Articles | Volume 18, issue 3
https://doi.org/10.5194/acp-18-1909-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-18-1909-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Formation of highly oxygenated organic molecules from aromatic compounds
Ugo Molteni
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Federico Bianchi
Institute for Atmospheric and Earth System Research, University of Helsinki, 00014 Helsinki, Finland
Felix Klein
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Imad El Haddad
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Carla Frege
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Michel J. Rossi
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Josef Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
Urs Baltensperger
CORRESPONDING AUTHOR
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232
Villigen, Switzerland
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Latest update: 20 Nov 2024
Short summary
Anthropogenic volatile organic compounds often dominate the urban atmosphere and consist to a large degree of aromatics. These compounds are already known as important precursors for the formation of secondary organic aerosol. This study shows how the oxidation of aromatics with an OH radical leads to subsequent autoxidation chain reactions forming highly oxygenated molecules. We hypothesize that these may contribute substantially to new particle formation events detected in urban areas.
Anthropogenic volatile organic compounds often dominate the urban atmosphere and consist to a...
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