Articles | Volume 18, issue 23
https://doi.org/10.5194/acp-18-17451-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-17451-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
H2SO4–H2O–NH3 ternary ion-mediated nucleation (TIMN): kinetic-based model and comparison with CLOUD measurements
Atmospheric Sciences Research Center, University at Albany, Albany,
New York, USA
Alexey B. Nadykto
Atmospheric Sciences Research Center, University at Albany, Albany,
New York, USA
Department of Applied Mathematics, Moscow State
Univ. of Technology “STANKIN”, Moscow, Russian Federation
National Research Nuclear University MEPhI (Moscow Engineering
Physics Institute), Department of General Physics, Moscow, Russian
Federation
Jason Herb
Atmospheric Sciences Research Center, University at Albany, Albany,
New York, USA
Atmospheric Sciences Research Center, University at Albany, Albany,
New York, USA
Kirill M. Nazarenko
Department of Applied Mathematics, Moscow State
Univ. of Technology “STANKIN”, Moscow, Russian Federation
Lyudmila A. Uvarova
Department of Applied Mathematics, Moscow State
Univ. of Technology “STANKIN”, Moscow, Russian Federation
National Research Nuclear University MEPhI (Moscow Engineering
Physics Institute), Department of General Physics, Moscow, Russian
Federation
Viewed
Total article views: 2,803 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Jun 2018)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,829 | 918 | 56 | 2,803 | 100 | 91 |
- HTML: 1,829
- PDF: 918
- XML: 56
- Total: 2,803
- BibTeX: 100
- EndNote: 91
Total article views: 2,178 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Dec 2018)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,482 | 652 | 44 | 2,178 | 85 | 80 |
- HTML: 1,482
- PDF: 652
- XML: 44
- Total: 2,178
- BibTeX: 85
- EndNote: 80
Total article views: 625 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 Jun 2018)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
347 | 266 | 12 | 625 | 15 | 11 |
- HTML: 347
- PDF: 266
- XML: 12
- Total: 625
- BibTeX: 15
- EndNote: 11
Viewed (geographical distribution)
Total article views: 2,803 (including HTML, PDF, and XML)
Thereof 2,738 with geography defined
and 65 with unknown origin.
Total article views: 2,178 (including HTML, PDF, and XML)
Thereof 2,115 with geography defined
and 63 with unknown origin.
Total article views: 625 (including HTML, PDF, and XML)
Thereof 623 with geography defined
and 2 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
51 citations as recorded by crossref.
- An Atmospheric Cluster Database Consisting of Sulfuric Acid, Bases, Organics, and Water J. Elm 10.1021/acsomega.9b00860
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
- Particle number concentrations and size distributions in the stratosphere: implications of nucleation mechanisms and particle microphysics F. Yu et al. 10.5194/acp-23-1863-2023
- Revised treatment of wet scavenging processes dramatically improves GEOS-Chem 12.0.0 simulations of surface nitric acid, nitrate, and ammonium over the United States G. Luo et al. 10.5194/gmd-12-3439-2019
- New Particle Formation in the Atmosphere: From Molecular Clusters to Global Climate S. Lee et al. 10.1029/2018JD029356
- Quantification of Atmospheric Ammonia Concentrations: A Review of Its Measurement and Modeling A. Nair & F. Yu 10.3390/atmos11101092
- On the Ship Particle Number Emission Index: Size‐Resolved Microphysics and Key Controlling Parameters J. Mao et al. 10.1029/2020JD034427
- Experiment–theory hybrid method for studying the formation mechanism of atmospheric new particle formation Y. Liu et al. 10.1039/D2CP03551K
- H<sub>2</sub>SO<sub>4</sub>–H<sub>2</sub>O binary and H<sub>2</sub>SO<sub>4</sub>–H<sub>2</sub>O–NH<sub>3</sub> ternary homogeneous and ion-mediated nucleation: lookup tables version 1.0 for 3-D modeling application F. Yu et al. 10.5194/gmd-13-2663-2020
- Sulfuric Acid Nucleation Potential Model Applied to Complex Reacting Systems in the Atmosphere J. Johnson & C. Jen 10.1029/2023JD039344
- Using machine learning to derive cloud condensation nuclei number concentrations from commonly available measurements A. Nair & F. Yu 10.5194/acp-20-12853-2020
- The importance of ammonia for springtime atmospheric new particle formation and aerosol number abundance over the United States A. Nair et al. 10.1016/j.scitotenv.2022.160756
- Tutorial: The discrete-sectional method to simulate an evolving aerosol C. Li & R. Cai 10.1016/j.jaerosci.2020.105615
- An indicator for sulfuric acid–amine nucleation in atmospheric environments R. Cai et al. 10.1080/02786826.2021.1922598
- Reducing chemical complexity in representation of new-particle formation: evaluation of simplification approaches T. Olenius et al. 10.1039/D2EA00174H
- Revisiting Contrail Ice Formation: Impact of Primary Soot Particle Sizes and Contribution of Volatile Particles F. Yu et al. 10.1021/acs.est.4c04340
- Environmental exposure disparities in ultrafine particles and PM2.5 by urbanicity and socio-demographics in New York state, 2013–2020 A. Nair et al. 10.1016/j.envres.2023.117246
- Volatile organic compounds enhancing sulfuric acid-based ternary homogeneous nucleation: The important role of synergistic effect Y. Zhao et al. 10.1016/j.atmosenv.2020.117609
- Evaluation of global simulations of aerosol particle and cloud condensation nuclei number, with implications for cloud droplet formation G. Fanourgakis et al. 10.5194/acp-19-8591-2019
- A sulfuric acid nucleation potential model for the atmosphere J. Johnson & C. Jen 10.5194/acp-22-8287-2022
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Wintertime new particle formation and its contribution to cloud condensation nuclei in the Northeastern United States F. Yu et al. 10.5194/acp-20-2591-2020
- Global–regional nested simulation of particle number concentration by combing microphysical processes with an evolving organic aerosol module X. Chen et al. 10.5194/acp-21-9343-2021
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- Toward a Holistic Understanding of the Formation and Growth of Atmospheric Molecular Clusters: A Quantum Machine Learning Perspective J. Elm 10.1021/acs.jpca.0c09762
- New Particle Formation Occurrence in the Urban Atmosphere of Beijing During 2013–2020 D. Shang et al. 10.1029/2022JD038334
- Discovery of a Potent Source of Gaseous Amines in Urban China Y. Chang et al. 10.1021/acs.estlett.1c00229
- New particle formation, growth and apparent shrinkage at a rural background site in western Saudi Arabia S. Hakala et al. 10.5194/acp-19-10537-2019
- Interactions of sulfuric acid with common atmospheric bases and organic acids: Thermodynamics and implications to new particle formation Y. Li et al. 10.1016/j.jes.2020.03.033
- An examination of the algorithm for estimating light extinction from IMPROVE particle speciation data A. Prenni et al. 10.1016/j.atmosenv.2019.116880
- Quantum Machine Learning Approach for Studying Atmospheric Cluster Formation J. Kubečka et al. 10.1021/acs.estlett.1c00997
- Analysis of new particle formation events and comparisons to simulations of particle number concentrations based on GEOS-Chem–advanced particle microphysics in Beijing, China K. Wang et al. 10.5194/acp-23-4091-2023
- The influence of marine environment on the conservation state of Built Heritage: An overview study H. Morillas et al. 10.1016/j.scitotenv.2020.140899
- On Nucleation Pathways and Particle Size Distribution Evolutions in Stratospheric Aircraft Exhaust Plumes with H2SO4 Enhancement F. Yu et al. 10.1021/acs.est.3c08408
- Predictive modeling of atmospheric nuclear fallout microphysics D. McGuffin et al. 10.1016/j.scitotenv.2024.175536
- Description and evaluation of the community aerosol dynamics model MAFOR v2.0 M. Karl et al. 10.5194/gmd-15-3969-2022
- Particle surface area, ultrafine particle number concentration, and cardiovascular hospitalizations S. Lin et al. 10.1016/j.envpol.2022.119795
- Atmospheric new particle formation in India: Current understanding and knowledge gaps V. Kanawade et al. 10.1016/j.atmosenv.2021.118894
- Nucleation mechanisms of iodic acid in clean and polluted coastal regions H. Rong et al. 10.1016/j.chemosphere.2020.126743
- Sulfuric acid–amine nucleation in urban Beijing R. Cai et al. 10.5194/acp-21-2457-2021
- Use of Machine Learning to Reduce Uncertainties in Particle Number Concentration and Aerosol Indirect Radiative Forcing Predicted by Climate Models F. Yu et al. 10.1029/2022GL098551
- Organic acid-ammonia ion-induced nucleation pathways unveiled by quantum chemical calculation and kinetics modeling: A case study of 3-methyl-1,2,3-butanetricarboxylic acid D. Xia et al. 10.1016/j.chemosphere.2021.131354
- Modeling the formation and growth of atmospheric molecular clusters: A review J. Elm et al. 10.1016/j.jaerosci.2020.105621
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- Understanding vapor nucleation on the molecular level: A review C. Li & R. Signorell 10.1016/j.jaerosci.2020.105676
- Trimethylamine from Subtropical Forests Rival Total Farmland Emissions in China Y. Chang et al. 10.1021/acs.est.4c00622
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- The effectiveness of the coagulation sink of 3–10 nm atmospheric particles R. Cai et al. 10.5194/acp-22-11529-2022
- Gas-phase catalytic hydration of I2O5 in the polluted coastal regions: Reaction mechanisms and atmospheric implications Y. Liang et al. 10.1016/j.jes.2021.09.028
- A core-shell box model for simulating viscosity dependent secondary organic aerosol (CSVA) and its application L. Jia & Y. Xu 10.1016/j.scitotenv.2021.147954
- Using machine learning to derive cloud condensation nuclei number concentrations from commonly available measurements A. Nair & F. Yu 10.5194/acp-20-12853-2020
50 citations as recorded by crossref.
- An Atmospheric Cluster Database Consisting of Sulfuric Acid, Bases, Organics, and Water J. Elm 10.1021/acsomega.9b00860
- Identification of molecular cluster evaporation rates, cluster formation enthalpies and entropies by Monte Carlo method A. Shcherbacheva et al. 10.5194/acp-20-15867-2020
- Particle number concentrations and size distributions in the stratosphere: implications of nucleation mechanisms and particle microphysics F. Yu et al. 10.5194/acp-23-1863-2023
- Revised treatment of wet scavenging processes dramatically improves GEOS-Chem 12.0.0 simulations of surface nitric acid, nitrate, and ammonium over the United States G. Luo et al. 10.5194/gmd-12-3439-2019
- New Particle Formation in the Atmosphere: From Molecular Clusters to Global Climate S. Lee et al. 10.1029/2018JD029356
- Quantification of Atmospheric Ammonia Concentrations: A Review of Its Measurement and Modeling A. Nair & F. Yu 10.3390/atmos11101092
- On the Ship Particle Number Emission Index: Size‐Resolved Microphysics and Key Controlling Parameters J. Mao et al. 10.1029/2020JD034427
- Experiment–theory hybrid method for studying the formation mechanism of atmospheric new particle formation Y. Liu et al. 10.1039/D2CP03551K
- H<sub>2</sub>SO<sub>4</sub>–H<sub>2</sub>O binary and H<sub>2</sub>SO<sub>4</sub>–H<sub>2</sub>O–NH<sub>3</sub> ternary homogeneous and ion-mediated nucleation: lookup tables version 1.0 for 3-D modeling application F. Yu et al. 10.5194/gmd-13-2663-2020
- Sulfuric Acid Nucleation Potential Model Applied to Complex Reacting Systems in the Atmosphere J. Johnson & C. Jen 10.1029/2023JD039344
- Using machine learning to derive cloud condensation nuclei number concentrations from commonly available measurements A. Nair & F. Yu 10.5194/acp-20-12853-2020
- The importance of ammonia for springtime atmospheric new particle formation and aerosol number abundance over the United States A. Nair et al. 10.1016/j.scitotenv.2022.160756
- Tutorial: The discrete-sectional method to simulate an evolving aerosol C. Li & R. Cai 10.1016/j.jaerosci.2020.105615
- An indicator for sulfuric acid–amine nucleation in atmospheric environments R. Cai et al. 10.1080/02786826.2021.1922598
- Reducing chemical complexity in representation of new-particle formation: evaluation of simplification approaches T. Olenius et al. 10.1039/D2EA00174H
- Revisiting Contrail Ice Formation: Impact of Primary Soot Particle Sizes and Contribution of Volatile Particles F. Yu et al. 10.1021/acs.est.4c04340
- Environmental exposure disparities in ultrafine particles and PM2.5 by urbanicity and socio-demographics in New York state, 2013–2020 A. Nair et al. 10.1016/j.envres.2023.117246
- Volatile organic compounds enhancing sulfuric acid-based ternary homogeneous nucleation: The important role of synergistic effect Y. Zhao et al. 10.1016/j.atmosenv.2020.117609
- Evaluation of global simulations of aerosol particle and cloud condensation nuclei number, with implications for cloud droplet formation G. Fanourgakis et al. 10.5194/acp-19-8591-2019
- A sulfuric acid nucleation potential model for the atmosphere J. Johnson & C. Jen 10.5194/acp-22-8287-2022
- New particle formation (NPF) events in China urban clusters given by sever composite pollution background Q. Zhang et al. 10.1016/j.chemosphere.2020.127842
- Wintertime new particle formation and its contribution to cloud condensation nuclei in the Northeastern United States F. Yu et al. 10.5194/acp-20-2591-2020
- Global–regional nested simulation of particle number concentration by combing microphysical processes with an evolving organic aerosol module X. Chen et al. 10.5194/acp-21-9343-2021
- New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions A. Kürten 10.5194/acp-19-5033-2019
- Toward a Holistic Understanding of the Formation and Growth of Atmospheric Molecular Clusters: A Quantum Machine Learning Perspective J. Elm 10.1021/acs.jpca.0c09762
- New Particle Formation Occurrence in the Urban Atmosphere of Beijing During 2013–2020 D. Shang et al. 10.1029/2022JD038334
- Discovery of a Potent Source of Gaseous Amines in Urban China Y. Chang et al. 10.1021/acs.estlett.1c00229
- New particle formation, growth and apparent shrinkage at a rural background site in western Saudi Arabia S. Hakala et al. 10.5194/acp-19-10537-2019
- Interactions of sulfuric acid with common atmospheric bases and organic acids: Thermodynamics and implications to new particle formation Y. Li et al. 10.1016/j.jes.2020.03.033
- An examination of the algorithm for estimating light extinction from IMPROVE particle speciation data A. Prenni et al. 10.1016/j.atmosenv.2019.116880
- Quantum Machine Learning Approach for Studying Atmospheric Cluster Formation J. Kubečka et al. 10.1021/acs.estlett.1c00997
- Analysis of new particle formation events and comparisons to simulations of particle number concentrations based on GEOS-Chem–advanced particle microphysics in Beijing, China K. Wang et al. 10.5194/acp-23-4091-2023
- The influence of marine environment on the conservation state of Built Heritage: An overview study H. Morillas et al. 10.1016/j.scitotenv.2020.140899
- On Nucleation Pathways and Particle Size Distribution Evolutions in Stratospheric Aircraft Exhaust Plumes with H2SO4 Enhancement F. Yu et al. 10.1021/acs.est.3c08408
- Predictive modeling of atmospheric nuclear fallout microphysics D. McGuffin et al. 10.1016/j.scitotenv.2024.175536
- Description and evaluation of the community aerosol dynamics model MAFOR v2.0 M. Karl et al. 10.5194/gmd-15-3969-2022
- Particle surface area, ultrafine particle number concentration, and cardiovascular hospitalizations S. Lin et al. 10.1016/j.envpol.2022.119795
- Atmospheric new particle formation in India: Current understanding and knowledge gaps V. Kanawade et al. 10.1016/j.atmosenv.2021.118894
- Nucleation mechanisms of iodic acid in clean and polluted coastal regions H. Rong et al. 10.1016/j.chemosphere.2020.126743
- Sulfuric acid–amine nucleation in urban Beijing R. Cai et al. 10.5194/acp-21-2457-2021
- Use of Machine Learning to Reduce Uncertainties in Particle Number Concentration and Aerosol Indirect Radiative Forcing Predicted by Climate Models F. Yu et al. 10.1029/2022GL098551
- Organic acid-ammonia ion-induced nucleation pathways unveiled by quantum chemical calculation and kinetics modeling: A case study of 3-methyl-1,2,3-butanetricarboxylic acid D. Xia et al. 10.1016/j.chemosphere.2021.131354
- Modeling the formation and growth of atmospheric molecular clusters: A review J. Elm et al. 10.1016/j.jaerosci.2020.105621
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- Understanding vapor nucleation on the molecular level: A review C. Li & R. Signorell 10.1016/j.jaerosci.2020.105676
- Trimethylamine from Subtropical Forests Rival Total Farmland Emissions in China Y. Chang et al. 10.1021/acs.est.4c00622
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- The effectiveness of the coagulation sink of 3–10 nm atmospheric particles R. Cai et al. 10.5194/acp-22-11529-2022
- Gas-phase catalytic hydration of I2O5 in the polluted coastal regions: Reaction mechanisms and atmospheric implications Y. Liang et al. 10.1016/j.jes.2021.09.028
- A core-shell box model for simulating viscosity dependent secondary organic aerosol (CSVA) and its application L. Jia & Y. Xu 10.1016/j.scitotenv.2021.147954
Latest update: 20 Nov 2024
Short summary
Aerosol nucleation exerts important influences on the climate, hydrological cycle, and air quality. We have developed an advanced physical–chemical model that describes ion-induced and neutral nucleation involving ammonia, sulfuric acid, and water vapors. The model is shown to reproduce laboratory measurements taken under a wide range of conditions, offers physiochemical insights into the ternary nucleation process, and provides an accurate approach to calculate ternary rate in the atmosphere.
Aerosol nucleation exerts important influences on the climate, hydrological cycle, and air...
Altmetrics
Final-revised paper
Preprint