Articles | Volume 18, issue 1
https://doi.org/10.5194/acp-18-357-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-357-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Jan 2018
Research article |
| 12 Jan 2018
Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Andreas Zuend
Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Québec, Canada
Juliane L. Fry
Department of Chemistry, Reed College, Portland, Oregon, USA
Gabriel Isaacman-VanWertz
Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA
Department of Environmental Science, Policy, and Management, University of California, Berkeley, California, USA
Shannon L. Capps
Civil, Architectural, and Environmental Engineering, Drexel University, Philadelphia, Pennsylvania, USA
K. Wyat Appel
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Hosein Foroutan
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Department of Biomedical Engineering and Mechanics, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA
Department of Environmental Science and Engineering, California Institute of Technology, Pasadena, California, USA
Nga L. Ng
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA
Allen H. Goldstein
Department of Environmental Science, Policy, and Management, University of California, Berkeley, California, USA
Department of Civil and Environmental Engineering, University of California, Berkeley, California, USA
Viewed
Total article views: 4,924 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 18 Jul 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,500 | 1,364 | 60 | 4,924 | 419 | 43 | 109 |
- HTML: 3,500
- PDF: 1,364
- XML: 60
- Total: 4,924
- Supplement: 419
- BibTeX: 43
- EndNote: 109
Total article views: 4,101 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Jan 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,955 | 1,093 | 53 | 4,101 | 282 | 38 | 95 |
- HTML: 2,955
- PDF: 1,093
- XML: 53
- Total: 4,101
- Supplement: 282
- BibTeX: 38
- EndNote: 95
Total article views: 823 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 18 Jul 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 545 | 271 | 7 | 823 | 137 | 5 | 14 |
- HTML: 545
- PDF: 271
- XML: 7
- Total: 823
- Supplement: 137
- BibTeX: 5
- EndNote: 14
Viewed (geographical distribution)
Total article views: 4,924 (including HTML, PDF, and XML)
Thereof 4,891 with geography defined
and 33 with unknown origin.
Total article views: 4,101 (including HTML, PDF, and XML)
Thereof 4,069 with geography defined
and 32 with unknown origin.
Total article views: 823 (including HTML, PDF, and XML)
Thereof 822 with geography defined
and 1 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
46 citations as recorded by crossref.
- Toward the improvement of total nitrogen deposition budgets in the United States J. Walker et al. 10.1016/j.scitotenv.2019.07.058
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- First Continuous Measurement of Gaseous and Particulate Formic Acid in a Suburban Area of East China: Seasonality and Gas–Particle Partitioning J. Xu et al. 10.1021/acsearthspacechem.9b00210
- Evaluation of the offline-coupled GFSv15–FV3–CMAQv5.0.2 in support of the next-generation National Air Quality Forecast Capability over the contiguous United States X. Chen et al. 10.5194/gmd-14-3969-2021
- Water uptake and optical properties of mixed organic-inorganic particles L. Nandy et al. 10.1080/02786826.2021.1966378
- Modeling organic aerosol over Europe in summer conditions with the VBS-GECKO parameterization: sensitivity to secondary organic compound properties and IVOC (intermediate-volatility organic compound) emissions V. Lannuque et al. 10.5194/acp-20-4905-2020
- Why is the Indo-Gangetic Plain the region with the largest NH<sub>3</sub> column in the globe during pre-monsoon and monsoon seasons? T. Wang et al. 10.5194/acp-20-8727-2020
- Extension of the AIOMFAC model by iodine and carbonate species: applications for aerosol acidity and cloud droplet activation H. Yin et al. 10.5194/acp-22-973-2022
- Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
- How alkaline compounds control atmospheric aerosol particle acidity V. Karydis et al. 10.5194/acp-21-14983-2021
- The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios H. Guo et al. 10.5194/acp-18-17307-2018
- Effects of water-soluble organic carbon on aerosol pH M. Battaglia Jr. et al. 10.5194/acp-19-14607-2019
- Pollution Transport Patterns Obtained Through Generalized Lagrangian Coherent Structures P. Nolan et al. 10.3390/atmos11020168
- A quantitative analysis of the driving factors affecting seasonal variation of aerosol pH in Guangzhou, China S. Jia et al. 10.1016/j.scitotenv.2020.138228
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
- Wet Inorganic Nitrogen Deposition at the Daheitin Reservoir in North China: Temporal Variation, Sources, and Biomass Burning Influences L. Wu et al. 10.3390/atmos11111260
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Enhancement of aqueous sulfate formation by the coexistence of NO2/NH3 under high ionic strengths in aerosol water T. Chen et al. 10.1016/j.envpol.2019.05.119
- α-Pinene-Derived organic coatings on acidic sulfate aerosol impacts secondary organic aerosol formation from isoprene in a box model R. Schmedding et al. 10.1016/j.atmosenv.2019.06.005
- PM2.5 pH estimation in Seoul during the KORUS-AQ campaign using different thermodynamic models Y. Kim et al. 10.1016/j.atmosenv.2021.118787
- Technical note: Comparison and interconversion of pH based on different standard states for aerosol acidity characterization S. Jia et al. 10.5194/acp-18-11125-2018
- Role of pH in Aerosol Processes and Measurement Challenges M. Freedman et al. 10.1021/acs.jpca.8b10676
- New Bidirectional Ammonia Flux Model in an Air Quality Model Coupled With an Agricultural Model J. Pleim et al. 10.1029/2019MS001728
- Determining Activity Coefficients of SOA from Isothermal Evaporation in a Laboratory Chamber X. Liu et al. 10.1021/acs.estlett.0c00888
- Understanding nitrate formation in a world with less sulfate P. Vasilakos et al. 10.5194/acp-18-12765-2018
- Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol A. Carlton et al. 10.1021/acs.est.8b01869
- High-Resolution Data Sets Unravel the Effects of Sources and Meteorological Conditions on Nitrate and Its Gas-Particle Partitioning X. Shi et al. 10.1021/acs.est.8b06524
- Gas–particle partitioning of polyol tracers at a suburban site in Nanjing, east China: increased partitioning to the particle phase C. Qin et al. 10.5194/acp-21-12141-2021
- Current and Future Responses of Aerosol pH and Composition in the U.S. to Declining SO2 Emissions and Increasing NH3 Emissions Y. Chen et al. 10.1021/acs.est.9b02005
- Parameterization of heterogeneous reaction of SO2 to sulfate on dust with coexistence of NH3 and NO2 under different humidity conditions S. Zhang et al. 10.1016/j.atmosenv.2019.04.004
- A predictive viscosity model for aqueous electrolytes and mixed organic–inorganic aerosol phases J. Lilek & A. Zuend 10.5194/acp-22-3203-2022
- Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model Y. Kim et al. 10.5194/acp-19-1241-2019
- Linked Response of Aerosol Acidity and Ammonia to SO2 and NOx Emissions Reductions in the United States A. Lawal et al. 10.1021/acs.est.8b00711
- Impact of non-ideality on reconstructing spatial and temporal variations in aerosol acidity with multiphase buffer theory G. Zheng et al. 10.5194/acp-22-47-2022
- Assessing PM2.5 model performance for the conterminous U.S. with comparison to model performance statistics from 2007-2015 J. Kelly et al. 10.1016/j.atmosenv.2019.116872
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- Effectiveness of ammonia reduction on control of fine particle nitrate H. Guo et al. 10.5194/acp-18-12241-2018
- Fine-particle pH for Beijing winter haze as inferred from different thermodynamic equilibrium models S. Song et al. 10.5194/acp-18-7423-2018
- Nitrogen Oxides Emissions, Chemistry, Deposition, and Export Over the Northeast United States During the WINTER Aircraft Campaign L. Jaeglé et al. 10.1029/2018JD029133
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Urban aerosol chemistry at a land–water transition site during summer – Part 2: Aerosol pH and liquid water content M. Battaglia Jr. et al. 10.5194/acp-21-18271-2021
- Characteristics and Formation Mechanisms of Winter Particulate Pollution in Lanzhou, Northwest China T. Du et al. 10.1029/2020JD033369
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Detailed Analysis of Estimated pH, Activity Coefficients, and Ion Concentrations between the Three Aerosol Thermodynamic Models X. Peng et al. 10.1021/acs.est.9b00181
45 citations as recorded by crossref.
- Toward the improvement of total nitrogen deposition budgets in the United States J. Walker et al. 10.1016/j.scitotenv.2019.07.058
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- First Continuous Measurement of Gaseous and Particulate Formic Acid in a Suburban Area of East China: Seasonality and Gas–Particle Partitioning J. Xu et al. 10.1021/acsearthspacechem.9b00210
- Evaluation of the offline-coupled GFSv15–FV3–CMAQv5.0.2 in support of the next-generation National Air Quality Forecast Capability over the contiguous United States X. Chen et al. 10.5194/gmd-14-3969-2021
- Water uptake and optical properties of mixed organic-inorganic particles L. Nandy et al. 10.1080/02786826.2021.1966378
- Modeling organic aerosol over Europe in summer conditions with the VBS-GECKO parameterization: sensitivity to secondary organic compound properties and IVOC (intermediate-volatility organic compound) emissions V. Lannuque et al. 10.5194/acp-20-4905-2020
- Why is the Indo-Gangetic Plain the region with the largest NH<sub>3</sub> column in the globe during pre-monsoon and monsoon seasons? T. Wang et al. 10.5194/acp-20-8727-2020
- Extension of the AIOMFAC model by iodine and carbonate species: applications for aerosol acidity and cloud droplet activation H. Yin et al. 10.5194/acp-22-973-2022
- Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
- How alkaline compounds control atmospheric aerosol particle acidity V. Karydis et al. 10.5194/acp-21-14983-2021
- The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios H. Guo et al. 10.5194/acp-18-17307-2018
- Effects of water-soluble organic carbon on aerosol pH M. Battaglia Jr. et al. 10.5194/acp-19-14607-2019
- Pollution Transport Patterns Obtained Through Generalized Lagrangian Coherent Structures P. Nolan et al. 10.3390/atmos11020168
- A quantitative analysis of the driving factors affecting seasonal variation of aerosol pH in Guangzhou, China S. Jia et al. 10.1016/j.scitotenv.2020.138228
- The acidity of atmospheric particles and clouds H. Pye et al. 10.5194/acp-20-4809-2020
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
- Wet Inorganic Nitrogen Deposition at the Daheitin Reservoir in North China: Temporal Variation, Sources, and Biomass Burning Influences L. Wu et al. 10.3390/atmos11111260
- Seasonal Contribution of Isoprene-Derived Organosulfates to Total Water-Soluble Fine Particulate Organic Sulfur in the United States Y. Chen et al. 10.1021/acsearthspacechem.1c00102
- Enhancement of aqueous sulfate formation by the coexistence of NO2/NH3 under high ionic strengths in aerosol water T. Chen et al. 10.1016/j.envpol.2019.05.119
- α-Pinene-Derived organic coatings on acidic sulfate aerosol impacts secondary organic aerosol formation from isoprene in a box model R. Schmedding et al. 10.1016/j.atmosenv.2019.06.005
- PM2.5 pH estimation in Seoul during the KORUS-AQ campaign using different thermodynamic models Y. Kim et al. 10.1016/j.atmosenv.2021.118787
- Technical note: Comparison and interconversion of pH based on different standard states for aerosol acidity characterization S. Jia et al. 10.5194/acp-18-11125-2018
- Role of pH in Aerosol Processes and Measurement Challenges M. Freedman et al. 10.1021/acs.jpca.8b10676
- New Bidirectional Ammonia Flux Model in an Air Quality Model Coupled With an Agricultural Model J. Pleim et al. 10.1029/2019MS001728
- Determining Activity Coefficients of SOA from Isothermal Evaporation in a Laboratory Chamber X. Liu et al. 10.1021/acs.estlett.0c00888
- Understanding nitrate formation in a world with less sulfate P. Vasilakos et al. 10.5194/acp-18-12765-2018
- Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol A. Carlton et al. 10.1021/acs.est.8b01869
- High-Resolution Data Sets Unravel the Effects of Sources and Meteorological Conditions on Nitrate and Its Gas-Particle Partitioning X. Shi et al. 10.1021/acs.est.8b06524
- Gas–particle partitioning of polyol tracers at a suburban site in Nanjing, east China: increased partitioning to the particle phase C. Qin et al. 10.5194/acp-21-12141-2021
- Current and Future Responses of Aerosol pH and Composition in the U.S. to Declining SO2 Emissions and Increasing NH3 Emissions Y. Chen et al. 10.1021/acs.est.9b02005
- Parameterization of heterogeneous reaction of SO2 to sulfate on dust with coexistence of NH3 and NO2 under different humidity conditions S. Zhang et al. 10.1016/j.atmosenv.2019.04.004
- A predictive viscosity model for aqueous electrolytes and mixed organic–inorganic aerosol phases J. Lilek & A. Zuend 10.5194/acp-22-3203-2022
- Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model Y. Kim et al. 10.5194/acp-19-1241-2019
- Linked Response of Aerosol Acidity and Ammonia to SO2 and NOx Emissions Reductions in the United States A. Lawal et al. 10.1021/acs.est.8b00711
- Impact of non-ideality on reconstructing spatial and temporal variations in aerosol acidity with multiphase buffer theory G. Zheng et al. 10.5194/acp-22-47-2022
- Assessing PM2.5 model performance for the conterminous U.S. with comparison to model performance statistics from 2007-2015 J. Kelly et al. 10.1016/j.atmosenv.2019.116872
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- Effectiveness of ammonia reduction on control of fine particle nitrate H. Guo et al. 10.5194/acp-18-12241-2018
- Fine-particle pH for Beijing winter haze as inferred from different thermodynamic equilibrium models S. Song et al. 10.5194/acp-18-7423-2018
- Nitrogen Oxides Emissions, Chemistry, Deposition, and Export Over the Northeast United States During the WINTER Aircraft Campaign L. Jaeglé et al. 10.1029/2018JD029133
- Current State of Atmospheric Aerosol Thermodynamics and Mass Transfer Modeling: A Review K. Semeniuk & A. Dastoor 10.3390/atmos11020156
- Urban aerosol chemistry at a land–water transition site during summer – Part 2: Aerosol pH and liquid water content M. Battaglia Jr. et al. 10.5194/acp-21-18271-2021
- Characteristics and Formation Mechanisms of Winter Particulate Pollution in Lanzhou, Northwest China T. Du et al. 10.1029/2020JD033369
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
Latest update: 24 Mar 2023
Short summary
Thermodynamic modeling revealed that some but not all measurements of ammonium-to-sulfate ratios are consistent with theory. The measurement diversity likely explains the previously reported range of results regarding the suitability of thermodynamic modeling. Despite particles being predominantly phase separated, organic–inorganic interactions resulted in increased aerosol pH and partitioning towards the particle phase for highly oxygenated organic compounds compared to traditional methods.
Thermodynamic modeling revealed that some but not all measurements of ammonium-to-sulfate ratios...
Altmetrics
Final-revised paper
Preprint