Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-14979-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-14979-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Oct 2018
Research article |
| 18 Oct 2018
| 18 Oct 2018
Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region
Christiane Schulz
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Johannes Schneider
CORRESPONDING AUTHOR
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Bruna Amorim Holanda
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Oliver Appel
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Anja Costa
Institut für Energie- und Klimaforschung (IEK7), Forschungszentrum Jülich GmbH, Jülich, Germany
Suzane S. de Sá
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
Volker Dreiling
Flight Experiments, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Daniel Fütterer
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Tina Jurkat-Witschas
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Thomas Klimach
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Christoph Knote
Meteorological Institute, Ludwig Maximilian University, Munich, Germany
Martina Krämer
Institut für Energie- und Klimaforschung (IEK7), Forschungszentrum Jülich GmbH, Jülich, Germany
Scot T. Martin
School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA
Department of Earth and Planetary Sciences, Harvard University, Cambridge, Massachusetts, USA
Stephan Mertes
Leibniz Institute for Tropospheric Research, Leipzig, Germany
Mira L. Pöhlker
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Daniel Sauer
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Christiane Voigt
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Institute for Physics of the Atmosphere, Johannes Gutenberg University, Mainz, Germany
Adrian Walser
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Meteorological Institute, Ludwig Maximilian University, Munich, Germany
Faculty of Physics, University of Vienna, Vienna, Austria
Bernadett Weinzierl
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Faculty of Physics, University of Vienna, Vienna, Austria
Helmut Ziereis
Institute for Atmospheric Physics, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Martin Zöger
Flight Experiments, German Aerospace Center (Deutsches Zentrum für Luft- und Raumfahrt), Oberpfaffenhofen, Germany
Meinrat O. Andreae
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Scripps Institution of Oceanography, University of California San Diego, La Jolla, California, USA
Paulo Artaxo
Instituto de Física, Universidade de São Paulo, São Paulo, Brazil
Luiz A. T. Machado
Instituto Nacional de Pesquisas Espaciais (INPE), Centro de Previsão de Tempo e Estudos Climáticos, São José dos Campos, Brazil
Ulrich Pöschl
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Manfred Wendisch
Leipzig Institute for Meteorology, University of Leipzig, Leipzig, Germany
Stephan Borrmann
Particle Chemistry, Biogeochemistry and Multiphase Chemistry Departments, Max Planck Institute for Chemistry, Mainz, Germany
Institute for Physics of the Atmosphere, Johannes Gutenberg University, Mainz, Germany
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36 citations as recorded by crossref.
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34 citations as recorded by crossref.
- Evaluation of the Sources, Precursors, and Processing of Aerosols at a High-Altitude Tropical Site P. Dominutti et al. 10.1021/acsearthspacechem.2c00149
- Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
- Anomalous Vertical Distribution of Organic Aerosol over the South of Western Siberia in September 2018 M. Arshinov et al. 10.1134/S1024856021050043
- A biogenic secondary organic aerosol source of cirrus ice nucleating particles M. Wolf et al. 10.1038/s41467-020-18424-6
- How weather events modify aerosol particle size distributions in the Amazon boundary layer L. Machado et al. 10.5194/acp-21-18065-2021
- Aerosol characteristics and particle production in the upper troposphere over the Amazon Basin M. Andreae et al. 10.5194/acp-18-921-2018
- Contribution of regional aerosol nucleation to low-level CCN in an Amazonian deep convective environment: results from a regionally nested global model X. Wang et al. 10.5194/acp-23-4431-2023
- Overview: On the transport and transformation of pollutants in the outflow of major population centres – observational data from the EMeRGe European intensive operational period in summer 2017 M. Andrés Hernández et al. 10.5194/acp-22-5877-2022
- Total OH reactivity over the Amazon rainforest: variability with temperature, wind, rain, altitude, time of day, season, and an overall budget closure E. Pfannerstill et al. 10.5194/acp-21-6231-2021
- Transport and chemistry of isoprene and its oxidation products in deep convective clouds R. Bardakov et al. 10.1080/16000889.2021.1979856
- Chemical analysis of the Asian tropopause aerosol layer (ATAL) with emphasis on secondary aerosol particles using aircraft-based in situ aerosol mass spectrometry O. Appel et al. 10.5194/acp-22-13607-2022
- A systematic re-evaluation of methods for quantification of bulk particle-phase organic nitrates using real-time aerosol mass spectrometry D. Day et al. 10.5194/amt-15-459-2022
- Modeling Novel Aqueous Particle and Cloud Chemistry Processes of Biomass Burning Phenols and Their Potential to Form Secondary Organic Aerosols J. Zhang et al. 10.1021/acs.est.3c07762
- Profiling of formaldehyde, glyoxal, methylglyoxal, and CO over the Amazon: normalized excess mixing ratios and related emission factors in biomass burning plumes F. Kluge et al. 10.5194/acp-20-12363-2020
- Atmospheric oxidation mechanism and kinetics of isoprene initiated by chlorine radicals: A computational study X. Guo et al. 10.1016/j.scitotenv.2019.136330
- Influx of African biomass burning aerosol during the Amazonian dry season through layered transatlantic transport of black carbon-rich smoke B. Holanda et al. 10.5194/acp-20-4757-2020
- In situ observation of new particle formation (NPF) in the tropical tropopause layer of the 2017 Asian monsoon anticyclone – Part 2: NPF inside ice clouds R. Weigel et al. 10.5194/acp-21-13455-2021
- Application of an O-ring pinch device as a constant-pressure inlet (CPI) for airborne sampling S. Molleker et al. 10.5194/amt-13-3651-2020
- Design, characterization, and first field deployment of a novel aircraft-based aerosol mass spectrometer combining the laser ablation and flash vaporization techniques A. Hünig et al. 10.5194/amt-15-2889-2022
- Exploring the Factors Controlling the Long‐Term Trend (1988–2019) of Surface Organic Aerosols in the Continental United States by Simulations Y. Liu et al. 10.1029/2022JD037935
- Tight Coupling of Surface and In-Plant Biochemistry and Convection Governs Key Fine Particulate Components over the Amazon Rainforest M. Shrivastava et al. 10.1021/acsearthspacechem.1c00356
- Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
- Ammonium nitrate particles formed in upper troposphere from ground ammonia sources during Asian monsoons M. Höpfner et al. 10.1038/s41561-019-0385-8
- Comparison of aircraft measurements during GoAmazon2014/5 and ACRIDICON-CHUVA F. Mei et al. 10.5194/amt-13-661-2020
- Constraints on the Role of Laplace Pressure in Multiphase Reactions and Viscosity of Organic Aerosols S. Petters 10.1029/2022GL098959
- The realization of autonomous, aircraft-based, real-time aerosol mass spectrometry in the upper troposphere and lower stratosphere A. Dragoneas et al. 10.5194/amt-15-5719-2022
- Radical Formation by Fine Particulate Matter Associated with Highly Oxygenated Molecules H. Tong et al. 10.1021/acs.est.9b05149
- Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
- Mass spectrometric measurements of ambient ions and estimation of gaseous sulfuric acid in the free troposphere and lowermost stratosphere during the CAFE-EU/BLUESKY campaign M. Zauner-Wieczorek et al. 10.5194/acp-22-11781-2022
- High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation B. Zhao et al. 10.1073/pnas.2006716117
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- Nocturnal survival of isoprene linked to formation of upper tropospheric organic aerosol P. Palmer et al. 10.1126/science.abg4506
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- Strong particle production and condensational growth in the upper troposphere sustained by biogenic VOCs from the canopy of the Amazon Basin Y. Liu et al. 10.5194/acp-23-251-2023
2 citations as recorded by crossref.
Saved (preprint)
Latest update: 24 Apr 2024
Short summary
Aerosol chemical composition measurements in the tropical upper troposphere over the Amazon region show that 78 % of the aerosol in the upper troposphere consists of organic matter. Up to 20 % of the organic aerosol can be attributed to isoprene epoxydiol secondary organic aerosol (IEPOX-SOA). Furthermore, organic nitrates were identified, suggesting a connection to the IEPOX-SOA formation.
Aerosol chemical composition measurements in the tropical upper troposphere over the Amazon...
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