Articles | Volume 18, issue 19
Atmos. Chem. Phys., 18, 13839–13863, 2018
https://doi.org/10.5194/acp-18-13839-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 18, 13839–13863, 2018
https://doi.org/10.5194/acp-18-13839-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
01 Oct 2018
Research article
| 01 Oct 2018
Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest
Heidi Hellén et al.
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Cited
42 citations as recorded by crossref.
- Foliar behaviour of biogenic semi-volatiles: potential applications in sustainable pest management A. Mofikoya et al. 10.1007/s11829-019-09676-1
- Sesquiterpenes and oxygenated sesquiterpenes dominate the VOC (C<sub>5</sub>–C<sub>20</sub>) emissions of downy birches H. Hellén et al. 10.5194/acp-21-8045-2021
- Unravelling the functions of biogenic volatiles in boreal and temperate forest ecosystems M. Šimpraga et al. 10.1007/s10342-019-01213-2
- Trends and source apportionment of atmospheric heavy metals at a subarctic site during 1996–2018 K. Kyllönen et al. 10.1016/j.atmosenv.2020.117644
- Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations L. Dada et al. 10.5194/acp-20-11747-2020
- Measurements of total ozone reactivity in a suburban forest in Japan J. Matsumoto 10.1016/j.atmosenv.2020.117990
- Significance of the organic aerosol driven climate feedback in the boreal area T. Yli-Juuti et al. 10.1038/s41467-021-25850-7
- Arthropod infestation sites and induced defence can be traced by emission from single spruce needles M. Danielsson et al. 10.1007/s11829-019-09677-0
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Evaluation of convective boundary layer height estimates using radars operating at different frequency bands A. Franck et al. 10.5194/amt-14-7341-2021
- Sesquiterpenes dominate monoterpenes in northern wetland emissions H. Hellén et al. 10.5194/acp-20-7021-2020
- Phytochemical Screening of Volatile Organic Compounds in Three Common Coniferous Tree Species in Terms of Forest Ecosystem Services M. Zorić et al. 10.3390/f12070928
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Trajectory-based analysis on the source areas and transportation pathways of atmospheric particulate matter over Eastern Finland O. Väisänen et al. 10.1080/16000889.2020.1799687
- Terpenes and their oxidation products in the French Landes forest: insights from Vocus PTR-TOF measurements H. Li et al. 10.5194/acp-20-1941-2020
- The importance of accounting for enhanced emissions of monoterpenes from new Scots pine foliage in models - A Finnish case study D. Taipale et al. 10.1016/j.aeaoa.2020.100097
- Ozone deposition impact assessments for forest canopies require accurate ozone flux partitioning on diurnal timescales A. Visser et al. 10.5194/acp-21-18393-2021
- Atmospheric reactivity of biogenic volatile organic compounds in a maritime pine forest during the LANDEX episode 1 field campaign K. Mermet et al. 10.1016/j.scitotenv.2020.144129
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. 10.5194/acp-20-5629-2020
- Seasonal and diurnal variations in biogenic volatile organic compounds in highland and lowland ecosystems in southern Kenya Y. Liu et al. 10.5194/acp-21-14761-2021
- Biogenic volatile organic compounds in different ecosystems in Southern Kenya Y. Liu et al. 10.1016/j.atmosenv.2020.118064
- Assessing volatile organic compound sources in a boreal forest using positive matrix factorization (PMF) M. Vestenius et al. 10.1016/j.atmosenv.2021.118503
- Optimisation of a thermal desorption–gas chromatography–mass spectrometry method for the analysis of monoterpenes, sesquiterpenes and diterpenes A. Helin et al. 10.5194/amt-13-3543-2020
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Clouds over Hyytiälä, Finland: an algorithm to classify clouds based on solar radiation and cloud base height measurements I. Ylivinkka et al. 10.5194/amt-13-5595-2020
- Measurement report: Variability in the composition of biogenic volatile organic compounds in a Southeastern US forest and their role in atmospheric reactivity D. McGlynn et al. 10.5194/acp-21-15755-2021
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Deadwood substrate and species-species interactions determine the release of volatile organic compounds by wood-decaying fungi M. Mäki et al. 10.1016/j.funeco.2021.101106
- A modelling study of OH, NO3 and H2SO4 in 2007–2018 at SMEAR II, Finland: analysis of long-term trends D. Chen et al. 10.1039/D1EA00020A
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Surprising chiral composition changes over the Amazon rainforest with height, time and season N. Zannoni et al. 10.1038/s43247-020-0007-9
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Kinetics and products of the aqueous-phase oxidation of β-caryophyllonic acid by hydroxyl radicals B. Witkowski et al. 10.1016/j.atmosenv.2019.06.016
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Drought affects carbon partitioning into volatile organic compound biosynthesis in Scots pine needles J. Kreuzwieser et al. 10.1111/nph.17736
- An instrument for in situ measurement of total ozone reactivity R. Sommariva et al. 10.5194/amt-13-1655-2020
- OH reactivity from the emissions of different tree species: investigating the missing reactivity in a boreal forest A. Praplan et al. 10.5194/bg-17-4681-2020
- Driving parameters of biogenic volatile organic compounds and consequences on new particle formation observed at an eastern Mediterranean background site C. Debevec et al. 10.5194/acp-18-14297-2018
41 citations as recorded by crossref.
- Foliar behaviour of biogenic semi-volatiles: potential applications in sustainable pest management A. Mofikoya et al. 10.1007/s11829-019-09676-1
- Sesquiterpenes and oxygenated sesquiterpenes dominate the VOC (C<sub>5</sub>–C<sub>20</sub>) emissions of downy birches H. Hellén et al. 10.5194/acp-21-8045-2021
- Unravelling the functions of biogenic volatiles in boreal and temperate forest ecosystems M. Šimpraga et al. 10.1007/s10342-019-01213-2
- Trends and source apportionment of atmospheric heavy metals at a subarctic site during 1996–2018 K. Kyllönen et al. 10.1016/j.atmosenv.2020.117644
- Sources and sinks driving sulfuric acid concentrations in contrasting environments: implications on proxy calculations L. Dada et al. 10.5194/acp-20-11747-2020
- Measurements of total ozone reactivity in a suburban forest in Japan J. Matsumoto 10.1016/j.atmosenv.2020.117990
- Significance of the organic aerosol driven climate feedback in the boreal area T. Yli-Juuti et al. 10.1038/s41467-021-25850-7
- Arthropod infestation sites and induced defence can be traced by emission from single spruce needles M. Danielsson et al. 10.1007/s11829-019-09677-0
- Long-term total OH reactivity measurements in a boreal forest A. Praplan et al. 10.5194/acp-19-14431-2019
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Evaluation of convective boundary layer height estimates using radars operating at different frequency bands A. Franck et al. 10.5194/amt-14-7341-2021
- Sesquiterpenes dominate monoterpenes in northern wetland emissions H. Hellén et al. 10.5194/acp-20-7021-2020
- Phytochemical Screening of Volatile Organic Compounds in Three Common Coniferous Tree Species in Terms of Forest Ecosystem Services M. Zorić et al. 10.3390/f12070928
- Atmospheric β-Caryophyllene-Derived Ozonolysis Products at Interfaces A. Bé et al. 10.1021/acsearthspacechem.8b00156
- Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes H. Li et al. 10.5194/acp-21-4123-2021
- Contrasting Reactive Organic Carbon Observations in the Southeast United States (SOAS) and Southern California (CalNex) C. Heald et al. 10.1021/acs.est.0c05027
- Trajectory-based analysis on the source areas and transportation pathways of atmospheric particulate matter over Eastern Finland O. Väisänen et al. 10.1080/16000889.2020.1799687
- Terpenes and their oxidation products in the French Landes forest: insights from Vocus PTR-TOF measurements H. Li et al. 10.5194/acp-20-1941-2020
- The importance of accounting for enhanced emissions of monoterpenes from new Scots pine foliage in models - A Finnish case study D. Taipale et al. 10.1016/j.aeaoa.2020.100097
- Ozone deposition impact assessments for forest canopies require accurate ozone flux partitioning on diurnal timescales A. Visser et al. 10.5194/acp-21-18393-2021
- Atmospheric reactivity of biogenic volatile organic compounds in a maritime pine forest during the LANDEX episode 1 field campaign K. Mermet et al. 10.1016/j.scitotenv.2020.144129
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. 10.5194/acp-20-5629-2020
- Seasonal and diurnal variations in biogenic volatile organic compounds in highland and lowland ecosystems in southern Kenya Y. Liu et al. 10.5194/acp-21-14761-2021
- Biogenic volatile organic compounds in different ecosystems in Southern Kenya Y. Liu et al. 10.1016/j.atmosenv.2020.118064
- Assessing volatile organic compound sources in a boreal forest using positive matrix factorization (PMF) M. Vestenius et al. 10.1016/j.atmosenv.2021.118503
- Optimisation of a thermal desorption–gas chromatography–mass spectrometry method for the analysis of monoterpenes, sesquiterpenes and diterpenes A. Helin et al. 10.5194/amt-13-3543-2020
- Contribution of Terpenes to Ozone Formation and Secondary Organic Aerosols in a Subtropical Forest Impacted by Urban Pollution C. Salvador et al. 10.3390/atmos11111232
- Clouds over Hyytiälä, Finland: an algorithm to classify clouds based on solar radiation and cloud base height measurements I. Ylivinkka et al. 10.5194/amt-13-5595-2020
- Measurement report: Variability in the composition of biogenic volatile organic compounds in a Southeastern US forest and their role in atmospheric reactivity D. McGlynn et al. 10.5194/acp-21-15755-2021
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Deadwood substrate and species-species interactions determine the release of volatile organic compounds by wood-decaying fungi M. Mäki et al. 10.1016/j.funeco.2021.101106
- A modelling study of OH, NO3 and H2SO4 in 2007–2018 at SMEAR II, Finland: analysis of long-term trends D. Chen et al. 10.1039/D1EA00020A
- First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS L. Fischer et al. 10.5194/amt-14-8019-2021
- Surprising chiral composition changes over the Amazon rainforest with height, time and season N. Zannoni et al. 10.1038/s43247-020-0007-9
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Kinetics and products of the aqueous-phase oxidation of β-caryophyllonic acid by hydroxyl radicals B. Witkowski et al. 10.1016/j.atmosenv.2019.06.016
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Drought affects carbon partitioning into volatile organic compound biosynthesis in Scots pine needles J. Kreuzwieser et al. 10.1111/nph.17736
- An instrument for in situ measurement of total ozone reactivity R. Sommariva et al. 10.5194/amt-13-1655-2020
- OH reactivity from the emissions of different tree species: investigating the missing reactivity in a boreal forest A. Praplan et al. 10.5194/bg-17-4681-2020
Latest update: 26 Jan 2023
Short summary
Exceptionally large ambient air concentration datasets of VOCs were measured in a boreal forest. For the first time concentration of the main sesquiterpene (β-caryophyllene) emitted by the local trees was also measured. Sesquiterpenes were found to have a major impact on local atmospheric chemistry, even though their concentrations were 30 times lower than the monoterpene concentrations. In addition, sesquiterpenes are expected to have a high impact on local secondary organic aerosol production.
Exceptionally large ambient air concentration datasets of VOCs were measured in a boreal forest....
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