Articles | Volume 18, issue 9
https://doi.org/10.5194/acp-18-6625-2018
https://doi.org/10.5194/acp-18-6625-2018
Research article
 | 
09 May 2018
Research article |  | 09 May 2018

Mass spectrometric measurement of hydrogen isotope fractionation for the reactions of chloromethane with OH and Cl

Frank Keppler, Enno Bahlmann, Markus Greule, Heinz Friedrich Schöler, Julian Wittmer, and Cornelius Zetzsch

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Short summary
Chloromethane is involved in stratospheric ozone depletion, but detailed knowledge of its global budget is missing. In this study stable hydrogen isotope analyses were performed to investigate the dominant loss process for atmospheric chloromethane with photochemically produced hydroxyl radicals. The findings might have significant implications for the use of stable isotope signatures in elucidation of global chloromethane cycling.
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