-span peroxy radical hydrogen-shift reaction in a long-chain diether H. Yu et al.
- Atmospheric Degradation of CH2═C(CH3)C(O)O[CH2]4CH3 by •OH Radicals: Reactivity, POCP, and Carbonyl Formation V. Straccia Cepeda et al.
- Assessing Air Quality Impacts of Greener Chemicals: Beyond Traditional Metrics J. D’Souza Metcalf et al.
- Automatization of Atmospheric OH Radical Abstraction Reactions D. Ayoubi et al.
- Importance of Particle-Phase Reactions in the Growth of Newly Formed Particles V. Vasudevan-Geetha et al.
- Mechanism Development and Evaluation of the Gas-Phase Photooxidation of Guaiacol: Insights from a Chamber Study R. Evans et al.
- Atmospheric oxidation of long chain aldehydes: OH and Cl reactivity, mechanisms and environmental impact F. Aguirre et al.
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al.
- An improved multiphase chemistry mechanism for methylamines: significant dimethylamine cloud production E. Hoffmann et al.
- Impact of Molecular Structure on the OH-Initiated Oxidation Mechanism of 2-(2-Ethoxyethoxy)ethanol and Resulting Aerosol Formation T. Melles et al.
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and α-pinene T. Galeazzo et al.
- Modeling SOA Formation from Monocyclic, Bicyclic, and Branched-Cyclic Alkanes A. Madhu & M. Jang
- Temperature dependent rate constants for the gas phase reactions of OH radical with first generation products of monoterpenes oxidation: nopinone, limononaldehyde, myrtenal and ketolimonene M. Fakih et al.
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al.
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al.
- Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour C. Roman et al.
- Kinetics of the reaction of OH radical with ethylfluoroacetate, ethyl 4,4,4-trifluorobutyrate, and butylfluoroacetate P. Lugo et al.
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al.
- The atmospheric fate of ethyl and neopentyl nitrates: ·OH-oxidation mechanism, kinetic property, and environmental impacts X. Liu et al.
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al.
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al.
- Atmospheric fate of a series of saturated alcohols: kinetic and mechanistic study I. Colmenar et al.
- Atmospheric Photo-Oxidation of 2-Ethoxyethanol: Autoxidation Chemistry of Glycol Ethers H. Yu et al.
- Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals C. Mapelli et al.
- Gas–particle partitioning of toluene oxidation products: an experimental and modeling study V. Lannuque et al.
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al.
- Gas-Phase Kinetic Investigation of the OH-Initiated Oxidation of a Series of Methyl-Butenols under Simulated Atmospheric Conditions A. Rusu (Vasilache) et al.
80 citations as recorded by crossref.
- Estimation of rate coefficients and branching ratios for reactions of organic peroxy radicals for use in automated mechanism construction M. Jenkin et al.
- Derivation of atmospheric reaction mechanisms for volatile organic compounds by the SAPRC mechanism generation system (MechGen) W. Carter et al.
- Rate coefficients of hydroxyl radical reaction with 1-chlorocyclopentene over a temperature range of 262–335 K A. Sharma et al.
- Estimation of mechanistic parameters in the gas-phase reactions of ozone with alkenes for use in automated mechanism construction M. Newland et al.
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al.
- Atmospheric Autoxidation Chemistry of Diethyl Ether H. Yu et al.
- Rate coefficients for the reactions of OH radical and ozone with a series of unsaturated esters Y. Ren et al.
- Atmospheric reactions of substituted butanes with OH radicals: kinetics and atmospheric implications B. Kar & B. Rajakumar
- OH radical and Cl atom initiated Reactions of Methyl n-propyl ether: Kinetics and Atmospheric Implications B. Kar & B. Rajakumar
- Rate coefficients for the reactions of OH radicals with C3–C11 alkanes determined by the relative-rate technique Y. Xin et al.
- Extension, development, and evaluation of the representation of the OH-initiated dimethyl sulfide (DMS) oxidation mechanism in the Master Chemical Mechanism (MCM) v3.3.1 framework L. Jacob et al.
- Evolution of Atmospheric Total Organic Carbon from Petrochemical Mixtures K. Li et al.
- Estimation of Rate Constants for Reactions of Organic Compounds under Atmospheric Conditions W. Carter
- Theoretical analysis of the OH-initiated atmospheric oxidation reactions of imidazole T. Golin Almeida et al.
- Detailed Investigation of 2,3-Dimethyl-2-butene Ozonolysis-Derived Hydroxyl, Peroxy, and Alkoxy Radical Chemistry B. Frandsen et al.
- Pesticide fate and transport in the atmosphere and implications for risk assessment C. Bedos et al.
- Tropospheric degradation of nerol: Kinetics with OH radicals, product distribution in the presence of NOx and atmospheric implications G. Mahecha et al.
- The Common Representative Intermediates Mechanism Version 2 in the United Kingdom Chemistry and Aerosols Model S. Archer‐Nicholls et al.
- Investigating the Impacts of Nonacyl Peroxy Nitrates on the Global Composition of the Troposphere Using a 3-D Chemical Transport Model, STOCHEM-CRI M. Khan et al.
- Diurnal photodegradation of fluorinated diketones (FDKs) by OH radicals using different atmospheric simulation chambers: Role of keto-enol tautomerization on reactivity P. Lugo et al.
- Estimation of rate coefficients and branching ratios for gas-phase reactions of OH with aromatic organic compounds for use in automated mechanism construction M. Jenkin et al.
- Reactions of tropospheric oxidants- Cl, OH and O3 with cyclic hydrocarbons with eight carbon atoms at 298 K A. Sharma et al.
- Opinion: Challenges and needs of tropospheric chemical mechanism development B. Ervens et al.
- Practical atmospheric photochemical kinetics for undergraduate teaching and research J. D'Souza Metcalf et al.
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al.
- Temperature-Dependent, Site-Specific Rate Coefficients for the Reaction of OH (OD) with Methyl Formate Isotopologues via Experimental and Theoretical Studies N. Robertson et al.
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al.
- Atmospheric oxidation of hydroxymethyl methyl α-lactone (HMML), initiated by OH radicals and Cl atoms S. Daimari et al.
- Reactivity study of 3,3-dimethylbutanal and 3,3-dimethylbutanone: kinetics, reaction products, mechanisms, and atmospheric implications I. Aranda et al.
- Atmospheric Autoxidation of Amines K. Møller et al.
- Relative Rate Coefficients for the Reactions of HO2 Radicals with Hydroxy-Substituted Alkyl Peroxy Radicals, and for Reactions of OH Radicals with Hydroxy Hydroperoxides G. Tyndall et al.
- Atmospheric oxidation of new “green” solvents – Part 2: methyl pivalate and pinacolone C. Mapelli et al.
- An aldehyde as a rapid source of secondary aerosol precursors: theoretical and experimental study of hexanal autoxidation S. Barua et al.
- Rate Constants for the Reaction of OH Radicals with Hydrocarbons in a Smog Chamber at Low Atmospheric Temperatures L. Han et al.
- Gas-Phase Kinetics of a Series of cis-3-Hexenyl Esters with OH Radicals under Simulated Atmospheric Conditions C. Mairean et al.
- Aqueous OH kinetics of saturated C6–C10 dicarboxylic acids under acidic and basic conditions between 283 and 318 K; new structure-activity relationship parameters B. Witkowski et al.
- Photolysis and oxidation by OH radicals of two carbonyl nitrates: 4-nitrooxy-2-butanone and 5-nitrooxy-2-pentanone B. Picquet-Varrault et al.
- Rate coefficients for reactions of OH with aromatic and aliphatic volatile organic compounds determined by the multivariate relative rate technique J. Shaw et al.
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al.
- Estimation of rate coefficients for the reactions of O3 with unsaturated organic compounds for use in automated mechanism construction M. Jenkin et al.
- Kinetic study of the atmospheric oxidation of a series of epoxy compounds by OH radicals C. Tovar et al.
- Impact of organic molecular structure on the estimation of atmospherically relevant physicochemical parameters G. Isaacman-VanWertz & B. Aumont
- On the importance of multiphase photolysis of organic nitrates on their global atmospheric removal J. González-Sánchez et al.
- Ether and ester formation from peroxy radical recombination: a qualitative reaction channel analysis L. Franzon et al.
- Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms: Reactivity trends, mechanism, and acid formation yields P. Lugo et al.
- Atmospheric breakdown kinetics and air quality impact of potential “green” solvents, the oxymethylene ethers OME3 and OME4 J. D'Souza Metcalf et al.
- The gas-phase reaction kinetics of different structure of unsaturated alcohols and ketones with O3 W. Li et al.
- Kinetics, products and mechanisms of the OH radicals and Cl atoms reactions with trans-2-octene and cycloheptene G. Imwinkelried et al.
- Estimating rate coefficients for the reactions of ethers + OH from atmospheric to combustion temperatures: an extension of the electrotopological state method L. Michelat et al.
- Formation of highly oxygenated organic molecules from α-pinene photooxidation: evidence for the importance of highly oxygenated alkoxy radicals S. Kang et al.
- Atmospheric oxidation of α,β-unsaturated ketones: kinetics and mechanism of the OH radical reaction N. Illmann et al.
- Developing the Maximum Incremental Reactivity for Volatile Organic Compounds in Major Cities of Central‐Eastern China Y. Zhang et al.
- Development of a detailed gaseous oxidation scheme of naphthalene for secondary organic aerosol (SOA) formation and speciation V. Lannuque & K. Sartelet
- Stealing from a distant neighbor: an unexpectedly fast long-span peroxy radical hydrogen-shift reaction in a long-chain diether H. Yu et al.
- Atmospheric Degradation of CH2═C(CH3)C(O)O[CH2]4CH3 by •OH Radicals: Reactivity, POCP, and Carbonyl Formation V. Straccia Cepeda et al.
- Assessing Air Quality Impacts of Greener Chemicals: Beyond Traditional Metrics J. D’Souza Metcalf et al.
- Automatization of Atmospheric OH Radical Abstraction Reactions D. Ayoubi et al.
- Importance of Particle-Phase Reactions in the Growth of Newly Formed Particles V. Vasudevan-Geetha et al.
- Mechanism Development and Evaluation of the Gas-Phase Photooxidation of Guaiacol: Insights from a Chamber Study R. Evans et al.
- Atmospheric oxidation of long chain aldehydes: OH and Cl reactivity, mechanisms and environmental impact F. Aguirre et al.
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al.
- An improved multiphase chemistry mechanism for methylamines: significant dimethylamine cloud production E. Hoffmann et al.
- Impact of Molecular Structure on the OH-Initiated Oxidation Mechanism of 2-(2-Ethoxyethoxy)ethanol and Resulting Aerosol Formation T. Melles et al.
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and α-pinene T. Galeazzo et al.
- Modeling SOA Formation from Monocyclic, Bicyclic, and Branched-Cyclic Alkanes A. Madhu & M. Jang
- Temperature dependent rate constants for the gas phase reactions of OH radical with first generation products of monoterpenes oxidation: nopinone, limononaldehyde, myrtenal and ketolimonene M. Fakih et al.
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al.
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al.
- Investigations into the gas-phase photolysis and OH radical kinetics of nitrocatechols: implications of intramolecular interactions on their atmospheric behaviour C. Roman et al.
- Kinetics of the reaction of OH radical with ethylfluoroacetate, ethyl 4,4,4-trifluorobutyrate, and butylfluoroacetate P. Lugo et al.
- Gas-Phase Photolysis and Photo-Oxidation of Isoprene-Derived Atmospherically Relevant Hydroxy Nitrates R. Verma et al.
- The atmospheric fate of ethyl and neopentyl nitrates: ·OH-oxidation mechanism, kinetic property, and environmental impacts X. Liu et al.
- On the importance of atmospheric loss of organic nitrates by aqueous-phase ●OH oxidation J. González-Sánchez et al.
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al.
- Atmospheric fate of a series of saturated alcohols: kinetic and mechanistic study I. Colmenar et al.
- Atmospheric Photo-Oxidation of 2-Ethoxyethanol: Autoxidation Chemistry of Glycol Ethers H. Yu et al.
- Atmospheric breakdown chemistry of the new “green” solvent 2,2,5,5-tetramethyloxolane via gas-phase reactions with OH and Cl radicals C. Mapelli et al.
- Gas–particle partitioning of toluene oxidation products: an experimental and modeling study V. Lannuque et al.
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al.
- Gas-Phase Kinetic Investigation of the OH-Initiated Oxidation of a Series of Methyl-Butenols under Simulated Atmospheric Conditions A. Rusu (Vasilache) et al.
Saved (final revised paper)
Latest update: 04 May 2026
Download
- Article
(7045 KB) - Full-text XML
Short summary
Organic compounds are emitted in large quantities from natural and human-influenced sources. Removal from the atmosphere occurs mainly by reaction with hydroxyl (OH) radicals, and initiates reaction sequences forming pollutants such as ozone and organic particles. Due to their very large number, it is impossible to measure the removal rate for all compounds, and most have to be estimated. An updated and extended estimation method is reported for use in atmospheric models and impact assessments.
Organic compounds are emitted in large quantities from natural and human-influenced sources....
Altmetrics
Final-revised paper
Preprint