Articles | Volume 18, issue 1
Atmos. Chem. Phys., 18, 357–370, 2018
https://doi.org/10.5194/acp-18-357-2018
Atmos. Chem. Phys., 18, 357–370, 2018
https://doi.org/10.5194/acp-18-357-2018
Research article
12 Jan 2018
Research article | 12 Jan 2018

Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US

Havala O. T. Pye et al.

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Latest update: 25 May 2022
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Short summary
Thermodynamic modeling revealed that some but not all measurements of ammonium-to-sulfate ratios are consistent with theory. The measurement diversity likely explains the previously reported range of results regarding the suitability of thermodynamic modeling. Despite particles being predominantly phase separated, organic–inorganic interactions resulted in increased aerosol pH and partitioning towards the particle phase for highly oxygenated organic compounds compared to traditional methods.
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