Articles | Volume 18, issue 5
https://doi.org/10.5194/acp-18-3589-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-3589-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Mar 2018
Research article |
| 12 Mar 2018
| 12 Mar 2018
Multi-generation chemical aging of α-pinene ozonolysis products by reactions with OH
Ningxin Wang
Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, USA
Evangelia Kostenidou
Department of Chemical Engineering, University of Patras, Patra, Greece
Institute of Chemical Engineering Sciences (ICE-HT), FORTH, Patra, Greece
Neil M. Donahue
Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, USA
Spyros N. Pandis
CORRESPONDING AUTHOR
Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, USA
Department of Chemical Engineering, University of Patras, Patra, Greece
Institute of Chemical Engineering Sciences (ICE-HT), FORTH, Patra, Greece
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Cited
20 citations as recorded by crossref.
- Effect of chemical aging of monoterpene products on biogenic secondary organic aerosol concentrations B. Dinkelacker & S. Pandis https://doi.org/10.1016/j.atmosenv.2021.118381
- Evolution under dark conditions of particles from old and modern diesel vehicles in a new environmental chamber characterized with fresh exhaust emissions B. Vansevenant et al. https://doi.org/10.5194/amt-14-7627-2021
- Morphology of Organic Carbon Coatings on Biomass-Burning Particles and Their Role in Reactive Gas Uptake L. Jahn et al. https://doi.org/10.1021/acsearthspacechem.1c00237
- Secondary organic aerosol yields from the oxidation of benzyl alcohol S. Charan et al. https://doi.org/10.5194/acp-20-13167-2020
- Properties and Atmospheric Oxidation of Norpinic Acid Aerosol E. Kostenidou et al. https://doi.org/10.3390/atmos13091481
- Larger than expected organic acid yields from the multi-generation oxidation of petrochemical alkenes B. Zhao et al. https://doi.org/10.5194/acp-25-16041-2025
- The current understanding of atmospheric new particle growth D. Shang et al. https://doi.org/10.1007/s11783-026-2178-9
- Chemical evolution of primary and secondary biomass burning aerosols during daytime and nighttime A. Yazdani et al. https://doi.org/10.5194/acp-23-7461-2023
- Properties and Atmospheric Oxidation of Terebic Acid Aerosol K. Florou et al. https://doi.org/10.1021/acsearthspacechem.4c00201
- Particle wall-loss correction methods in smog chamber experiments N. Wang et al. https://doi.org/10.5194/amt-11-6577-2018
- Reaction Rate Coefficient of OH Radicals with d9-Butanol as a Function of Temperature A. Allani et al. https://doi.org/10.1021/acsomega.1c01942
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. https://doi.org/10.1021/acsearthspacechem.0c00106
- Formation and chemical evolution of secondary organic aerosol in two different environments: a dual-chamber study A. Aktypis et al. https://doi.org/10.5194/acp-24-13769-2024
- Multi-generation oxidation mechanism of M-xylene: Unexpected implications for secondary organic aerosol formation R. Lu et al. https://doi.org/10.1016/j.atmosenv.2024.120511
- Response of biogenic secondary organic aerosol formation to anthropogenic NOx emission mitigation Z. Wang et al. https://doi.org/10.1016/j.scitotenv.2024.172142
- Study of the surface, rheological and morphological characteristics of isotactic polypropylene microplastics aged in a photothermal oxidation chamber G. Martins et al. https://doi.org/10.1016/j.polymdegradstab.2024.110728
- Fragment ion–functional group relationships in organic aerosols using aerosol mass spectrometry and mid-infrared spectroscopy A. Yazdani et al. https://doi.org/10.5194/amt-15-2857-2022
- Formation of secondary organic aerosol during the dark-ozonolysis of α-humulene D. Sippial et al. https://doi.org/10.1039/D2EA00181K
- Size-dependent depositional loss of inorganic, organic, and mixed composition particles to Teflon chamber walls under various environmental and chemical conditions A. Nakagawa et al. https://doi.org/10.1080/02786826.2023.2298219
- Modeling Intra‐ and Interannual Variability of BVOC Emissions From Maize, Oil‐Seed Rape, and Ryegrass F. Havermann et al. https://doi.org/10.1029/2021MS002683
20 citations as recorded by crossref.
- Effect of chemical aging of monoterpene products on biogenic secondary organic aerosol concentrations B. Dinkelacker & S. Pandis https://doi.org/10.1016/j.atmosenv.2021.118381
- Evolution under dark conditions of particles from old and modern diesel vehicles in a new environmental chamber characterized with fresh exhaust emissions B. Vansevenant et al. https://doi.org/10.5194/amt-14-7627-2021
- Morphology of Organic Carbon Coatings on Biomass-Burning Particles and Their Role in Reactive Gas Uptake L. Jahn et al. https://doi.org/10.1021/acsearthspacechem.1c00237
- Secondary organic aerosol yields from the oxidation of benzyl alcohol S. Charan et al. https://doi.org/10.5194/acp-20-13167-2020
- Properties and Atmospheric Oxidation of Norpinic Acid Aerosol E. Kostenidou et al. https://doi.org/10.3390/atmos13091481
- Larger than expected organic acid yields from the multi-generation oxidation of petrochemical alkenes B. Zhao et al. https://doi.org/10.5194/acp-25-16041-2025
- The current understanding of atmospheric new particle growth D. Shang et al. https://doi.org/10.1007/s11783-026-2178-9
- Chemical evolution of primary and secondary biomass burning aerosols during daytime and nighttime A. Yazdani et al. https://doi.org/10.5194/acp-23-7461-2023
- Properties and Atmospheric Oxidation of Terebic Acid Aerosol K. Florou et al. https://doi.org/10.1021/acsearthspacechem.4c00201
- Particle wall-loss correction methods in smog chamber experiments N. Wang et al. https://doi.org/10.5194/amt-11-6577-2018
- Reaction Rate Coefficient of OH Radicals with d9-Butanol as a Function of Temperature A. Allani et al. https://doi.org/10.1021/acsomega.1c01942
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. https://doi.org/10.1021/acsearthspacechem.0c00106
- Formation and chemical evolution of secondary organic aerosol in two different environments: a dual-chamber study A. Aktypis et al. https://doi.org/10.5194/acp-24-13769-2024
- Multi-generation oxidation mechanism of M-xylene: Unexpected implications for secondary organic aerosol formation R. Lu et al. https://doi.org/10.1016/j.atmosenv.2024.120511
- Response of biogenic secondary organic aerosol formation to anthropogenic NOx emission mitigation Z. Wang et al. https://doi.org/10.1016/j.scitotenv.2024.172142
- Study of the surface, rheological and morphological characteristics of isotactic polypropylene microplastics aged in a photothermal oxidation chamber G. Martins et al. https://doi.org/10.1016/j.polymdegradstab.2024.110728
- Fragment ion–functional group relationships in organic aerosols using aerosol mass spectrometry and mid-infrared spectroscopy A. Yazdani et al. https://doi.org/10.5194/amt-15-2857-2022
- Formation of secondary organic aerosol during the dark-ozonolysis of α-humulene D. Sippial et al. https://doi.org/10.1039/D2EA00181K
- Size-dependent depositional loss of inorganic, organic, and mixed composition particles to Teflon chamber walls under various environmental and chemical conditions A. Nakagawa et al. https://doi.org/10.1080/02786826.2023.2298219
- Modeling Intra‐ and Interannual Variability of BVOC Emissions From Maize, Oil‐Seed Rape, and Ryegrass F. Havermann et al. https://doi.org/10.1029/2021MS002683
Saved (final revised paper)
Latest update: 02 Sep 2026
Short summary
This study investigates aging in the α-pinene ozonolysis system with hydroxyl radicals (OH) through smog chamber experiments. After an equivalent of 2–4 days of typical atmospheric oxidation conditions, homogeneous OH oxidation of the α-pinene ozonolysis products resulted in a 20–40 % net increase in the organic aerosol concentration and an increase in aerosol O : C by up to 0.04. The relative humidity in the 5–50 % range had a minimum effect on aging.
This study investigates aging in the α-pinene ozonolysis system with hydroxyl radicals (OH)...
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