Articles | Volume 18, issue 3
https://doi.org/10.5194/acp-18-1895-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-18-1895-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
09 Feb 2018
Research article |
| 09 Feb 2018
Nanoparticle growth by particle-phase chemistry
Michael J. Apsokardu
Department of Chemistry and Biochemistry, University of Delaware, Newark,
DE, 19716, USA
Department of Chemistry and Biochemistry, University of Delaware, Newark,
DE, 19716, USA
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30 citations as recorded by crossref.
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- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. https://doi.org/10.1126/sciadv.aax8922
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. https://doi.org/10.1039/D1EM00409C
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. https://doi.org/10.1021/acs.analchem.0c03697
- Global Modeling of Secondary Organic Aerosol With Organic Nucleation J. Zhu & J. Penner https://doi.org/10.1029/2019JD030414
- The role of aldehydes on sulfur based-new particle formation: a theoretical study G. Zhang et al. https://doi.org/10.1039/D4RA00952E
- The current understanding of atmospheric new particle growth D. Shang et al. https://doi.org/10.1007/s11783-026-2178-9
- Modelling ultrafine particle growth in a flow tube reactor M. Taylor Jr. et al. https://doi.org/10.5194/amt-15-4663-2022
- Rapid growth of organic aerosol nanoparticles over a wide tropospheric temperature range D. Stolzenburg et al. https://doi.org/10.1073/pnas.1807604115
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman https://doi.org/10.1146/annurev-anchem-061516-045135
- Atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1103/RevModPhys.95.045002
- Unraveling the cross-reaction kinetics of keto-hydroperoxide and NH2 radicals: Theoretical insights into low-temperature oxidation mechanism S. Wang et al. https://doi.org/10.1016/j.fuel.2026.139688
- Spatiotemporal distribution and source analysis of PM2.5 and its chemical components in national industrial complexes of Korea: a case study of Ansan and Siheung S. Park et al. https://doi.org/10.1007/s11356-024-35537-3
- High Pressure Inside Nanometer-Sized Particles Influences the Rate and Products of Chemical Reactions M. Riva et al. https://doi.org/10.1021/acs.est.0c07386
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. https://doi.org/10.1080/02786826.2019.1568381
- Comprehensive analysis of particle growth rates from nucleation mode to cloud condensation nuclei in boreal forest P. Paasonen et al. https://doi.org/10.5194/acp-18-12085-2018
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- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. https://doi.org/10.1021/acs.jpca.1c08427
- Evaluation of factors influencing secondary organic carbon (SOC) estimation by CO and EC tracer methods Q. Zhang et al. https://doi.org/10.1016/j.scitotenv.2019.05.402
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- Boreal afforestation’s underestimated cloud influence on Earth’s energy imbalance E. Ofosu et al. https://doi.org/10.1038/s41612-026-01365-0
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- Ultrafine Particle Growth Rate During Biogenic Secondary Organic Matter Formation as a Function of Particle Composition, Size, and Phase M. Taylor et al. https://doi.org/10.1021/acsestair.4c00339
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. https://doi.org/10.1016/j.chemosphere.2020.127842
- Increased new particle yields with largely decreased probability of survival to CCN size at the summit of Mt. Tai under reduced SO2 emissions Y. Zhu et al. https://doi.org/10.5194/acp-21-1305-2021
- Quantifying the Impact of Outdoor Airborne Nano-Contamination on eSiGe Defect Generation and Machine Learning-Based Predictive Modeling J. Lee et al. https://doi.org/10.1109/TSM.2025.3554783
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al. https://doi.org/10.1021/acs.est.4c07748
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30 citations as recorded by crossref.
- Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. https://doi.org/10.1126/sciadv.abj0329
- On the fate of oxygenated organic molecules in atmospheric aerosol particles V. Pospisilova et al. https://doi.org/10.1126/sciadv.aax8922
- Secondary organic aerosol formation from monocyclic aromatic hydrocarbons: insights from laboratory studies Z. Yang et al. https://doi.org/10.1039/D1EM00409C
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al. https://doi.org/10.1021/acs.analchem.0c03697
- Global Modeling of Secondary Organic Aerosol With Organic Nucleation J. Zhu & J. Penner https://doi.org/10.1029/2019JD030414
- The role of aldehydes on sulfur based-new particle formation: a theoretical study G. Zhang et al. https://doi.org/10.1039/D4RA00952E
- The current understanding of atmospheric new particle growth D. Shang et al. https://doi.org/10.1007/s11783-026-2178-9
- Modelling ultrafine particle growth in a flow tube reactor M. Taylor Jr. et al. https://doi.org/10.5194/amt-15-4663-2022
- Rapid growth of organic aerosol nanoparticles over a wide tropospheric temperature range D. Stolzenburg et al. https://doi.org/10.1073/pnas.1807604115
- Molecular Characterization of Atmospheric Organic Aerosol by Mass Spectrometry M. Johnston & D. Kerecman https://doi.org/10.1146/annurev-anchem-061516-045135
- Atmospheric nanoparticle growth D. Stolzenburg et al. https://doi.org/10.1103/RevModPhys.95.045002
- Unraveling the cross-reaction kinetics of keto-hydroperoxide and NH2 radicals: Theoretical insights into low-temperature oxidation mechanism S. Wang et al. https://doi.org/10.1016/j.fuel.2026.139688
- Spatiotemporal distribution and source analysis of PM2.5 and its chemical components in national industrial complexes of Korea: a case study of Ansan and Siheung S. Park et al. https://doi.org/10.1007/s11356-024-35537-3
- High Pressure Inside Nanometer-Sized Particles Influences the Rate and Products of Chemical Reactions M. Riva et al. https://doi.org/10.1021/acs.est.0c07386
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. https://doi.org/10.1080/02786826.2019.1568381
- Comprehensive analysis of particle growth rates from nucleation mode to cloud condensation nuclei in boreal forest P. Paasonen et al. https://doi.org/10.5194/acp-18-12085-2018
- Growth Rate Dependence of Secondary Organic Aerosol on Seed Particle Size, Composition, and Phase D. Higgins et al. https://doi.org/10.1021/acsearthspacechem.2c00049
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. https://doi.org/10.1021/acs.jpca.1c08427
- Evaluation of factors influencing secondary organic carbon (SOC) estimation by CO and EC tracer methods Q. Zhang et al. https://doi.org/10.1016/j.scitotenv.2019.05.402
- SO2 enhances aerosol formation from anthropogenic volatile organic compound ozonolysis by producing sulfur-containing compounds Z. Yang et al. https://doi.org/10.5194/acp-23-417-2023
- Boreal afforestation’s underestimated cloud influence on Earth’s energy imbalance E. Ofosu et al. https://doi.org/10.1038/s41612-026-01365-0
- The High Pressure Inside Aerosol Particles Enhances Photochemical Reactions of Biomass Burning Compounds C. Dubois et al. https://doi.org/10.1021/acsearthspacechem.4c00011
- Iodine-mediated nucleation and particle growth: laboratory measurements of IO production and its implications Y. Yan et al. https://doi.org/10.1039/D6RA01191H
- Ultrafine Particle Growth Rate During Biogenic Secondary Organic Matter Formation as a Function of Particle Composition, Size, and Phase M. Taylor et al. https://doi.org/10.1021/acsestair.4c00339
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. https://doi.org/10.1016/j.chemosphere.2020.127842
- Increased new particle yields with largely decreased probability of survival to CCN size at the summit of Mt. Tai under reduced SO2 emissions Y. Zhu et al. https://doi.org/10.5194/acp-21-1305-2021
- Quantifying the Impact of Outdoor Airborne Nano-Contamination on eSiGe Defect Generation and Machine Learning-Based Predictive Modeling J. Lee et al. https://doi.org/10.1109/TSM.2025.3554783
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al. https://doi.org/10.1021/acs.est.4c07748
- Survival probabilities of atmospheric particles: comparison based on theory, cluster population simulations, and observations in Beijing S. Tuovinen et al. https://doi.org/10.5194/acp-22-15071-2022
- SO2 and NH3 emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al. https://doi.org/10.5194/acp-21-7963-2021
Saved (final revised paper)
Latest update: 04 Sep 2026
Short summary
The ability of particle-phase chemistry to alter the molecular composition and enhance the growth rate of nanoparticles is investigated through the use of a kinetic growth model. The effects of particle-phase chemistry are found to be most pronounced for particles larger than about 20 nm in diameter. The results are discussed in the context of recent experimental measurements of particle-size-dependent molecular composition.
The ability of particle-phase chemistry to alter the molecular composition and enhance the...
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