Articles | Volume 18, issue 10
Atmos. Chem. Phys., 18, 7109–7129, 2018
https://doi.org/10.5194/acp-18-7109-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 7109–7129, 2018
https://doi.org/10.5194/acp-18-7109-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article 24 May 2018
Research article | 24 May 2018
Global modelling of the total OH reactivity: investigations on the “missing” OH sink and its atmospheric implications
Valerio Ferracci et al.
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Cited
20 citations as recorded by crossref.
- Peroxy radical kinetics and new particle formation M. Schervish & N. Donahue 10.1039/D0EA00017E
- Continuous Isoprene Measurements in a UK Temperate Forest for a Whole Growing Season: Effects of Drought Stress During the 2018 Heatwave V. Ferracci et al. 10.1029/2020GL088885
- Parameterized atmospheric oxidation capacity and speciated OH reactivity over a suburban site in the North China Plain: A comparative study between summer and winter Y. Yang et al. 10.1016/j.scitotenv.2021.145264
- The Global Budget of Atmospheric Methanol: New Constraints on Secondary, Oceanic, and Terrestrial Sources K. Bates et al. 10.1029/2020JD033439
- Tropospheric oxidation of methyl hydrotrioxide (CH3OOOH) by hydroxyl radical J. Anglada & A. Solé 10.1039/C8CP04486D
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Distribution and regeneration of hydroxyl free radicals in gaseous and particulate phases of pollutants in near-ground ambient air G. Wang et al. 10.1016/j.scitotenv.2019.05.300
- Pressure-Dependent Kinetics of the Reaction between CH3OO and OH Focusing on the Product Yield of Methyltrioxide (CH3OOOH) F. Zhang & C. Huang 10.1021/acs.jpclett.9b00781
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- Experimental and theoretical investigation of the reaction of RO2radicals with OH radicals: Dependence of the HO2yield on the size of the alkyl group E. Assaf et al. 10.1002/kin.21191
- OH reactivity from the emissions of different tree species: investigating the missing reactivity in a boreal forest A. Praplan et al. 10.5194/bg-17-4681-2020
- BrHgO• + CO: Analogue of OH + CO and Reduction Path for Hg(II) in the Atmosphere D. Khiri et al. 10.1021/acsearthspacechem.0c00171
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure E. Pfannerstill et al. 10.5194/acp-21-6231-2021
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
- The reaction of peroxy radicals with OH radicals C. Fittschen 10.1016/j.cplett.2019.04.002
- Using a virtual machine environment for developing, testing, and training for the UM-UKCA composition-climate model, using Unified Model version 10.9 and above N. Abraham et al. 10.5194/gmd-11-3647-2018
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol R. Caravan et al. 10.1038/s41467-018-06716-x
20 citations as recorded by crossref.
- Peroxy radical kinetics and new particle formation M. Schervish & N. Donahue 10.1039/D0EA00017E
- Continuous Isoprene Measurements in a UK Temperate Forest for a Whole Growing Season: Effects of Drought Stress During the 2018 Heatwave V. Ferracci et al. 10.1029/2020GL088885
- Parameterized atmospheric oxidation capacity and speciated OH reactivity over a suburban site in the North China Plain: A comparative study between summer and winter Y. Yang et al. 10.1016/j.scitotenv.2021.145264
- The Global Budget of Atmospheric Methanol: New Constraints on Secondary, Oceanic, and Terrestrial Sources K. Bates et al. 10.1029/2020JD033439
- Tropospheric oxidation of methyl hydrotrioxide (CH3OOOH) by hydroxyl radical J. Anglada & A. Solé 10.1039/C8CP04486D
- Atmospheric reactivity and oxidation capacity during summer at a suburban site between Beijing and Tianjin Y. Yang et al. 10.5194/acp-20-8181-2020
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Distribution and regeneration of hydroxyl free radicals in gaseous and particulate phases of pollutants in near-ground ambient air G. Wang et al. 10.1016/j.scitotenv.2019.05.300
- Pressure-Dependent Kinetics of the Reaction between CH3OO and OH Focusing on the Product Yield of Methyltrioxide (CH3OOOH) F. Zhang & C. Huang 10.1021/acs.jpclett.9b00781
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- Experimental and theoretical investigation of the reaction of RO2radicals with OH radicals: Dependence of the HO2yield on the size of the alkyl group E. Assaf et al. 10.1002/kin.21191
- OH reactivity from the emissions of different tree species: investigating the missing reactivity in a boreal forest A. Praplan et al. 10.5194/bg-17-4681-2020
- BrHgO• + CO: Analogue of OH + CO and Reduction Path for Hg(II) in the Atmosphere D. Khiri et al. 10.1021/acsearthspacechem.0c00171
- Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air C. Wu et al. 10.5194/acp-20-14769-2020
- Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure E. Pfannerstill et al. 10.5194/acp-21-6231-2021
- Significant decreases in the volatile organic compound concentration, atmospheric oxidation capacity and photochemical reactivity during the National Day holiday over a suburban site in the North China Plain Y. Yang et al. 10.1016/j.envpol.2020.114657
- The reaction of peroxy radicals with OH radicals C. Fittschen 10.1016/j.cplett.2019.04.002
- Using a virtual machine environment for developing, testing, and training for the UM-UKCA composition-climate model, using Unified Model version 10.9 and above N. Abraham et al. 10.5194/gmd-11-3647-2018
- Constraining remote oxidation capacity with ATom observations K. Travis et al. 10.5194/acp-20-7753-2020
- The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol R. Caravan et al. 10.1038/s41467-018-06716-x
Discussed (final revised paper)
Latest update: 17 May 2021
Short summary
Hydroxyl radicals (OH) control the removal of species emitted in the atmosphere. Field campaigns reported a "missing" OH sink, not included in current atmospheric models. In this work a global model was used to establish the impact of additional OH sinks, based on both observations of the missing sink and newly discovered reactions of OH. Results show modest increases in global atmospheric lifetimes but pronounced regional effects on the abundance of some key species.
Hydroxyl radicals (OH) control the removal of species emitted in the atmosphere. Field campaigns...
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