Articles | Volume 18, issue 21
https://doi.org/10.5194/acp-18-15535-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-15535-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS
Dongyu S. Wang
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, USA
McKetta Department of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712, USA
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47 citations as recorded by crossref.
- Different chlorine and hydroxyl radical environments impact m-xylene oxidation products N. Bhattacharyya et al. 10.1039/D3EA00024A
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- Deconvolution of FIGAERO–CIMS thermal desorption profiles using positive matrix factorisation to identify chemical and physical processes during particle evaporation A. Buchholz et al. 10.5194/acp-20-7693-2020
- Insights into the different mixing states and formation processes of amine-containing single particles in Guangzhou, China Q. Zhong et al. 10.1016/j.scitotenv.2022.157440
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- Roles of semivolatile and intermediate-volatility organic compounds in secondary organic aerosol formation and its implication: A review Z. Ling et al. 10.1016/j.jes.2021.08.055
- Characterization and Seasonal Variation of PM2.5 Composition in Xi’an, Northwest China: Oxygenated and Nitrogenous Organic Aerosol Y. Shang et al. 10.1021/acsearthspacechem.4c00042
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany W. Huang et al. 10.5194/acp-19-11687-2019
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Advances on analytical strategies for targeted and untargeted profiling of organic aerosols: Lessons learned and future challenges R. Duarte et al. 10.1016/j.hazadv.2023.100375
- Photoinduced Production of Chlorine Molecules from Titanium Dioxide Surfaces Containing Chloride Y. Li et al. 10.1021/acs.estlett.9b00704
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Measurement report: Distinct size dependence and diurnal variation in organic aerosol hygroscopicity, volatility, and cloud condensation nuclei activity at a rural site in the Pearl River Delta (PRD) region, China M. Cai et al. 10.5194/acp-22-8117-2022
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- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
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- Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane A. Avery et al. 10.1021/acsearthspacechem.2c00304
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
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- High Chlorine Concentrations in an Unconventional Oil and Gas Development Region and Impacts on Atmospheric Chemistry C. Masoud et al. 10.1021/acs.est.3c04005
1 citations as recorded by crossref.
Latest update: 16 Aug 2024
Short summary
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of alkanes, which may occur in polluted environments. We report for the first the formation of alkane-derived chlorinated organics. We also propose a new approach to representing the chemical composition, volatility, and thermal desorption behavior of organic aerosols. Overall, our study suggests that the oxidation of alkanes can be an important source of organic aerosols in polluted environments.
We investigated the formation of atmospheric pollutants from chlorine-initiated oxidation of...
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