Articles | Volume 18, issue 21
https://doi.org/10.5194/acp-18-15535-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-15535-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS
Dongyu S. Wang
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, USA
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, USA
Viewed
Total article views: 4,015 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 May 2018)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,553 | 1,389 | 73 | 4,015 | 491 | 70 | 97 |
- HTML: 2,553
- PDF: 1,389
- XML: 73
- Total: 4,015
- Supplement: 491
- BibTeX: 70
- EndNote: 97
Total article views: 3,119 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 30 Oct 2018)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,008 | 1,056 | 55 | 3,119 | 348 | 54 | 83 |
- HTML: 2,008
- PDF: 1,056
- XML: 55
- Total: 3,119
- Supplement: 348
- BibTeX: 54
- EndNote: 83
Total article views: 896 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 May 2018)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
545 | 333 | 18 | 896 | 143 | 16 | 14 |
- HTML: 545
- PDF: 333
- XML: 18
- Total: 896
- Supplement: 143
- BibTeX: 16
- EndNote: 14
Viewed (geographical distribution)
Total article views: 4,015 (including HTML, PDF, and XML)
Thereof 4,049 with geography defined
and -34 with unknown origin.
Total article views: 3,119 (including HTML, PDF, and XML)
Thereof 3,160 with geography defined
and -41 with unknown origin.
Total article views: 896 (including HTML, PDF, and XML)
Thereof 889 with geography defined
and 7 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
49 citations as recorded by crossref.
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Nighttime NO emissions strongly suppress chlorine and nitrate radical formation during the winter in Delhi S. Haslett et al. 10.5194/acp-23-9023-2023
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation A. Buchholz et al. 10.5194/acp-20-7693-2020
- Insights into the different mixing states and formation processes of amine-containing single particles in Guangzhou, China Q. Zhong et al. 10.1016/j.scitotenv.2022.157440
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- Roles of semivolatile and intermediate-volatility organic compounds in secondary organic aerosol formation and its implication: A review Z. Ling et al. 10.1016/j.jes.2021.08.055
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. 10.1021/acsearthspacechem.4c00042
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany W. Huang et al. 10.5194/acp-19-11687-2019
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Advances on analytical strategies for targeted and untargeted profiling of organic aerosols: Lessons learned and future challenges R. Duarte et al. 10.1016/j.hazadv.2023.100375
- Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride Y. Li et al. 10.1021/acs.estlett.9b00704
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Measurement report: Distinct size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei activity at a rural site in the Pearl River Delta (PRD) region, China M. Cai et al. 10.5194/acp-22-8117-2022
- Roles of Semivolatile/Intermediate‐Volatility Organic Compounds on SOA Formation Over China During a Pollution Episode: Sensitivity Analysis and Implications for Future Studies L. Wu et al. 10.1029/2020JD033999
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain S. Ren et al. 10.5194/acp-22-9283-2022
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Relative contributions of selected multigeneration products to chamber SOA formed from photooxidation of a range (C10–C17) of n-alkanes under high NO conditions K. Docherty et al. 10.1016/j.atmosenv.2020.117976
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- The Spatial Distribution of Dissolved Organic Matter and Its Molecular Fingerprints in Seasonal Snow Over Northeastern China Z. Mu et al. 10.1029/2023JD039117
- Measured and Modeled Secondary Organic Aerosol Products and Yields from the Reaction of n-Hexadecane + OH/NOx A. Ranney et al. 10.1021/acsearthspacechem.3c00227
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al. 10.5194/acp-20-2489-2020
- Kinetic and mechanism of the reaction between Cl and several mono-methyl branched alkanes Y. Chen et al. 10.1016/j.jes.2022.08.010
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- A review of aerosol chemistry in Asia: insights from aerosol mass spectrometer measurements W. Zhou et al. 10.1039/D0EM00212G
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Drivers of High Concentrations of Secondary Organic Aerosols in Northern China during the COVID-19 Lockdowns X. Chang et al. 10.1021/acs.est.2c06914
- New insights into the influences of firework combustion on molecular composition and formation of sulfur- and halogen-containing organic compounds C. Yan et al. 10.1016/j.scitotenv.2024.172929
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
- Secondary Organic Aerosol Formation from Reaction of 3-Methylfuran with Nitrate Radicals T. Joo et al. 10.1021/acsearthspacechem.9b00068
48 citations as recorded by crossref.
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
- Secondary organic aerosols from oxidation of 1-methylnaphthalene: Yield, composition, and volatility W. Xiang et al. 10.1016/j.scitotenv.2024.170379
- Nighttime NO emissions strongly suppress chlorine and nitrate radical formation during the winter in Delhi S. Haslett et al. 10.5194/acp-23-9023-2023
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation A. Buchholz et al. 10.5194/acp-20-7693-2020
- Insights into the different mixing states and formation processes of amine-containing single particles in Guangzhou, China Q. Zhong et al. 10.1016/j.scitotenv.2022.157440
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- Roles of semivolatile and intermediate-volatility organic compounds in secondary organic aerosol formation and its implication: A review Z. Ling et al. 10.1016/j.jes.2021.08.055
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. 10.1021/acsearthspacechem.4c00042
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany W. Huang et al. 10.5194/acp-19-11687-2019
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Advances on analytical strategies for targeted and untargeted profiling of organic aerosols: Lessons learned and future challenges R. Duarte et al. 10.1016/j.hazadv.2023.100375
- Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride Y. Li et al. 10.1021/acs.estlett.9b00704
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Measurement report: Distinct size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei activity at a rural site in the Pearl River Delta (PRD) region, China M. Cai et al. 10.5194/acp-22-8117-2022
- Roles of Semivolatile/Intermediate‐Volatility Organic Compounds on SOA Formation Over China During a Pollution Episode: Sensitivity Analysis and Implications for Future Studies L. Wu et al. 10.1029/2020JD033999
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain S. Ren et al. 10.5194/acp-22-9283-2022
- An intercomparison study of four different techniques for measuring the chemical composition of nanoparticles L. Caudillo et al. 10.5194/acp-23-6613-2023
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Relative contributions of selected multigeneration products to chamber SOA formed from photooxidation of a range (C10–C17) of n-alkanes under high NO conditions K. Docherty et al. 10.1016/j.atmosenv.2020.117976
- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- The Spatial Distribution of Dissolved Organic Matter and Its Molecular Fingerprints in Seasonal Snow Over Northeastern China Z. Mu et al. 10.1029/2023JD039117
- Measured and Modeled Secondary Organic Aerosol Products and Yields from the Reaction of n-Hexadecane + OH/NOx A. Ranney et al. 10.1021/acsearthspacechem.3c00227
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al. 10.5194/acp-20-2489-2020
- Kinetic and mechanism of the reaction between Cl and several mono-methyl branched alkanes Y. Chen et al. 10.1016/j.jes.2022.08.010
- Formation of secondary organic aerosols from anthropogenic precursors in laboratory studies D. Srivastava et al. 10.1038/s41612-022-00238-6
- A review of aerosol chemistry in Asia: insights from aerosol mass spectrometer measurements W. Zhou et al. 10.1039/D0EM00212G
- Reactions of C12–C14 n-Alkylcyclohexanes with Cl Atoms: Kinetics and Secondary Organic Aerosol Formation K. Wang et al. 10.1021/acs.est.1c08958
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Drivers of High Concentrations of Secondary Organic Aerosols in Northern China during the COVID-19 Lockdowns X. Chang et al. 10.1021/acs.est.2c06914
- New insights into the influences of firework combustion on molecular composition and formation of sulfur- and halogen-containing organic compounds C. Yan et al. 10.1016/j.scitotenv.2024.172929
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al. 10.1080/02786826.2022.2133593
- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
1 citations as recorded by crossref.
Latest update: 20 Nov 2024
Short summary
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of alkanes, which may occur in polluted environments. We report for the first the formation of alkane-derived chlorinated organics. We also propose a new approach to representing the chemical composition, volatility, and thermal desorption behavior of organic aerosols. Overall, our study suggests that the oxidation of alkanes can be an important source of organic aerosols in polluted environments.
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of...
Altmetrics
Final-revised paper
Preprint