Articles | Volume 18, issue 1
https://doi.org/10.5194/acp-18-357-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-357-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Coupling of organic and inorganic aerosol systems and the effect on gas–particle partitioning in the southeastern US
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Andreas Zuend
Department of Atmospheric and Oceanic Sciences, McGill University, Montreal, Québec, Canada
Juliane L. Fry
Department of Chemistry, Reed College, Portland, Oregon, USA
Gabriel Isaacman-VanWertz
Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA
Department of Environmental Science, Policy, and Management, University of California, Berkeley, California, USA
Shannon L. Capps
Civil, Architectural, and Environmental Engineering, Drexel University, Philadelphia, Pennsylvania, USA
K. Wyat Appel
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Hosein Foroutan
National Exposure Research Laboratory, US Environmental Protection Agency, Research Triangle Park, North Carolina, USA
Department of Biomedical Engineering and Mechanics, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, USA
Department of Environmental Science and Engineering, California Institute of Technology, Pasadena, California, USA
Nga L. Ng
School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia, USA
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, Georgia, USA
Allen H. Goldstein
Department of Environmental Science, Policy, and Management, University of California, Berkeley, California, USA
Department of Civil and Environmental Engineering, University of California, Berkeley, California, USA
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Latest update: 24 Mar 2023
Short summary
Thermodynamic modeling revealed that some but not all measurements of ammonium-to-sulfate ratios are consistent with theory. The measurement diversity likely explains the previously reported range of results regarding the suitability of thermodynamic modeling. Despite particles being predominantly phase separated, organic–inorganic interactions resulted in increased aerosol pH and partitioning towards the particle phase for highly oxygenated organic compounds compared to traditional methods.
Thermodynamic modeling revealed that some but not all measurements of ammonium-to-sulfate ratios...
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