Articles | Volume 18, issue 18
https://doi.org/10.5194/acp-18-13457-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-13457-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Sep 2018
Research article |
| 21 Sep 2018
| 21 Sep 2018
Insights into HOx and ROx chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Nicolas Pouvesle
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Gavin J. Phillips
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Raoul Axinte
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Horst Fischer
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Tuukka Petäjä
Institute for Atmospheric and Earth System Research INAR/Physics, University of Helsinki, Helsinki, Finland
Anke Nölscher
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Jonathan Williams
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Korbinian Hens
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Hartwig Harder
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Monica Martinez-Harder
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Anna Novelli
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Dagmar Kubistin
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
Birger Bohn
Institut für Energie- und Klimaforschung,
Troposphäre (IEK-8), Forschungszentrum Jülich GmbH, 52425 Jülich, Germany
Jos Lelieveld
Division of Atmospheric Chemistry, Max-Planck-Institute für Chemie, Mainz, Germany
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Cited
25 citations as recorded by crossref.
- Formation of peroxyacetyl nitrate (PAN) and its impact on ozone production in the coastal atmosphere of Qingdao, North China Y. Liu et al. 10.1016/j.scitotenv.2021.146265
- Evaluation of local measurement-driven adjustments of modelled cloud-free atmospheric photolysis rate coefficients H. Walker et al. 10.1039/D2EA00072E
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. 10.1016/j.jes.2022.06.021
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Atmospheric and ecosystem big data providing key contributions in reaching United Nations’ Sustainable Development Goals M. Kulmala et al. 10.1080/20964471.2021.1936943
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- Reaction between CH<sub>3</sub>C(O)OOH (peracetic acid) and OH in the gas phase: a combined experimental and theoretical study of the kinetics and mechanism M. Berasategui et al. 10.5194/acp-20-13541-2020
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Seasonal discrepancies in peroxyacetyl nitrate (PAN) and its correlation with ozone and PM2.5: Effects of regional transport from circumjacent industrial cities M. Sun et al. 10.1016/j.scitotenv.2021.147303
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Acylperoxy Radicals as Key Intermediates in the Formation of Dimeric Compounds in α-Pinene Secondary Organic Aerosol Y. Zhao et al. 10.1021/acs.est.2c02090
- Data quality enhancement for field experiments in atmospheric chemistry via sequential Monte Carlo filters L. Röder et al. 10.5194/amt-16-1167-2023
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Laboratory measurements of stomatal NO<sub>2</sub> deposition to native California trees and the role of forests in the NO<sub>x</sub> cycle E. Delaria et al. 10.5194/acp-20-14023-2020
- Strong impacts of biomass burning, nitrogen fertilization, and fine particles on gas-phase hydrogen peroxide (H2O2) C. Ye et al. 10.1016/j.scitotenv.2022.156997
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Diurnal variability, photochemical production and loss processes of hydrogen peroxide in the boundary layer over Europe H. Fischer et al. 10.5194/acp-19-11953-2019
- OH and HO<sub>2</sub> radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. 10.5194/acp-20-9209-2020
- Photostationary Equilibrium in the O3–NOx System and Ozone Generation According to ZOTTO Tall Tower Data K. Moiseenko et al. 10.1134/S1024856023010128
- Atmospheric Hydrogen Peroxide (H2O2) at the Foot and Summit of Mt. Tai: Variations, Sources and Sinks, and Implications for Ozone Formation Chemistry C. Ye et al. 10.1029/2020JD033975
- Reaction between peracetic acid and carbonyl oxide: Quantitative kinetics and insight into implications in the atmosphere C. Xie et al. 10.1016/j.atmosenv.2024.120928
25 citations as recorded by crossref.
- Formation of peroxyacetyl nitrate (PAN) and its impact on ozone production in the coastal atmosphere of Qingdao, North China Y. Liu et al. 10.1016/j.scitotenv.2021.146265
- Evaluation of local measurement-driven adjustments of modelled cloud-free atmospheric photolysis rate coefficients H. Walker et al. 10.1039/D2EA00072E
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. 10.1016/j.jes.2022.06.021
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- Atmospheric and ecosystem big data providing key contributions in reaching United Nations’ Sustainable Development Goals M. Kulmala et al. 10.1080/20964471.2021.1936943
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- Reaction between CH<sub>3</sub>C(O)OOH (peracetic acid) and OH in the gas phase: a combined experimental and theoretical study of the kinetics and mechanism M. Berasategui et al. 10.5194/acp-20-13541-2020
- Measurement report: Photochemical production and loss rates of formaldehyde and ozone across Europe C. Nussbaumer et al. 10.5194/acp-21-18413-2021
- Seasonal discrepancies in peroxyacetyl nitrate (PAN) and its correlation with ozone and PM2.5: Effects of regional transport from circumjacent industrial cities M. Sun et al. 10.1016/j.scitotenv.2021.147303
- Impact of pyruvic acid photolysis on acetaldehyde and peroxy radical formation in the boreal forest: theoretical calculations and model results P. Eger et al. 10.5194/acp-21-14333-2021
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Acylperoxy Radicals as Key Intermediates in the Formation of Dimeric Compounds in α-Pinene Secondary Organic Aerosol Y. Zhao et al. 10.1021/acs.est.2c02090
- Data quality enhancement for field experiments in atmospheric chemistry via sequential Monte Carlo filters L. Röder et al. 10.5194/amt-16-1167-2023
- Chemical ionization quadrupole mass spectrometer with an electrical discharge ion source for atmospheric trace gas measurement P. Eger et al. 10.5194/amt-12-1935-2019
- Alkyl nitrates in the boreal forest: formation via the NO<sub>3</sub>-, OH- and O<sub>3</sub>-induced oxidation of biogenic volatile organic compounds and ambient lifetimes J. Liebmann et al. 10.5194/acp-19-10391-2019
- Laboratory measurements of stomatal NO<sub>2</sub> deposition to native California trees and the role of forests in the NO<sub>x</sub> cycle E. Delaria et al. 10.5194/acp-20-14023-2020
- Strong impacts of biomass burning, nitrogen fertilization, and fine particles on gas-phase hydrogen peroxide (H2O2) C. Ye et al. 10.1016/j.scitotenv.2022.156997
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. 10.5194/acp-20-5513-2020
- Diurnal variability, photochemical production and loss processes of hydrogen peroxide in the boundary layer over Europe H. Fischer et al. 10.5194/acp-19-11953-2019
- OH and HO<sub>2</sub> radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. 10.5194/acp-20-9209-2020
- Photostationary Equilibrium in the O3–NOx System and Ozone Generation According to ZOTTO Tall Tower Data K. Moiseenko et al. 10.1134/S1024856023010128
- Atmospheric Hydrogen Peroxide (H2O2) at the Foot and Summit of Mt. Tai: Variations, Sources and Sinks, and Implications for Ozone Formation Chemistry C. Ye et al. 10.1029/2020JD033975
- Reaction between peracetic acid and carbonyl oxide: Quantitative kinetics and insight into implications in the atmosphere C. Xie et al. 10.1016/j.atmosenv.2024.120928
Latest update: 25 Dec 2024
Short summary
Simultaneous observations of PAA, PAN and H2O2 are used to provide insight into processes influencing the HOx chemistry of the boreal forest, including two biomass-burning-impacted periods. A significant contribution from photolytic HOx sources was included in a box model analysis to align model predictions with measurements. The model predicts high levels of organic peroxy radicals, also at night-time.
Simultaneous observations of PAA, PAN and H2O2 are used to provide insight into processes...
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