Articles | Volume 18, issue 8
https://doi.org/10.5194/acp-18-6095-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-6095-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
02 May 2018
Research article |
| 02 May 2018
| 02 May 2018
The atmospheric impacts of monoterpene ozonolysis on global stabilised Criegee intermediate budgets and SO2 oxidation: experiment, theory and modelling
Mike J. Newland
CORRESPONDING AUTHOR
University of Birmingham, School of Geography, Earth and Environmental Sciences, Birmingham, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Andrew R. Rickard
CORRESPONDING AUTHOR
National Centre for Atmospheric Science (NCAS), University of York, York, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Mathew J. Evans
National Centre for Atmospheric Science (NCAS), University of York, York, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Luc Vereecken
Max Planck Institute for Chemistry, Atmospheric Sciences, Hahn-Meitner-Weg 1, Mainz, Germany
Institute for Energy and Climate Research, Forschungszentrum Jülich GmbH, Jülich, Germany
Amalia Muñoz
Fundación CEAM, EUPHORE Laboratories, Avda/Charles R. Darwin 14. Parque Tecnologico, Valencia, Spain
Milagros Ródenas
Fundación CEAM, EUPHORE Laboratories, Avda/Charles R. Darwin 14. Parque Tecnologico, Valencia, Spain
William J. Bloss
University of Birmingham, School of Geography, Earth and Environmental Sciences, Birmingham, UK
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- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. 10.1039/D2CP02849B
- Importance of Hydroxyl Radical Chemistry in Isoprene Suppression of Particle Formation from α-Pinene Ozonolysis Y. Wang et al. 10.1021/acsearthspacechem.0c00294
- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. 10.1039/D2CP01118B
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact T. Stephenson & M. Lester 10.1080/0144235X.2020.1688530
- Role of Criegee intermediates in the formation of sulfuric acid at a Mediterranean (Cape Corsica) site under influence of biogenic emissions A. Kukui et al. 10.5194/acp-21-13333-2021
- Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene T. Berndt et al. 10.1021/acs.est.8b02210
- Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry B. Long et al. 10.1038/s41467-019-09948-7
- Atmospheric degradation of two pesticides mixed with volatile organic compounds emitted by citrus trees. Ozone and secondary organic aerosol production A. Muñoz et al. 10.1016/j.atmosenv.2022.119541
- Sulfur Dioxide Modifies Aerosol Particle Formation and Growth by Ozonolysis of Monoterpenes and Isoprene C. Stangl et al. 10.1029/2018JD030064
- Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates R. Cox et al. 10.5194/acp-20-13497-2020
- Isolating α-Pinene Ozonolysis Pathways Reveals New Insights into Peroxy Radical Chemistry and Secondary Organic Aerosol Formation Z. Zhao et al. 10.1021/acs.est.1c02107
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. 10.1080/02786826.2019.1568381
- Theoretical study on the formation of Criegee intermediates from ozonolysis of pentenal: An example of trans-2-pentenal W. Xiao et al. 10.1016/j.chemosphere.2022.135142
- Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase A. Zaytsev et al. 10.5194/amt-14-2501-2021
- Carbonyl Oxide Stabilization from Trans Alkene and Terpene Ozonolysis J. Hakala & N. Donahue 10.1021/acs.jpca.3c03650
- Theoretical Study on Criegee Intermediate’s Role in Ozonolysis of Acrylic Acid X. Lin et al. 10.1021/acs.jpca.8b11671
- Impact of Criegee Intermediate Reactions with Peroxy Radicals on Tropospheric Organic Aerosol R. Chhantyal-Pun et al. 10.1021/acsearthspacechem.0c00147
- Increased primary and secondary H<sub>2</sub>SO<sub>4</sub> showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Modeling the Unimolecular Decay Dynamics of the Fluorinated Criegee Intermediate, CF3CHOO L. Guidry et al. 10.3390/photochem3030020
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- Trends in stabilisation of Criegee intermediates from alkene ozonolysis M. Newland et al. 10.1039/D0CP00897D
- Theoretical study on the degradation mechanism, kinetics and toxicity for aqueous ozonation reaction of furan derivatives W. Xiao et al. 10.1016/j.chemosphere.2023.138782
- Acylperoxy Radicals as Key Intermediates in the Formation of Dimeric Compounds in α-Pinene Secondary Organic Aerosol Y. Zhao et al. 10.1021/acs.est.2c02090
- Peroxy Radical and Product Formation in the Gas-Phase Ozonolysis of α-Pinene under Near-Atmospheric Conditions: Occurrence of an Additional Series of Peroxy Radicals O,O–C10H15O(O2)yO2 with y = 1–3 T. Berndt 10.1021/acs.jpca.2c05094
- Estimation of mechanistic parameters in the gas-phase reactions of ozone with alkenes for use in automated mechanism construction M. Newland et al. 10.5194/acp-22-6167-2022
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- Criegee intermediates: production, detection and reactivity R. Chhantyal-Pun et al. 10.1080/0144235X.2020.1792104
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- New particle formation from the reactions of ozone with indene and styrene L. Bracco et al. 10.1039/C9CP00912D
- Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications S. Liu et al. 10.1016/j.atmosenv.2023.120012
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al. 10.1039/C9CP06306D
- Impacts of the Degradation of 2,3,3,3-Tetrafluoropropene into Trifluoroacetic Acid from Its Application in Automobile Air Conditioners in China, the United States, and Europe Z. Wang et al. 10.1021/acs.est.7b05960
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Criegee intermediates and their impacts on the troposphere M. Khan et al. 10.1039/C7EM00585G
32 citations as recorded by crossref.
- Quantitative kinetics for the atmospheric reactions of Criegee intermediates with acetonitrile Y. Zhang et al. 10.1039/D2CP02849B
- Importance of Hydroxyl Radical Chemistry in Isoprene Suppression of Particle Formation from α-Pinene Ozonolysis Y. Wang et al. 10.1021/acsearthspacechem.0c00294
- Temperature-dependent kinetics of the atmospheric reaction between CH2OO and acetone P. Wang et al. 10.1039/D2CP01118B
- Persistence of Monoterpene-Derived Organic Peroxides in the Atmospheric Aqueous Phase Z. Liu et al. 10.1021/acsearthspacechem.2c00145
- Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact T. Stephenson & M. Lester 10.1080/0144235X.2020.1688530
- Role of Criegee intermediates in the formation of sulfuric acid at a Mediterranean (Cape Corsica) site under influence of biogenic emissions A. Kukui et al. 10.5194/acp-21-13333-2021
- Accretion Product Formation from Ozonolysis and OH Radical Reaction of α-Pinene: Mechanistic Insight and the Influence of Isoprene and Ethylene T. Berndt et al. 10.1021/acs.est.8b02210
- Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry B. Long et al. 10.1038/s41467-019-09948-7
- Atmospheric degradation of two pesticides mixed with volatile organic compounds emitted by citrus trees. Ozone and secondary organic aerosol production A. Muñoz et al. 10.1016/j.atmosenv.2022.119541
- Sulfur Dioxide Modifies Aerosol Particle Formation and Growth by Ozonolysis of Monoterpenes and Isoprene C. Stangl et al. 10.1029/2018JD030064
- Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates R. Cox et al. 10.5194/acp-20-13497-2020
- Isolating α-Pinene Ozonolysis Pathways Reveals New Insights into Peroxy Radical Chemistry and Secondary Organic Aerosol Formation Z. Zhao et al. 10.1021/acs.est.1c02107
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. 10.1080/02786826.2019.1568381
- Theoretical study on the formation of Criegee intermediates from ozonolysis of pentenal: An example of trans-2-pentenal W. Xiao et al. 10.1016/j.chemosphere.2022.135142
- Application of chemical derivatization techniques combined with chemical ionization mass spectrometry to detect stabilized Criegee intermediates and peroxy radicals in the gas phase A. Zaytsev et al. 10.5194/amt-14-2501-2021
- Carbonyl Oxide Stabilization from Trans Alkene and Terpene Ozonolysis J. Hakala & N. Donahue 10.1021/acs.jpca.3c03650
- Theoretical Study on Criegee Intermediate’s Role in Ozonolysis of Acrylic Acid X. Lin et al. 10.1021/acs.jpca.8b11671
- Impact of Criegee Intermediate Reactions with Peroxy Radicals on Tropospheric Organic Aerosol R. Chhantyal-Pun et al. 10.1021/acsearthspacechem.0c00147
- Increased primary and secondary H<sub>2</sub>SO<sub>4</sub> showing the opposing roles in secondary organic aerosol formation from ethyl methacrylate ozonolysis P. Zhang et al. 10.5194/acp-21-7099-2021
- Modeling the Unimolecular Decay Dynamics of the Fluorinated Criegee Intermediate, CF3CHOO L. Guidry et al. 10.3390/photochem3030020
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen 10.5194/acp-21-813-2021
- Trends in stabilisation of Criegee intermediates from alkene ozonolysis M. Newland et al. 10.1039/D0CP00897D
- Theoretical study on the degradation mechanism, kinetics and toxicity for aqueous ozonation reaction of furan derivatives W. Xiao et al. 10.1016/j.chemosphere.2023.138782
- Acylperoxy Radicals as Key Intermediates in the Formation of Dimeric Compounds in α-Pinene Secondary Organic Aerosol Y. Zhao et al. 10.1021/acs.est.2c02090
- Peroxy Radical and Product Formation in the Gas-Phase Ozonolysis of α-Pinene under Near-Atmospheric Conditions: Occurrence of an Additional Series of Peroxy Radicals O,O–C10H15O(O2)yO2 with y = 1–3 T. Berndt 10.1021/acs.jpca.2c05094
- Estimation of mechanistic parameters in the gas-phase reactions of ozone with alkenes for use in automated mechanism construction M. Newland et al. 10.5194/acp-22-6167-2022
- Quantitative constraints on autoxidation and dimer formation from direct probing of monoterpene-derived peroxy radical chemistry Y. Zhao et al. 10.1073/pnas.1812147115
- Criegee intermediates: production, detection and reactivity R. Chhantyal-Pun et al. 10.1080/0144235X.2020.1792104
- Anthropogenic Effects on Biogenic Secondary Organic Aerosol Formation L. Xu et al. 10.1007/s00376-020-0284-3
- New particle formation from the reactions of ozone with indene and styrene L. Bracco et al. 10.1039/C9CP00912D
- Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications S. Liu et al. 10.1016/j.atmosenv.2023.120012
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al. 10.1039/C9CP06306D
3 citations as recorded by crossref.
- Impacts of the Degradation of 2,3,3,3-Tetrafluoropropene into Trifluoroacetic Acid from Its Application in Automobile Air Conditioners in China, the United States, and Europe Z. Wang et al. 10.1021/acs.est.7b05960
- Ozonolysis of <i>α</i>-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. 10.5194/acp-18-4673-2018
- Criegee intermediates and their impacts on the troposphere M. Khan et al. 10.1039/C7EM00585G
Latest update: 03 Dec 2023
Short summary
Stabilised Criegee intermediates (SCIs) are formed in the reaction of alkenes with ozone, both of which are ubiquitous throughout the troposphere. We determine the fate and global distribution of SCI from monoterpene ozonolysis. One major fate of SCI is reaction with H2O, but for a fraction of SCIs, unimolecular reactions dominate. Concentrations of SCIs are high enough regionally to play a key role in the conversion of sulfur dioxide to aerosol, affecting air quality and climate.
Stabilised Criegee intermediates (SCIs) are formed in the reaction of alkenes with ozone, both...
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